US2019248678A1PendingUtilityA1

Filter materials, filters, filtering systems, and methods of filtering

Assignee: UNIV FLORIDAPriority: Apr 14, 2011Filed: Apr 17, 2019Published: Aug 15, 2019
Est. expiryApr 14, 2031(~4.7 yrs left)· nominal 20-yr term from priority
B01D 39/14C02F 2305/08B01J 20/0211B01J 20/28007B01J 20/3208C02F 1/281C02F 2101/105B01D 15/00B01D 15/02B01J 20/10B01J 20/3204B01J 20/22C02F 2101/103B01J 20/103B01J 20/3265B82Y 30/00B01J 20/0292B01J 20/3236Y02W10/37
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Claims

Abstract

Embodiments of the present disclosure provide metal ligand nanoparticles, particles including the metal ligand nanoparticles, filters including the metal ligand nanoparticles and/or particles, devices and systems for filtering a fluid, compositions including the metal ligand nanoparticles, and the like.

Claims

exact text as granted — not AI-modified
At least the following is claimed: 
     
         1 . A system for filtering a fluid to remove an anionic contaminant from a fluid comprising:
 a device including a filter, wherein the device is configured to flow the fluid through the filter to remove the anionic contaminant from the fluid, wherein the anionic contaminant is selected from a group consisting of: a phosphate, an arsenate, and a combination thereof, wherein the device is selected from the group consisting of: a down flow filtering device, a static filtering device, a fixed-media filtering device, an up flow filtering device, a fluidized-bed filtering device, a plug-flow batch filtering device, an agitated batch filtering device, a continuous stirred tank filtering device, a centrifugation filtering device, and a combination thereof,   wherein the filter configured to receive the fluid and filter the fluid comprises a metal ligand nanoparticle that has the characteristic of absorbing the anionic contaminant, wherein the metal ligand nanoparticle is selected from the group consisting of: Zr, Ti, and Hf, wherein the metal ligand nanoparticle comprises a ligand selected from the group consisting of: HPO 4   2− , (O 3 P—R—PO 3 ) 4− , (O 3 PO—ROPO 3 ) 4− , and a combination thereof, where R=CH 2 , C 2 H 4 , C 3 H 6 , C 2 H 40 , or C 6 H 4 .   
     
     
         2 . The system of  claim 1 , wherein the metal is Zr. 
     
     
         3 . The system of  claim 1 , wherein the metal ligand nanoparticle is attached to a particle. 
     
     
         4 . The system of  claim 3 , wherein particle is selected from the group consisting of a silica particle, a polymer particle, and a combination thereof. 
     
     
         5 . The system of  claim 1 , wherein the metal is Ti. 
     
     
         6 . The system of  claim 1 , wherein the metal is Hf. 
     
     
         7 . The system of  claim 1 , wherein the metal ligand nanoparticle comprises a ligand selected from the group consisting of: HPO 4   2− , (O 3 P—R—PO 3 ) 4− , or (O 3 PO—ROPO 3 ) 4− . 
     
     
         8 . The system of  claim 1 , wherein the metal ligand nanoparticle comprises a ligand, wherein the ligand is HPO 4   2− . 
     
     
         9 . The system of  claim 1 , wherein the metal ligand nanoparticle comprises a ligand, wherein the ligand is (O 3 P—R—PO 3 ) 4− . 
     
     
         10 . The system of  claim 1 , wherein the metal ligand nanoparticle comprises a ligand, wherein the ligand is (O 3 PO—ROPO 3 ) 4− . 
     
     
         11 . The system of  claim 1 , wherein the anionic contaminant is a phosphate. 
     
     
         12 . The system of  claim 1 , wherein the anionic contaminant is an arsenate. 
     
     
         13 . A system for filtering a fluid to remove an anionic contaminant from a fluid comprising:
 a device including a filter, wherein the device is configured to flow the fluid through the filter to remove the anionic contaminant from the fluid, wherein the anionic contaminant is selected from a group consisting of: a phosphate, an arsenate, and a combination thereof, wherein the device is selected from the group consisting of: a down flow filtering device, a static filtering device, a fixed-media filtering device, an up flow filtering device, a fluidized-bed filtering device, a plug-flow batch filtering device, an agitated batch filtering device, a continuous stirred tank filtering device, a centrifugation filtering device, and a combination thereof,   wherein the filter configured to receive the fluid and filter the fluid comprises a metal ligand nanoparticle that has the characteristic of absorbing the anionic contaminant, wherein the metal ligand nanoparticle is Zr, wherein the metal ligand nanoparticle comprises a HPO 4   2−  ligand.   
     
     
         14 . The system of  claim 13 , wherein the anionic contaminant is a phosphate. 
     
     
         15 . The system of  claim 13 , wherein the anionic contaminant is an arsenate. 
     
     
         16 . A system for filtering a fluid to remove an anionic contaminant from a fluid comprising:
 a device including a filter, wherein the device is configured to flow the fluid through the filter to remove the anionic contaminant from the fluid, wherein the anionic contaminant is selected from a group consisting of: a phosphate, an arsenate, and a combination thereof, wherein the device is selected from the group consisting of: a down flow filtering device, a static filtering device, a fixed-media filtering device, an up flow filtering device, a fluidized-bed filtering device, a plug-flow batch filtering device, an agitated batch filtering device, a continuous stirred tank filtering device, a centrifugation filtering device, and a combination thereof,   wherein the filter configured to receive the fluid and filter the fluid comprises a metal ligand nanoparticle that has the characteristic of absorbing the anionic contaminant, wherein the metal ligand nanoparticle is Zr, a ligand selected from the group consisting of: (O 3 P—R—PO 3 ) 4− , (O 3 PO—ROPO 3 ) 4− , and a combination thereof, where R=CH 2 , C 2 H 4 , C 3 H 6 , C 2 H 40 , or C 6 H 4 .   
     
     
         17 . The system of  claim 16 , wherein the anionic contaminant is a phosphate. 
     
     
         18 . The system of  claim 16 , wherein the anionic contaminant is an arsenate.

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