US2019249285A1PendingUtilityA1

Thin sheets made of an aluminum-magnesium-scandium alloy for aerospace applications

64
Assignee: CONSTELLIUM ISSOIREPriority: Oct 17, 2016Filed: Oct 17, 2017Published: Aug 15, 2019
Est. expiryOct 17, 2036(~10.3 yrs left)· nominal 20-yr term from priority
C22C 21/06C22F 1/047
64
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Claims

Abstract

The invention relates to a method for producing a wrought product made of an aluminum alloy composed, in wt %, of Mg: 3.8-4.2; Mn: 0.3-0.8 and preferably 0.5-0.7; Sc: 0.1-0.3; Zn: 0.1-0.4; Ti: 0.01-0.05; Zr: 0.07-0.15; Cr: <0.01; Fe: <0.15; Si<0.1; wherein the homogenization is carried out at a temperature of between 370° C. and 450° C., for between 2 and 50 hours, such that the equivalent time at 400° C. is between 5 and 100 hours, and the hot deformation is carried out at an initial temperature of between 350° C. and 450° C. The invention also relates to hot-worked products obtained by the method according to the invention, in particular sheets with a thickness of less than 12 mm. The products according to the invention are advantageous as they offer a better compromise in terms of mechanical strength, toughness and hot-formability.

Claims

exact text as granted — not AI-modified
1 . Method for producing a wrought product made of an aluminum alloy comprising:
 a) Producing a molten metal bath having an aluminum base, comprising, in wt %,
 Mg: 3.8-4.2; 
 Mn: 0.3-0.8 and optionally 0.5-0.7; 
 Sc: 0.1-0.3; 
 Zn: 0.1-0.4; 
 Ti: 0.01-0.05 and optionally 0.015-0.030; 
 Zr: 0.07-0.15 and optionally 0.08-0.12; 
 Cr: <0.01; 
 Fe: <0.15; 
 Si<0.1; 
 other elements <0.05 each and <0.15 combined, the remainder being aluminum; 
   b) Casting an unwrought product from said metal bath;   c) Homogenizing said unwrought product at a temperature that lies in the range 370° C. to 450° C., for a duration that lies in the range 2 to 50 hours such that the equivalent time at 400° C. lies in a range 5 to 100 hours,
 the equivalent time t(eq) at 400° C. being defined by formula: 
   
       
         
           
             
               
                 t 
                  
                 
                   ( 
                   eq 
                   ) 
                 
               
               = 
               
                 
                   ∫ 
                   
                     
                       exp 
                        
                       
                         ( 
                         
                           
                             - 
                             29122 
                           
                           / 
                           T 
                         
                         ) 
                       
                     
                      
                     dt 
                   
                 
                 
                   exp 
                    
                   
                     ( 
                     
                       
                         - 
                         29122 
                       
                       / 
                       
                         T 
                         ref 
                       
                     
                     ) 
                   
                 
               
             
           
         
         
           where T is the current temperature expressed in Kelvin, which changes over time t (in hours) and Tref is a reference temperature of 400° C. (673 K), t(eq) being expressed in hours, the constant Q/R=29122 K being derived from the activation energy for the diffusion of Zr, Q=242000 J/mol, 
         
         d) Hot-working the unwrought product thus homogenized is hot worked with an initial temperature in the range 350° C. to 450° C. and is optionally cold-worked; 
         e) a flattening and/or straightening process is optionally carried out; 
         f) an annealing process is optionally carried out at a temperature that lies in the range 300° C. to 350° C. 
       
     
     
         2 . Method according to  claim 1 , wherein the homogenization duration lies in a range 5 to 30 hours. 
     
     
         3 . Method according to  claim 1 , wherein working is carried out by rolling in order to obtain a sheet metal and wherein a final thickness of a sheet obtained is less than 12 mm. 
     
     
         4 . Method according to  claim 1 , wherein working is carried out by extrusion in order to obtain a profile. 
     
     
         5 . Wrought product made of an aluminum alloy having the composition, in wt %,
 Mg: 3.8-4.2;   Mn: 0.3-0.8 and optionally 0.5-0.7;   Sc: 0.1-0.3;   Zn: 0.1-0.4;   Ti: 0.01-0.05 and optionally 0.015-0.030;   Zr: 0.07-0.15 and optionally 0.08-0.12;   Cr: <0.01;   Fe: <0.15;   Si<0.1;   other elements <0.05 each and <0.15 combined, the remainder being aluminum, obtainable by the method according to  claim 1 .   
     
     
         6 . Wrought product in the form of a sheet having a thickness of less than 12 mm, obtainable by the method according to  claim 3 , wherein
 (a) the tensile yield stress thereof measured at 0.2% elongation in the LT direction of at least 250 MPa, and optionally of at least 260 MPa and/or   (b) the tensile yield stress thereof measured at 0.2% elongation in the L direction of at least 260 MPa, and optionally of at least 270 MPa.   
     
     
         7 . Wrought Product in the form of a Sheet according to  claim 6 , wherein
 (c) the toughness K R 60 thereof, measured on specimens of type CCT760 in the L-T direction (where 2ao=253 mm), for an effective crack growth Δa eff  of 60 mm, of at least 155 MPa √{square root over (m)} , and optionally of at least 165 MPa √{square root over (m)}  and/or   (d) the toughness K R 60 thereof, measured on specimens of type CCT760 in the T-L direction (where 2ao=253 mm), for an effective crack growth Δa eff  of 60 mm, of at least 160 MPa √{square root over (m)} , and optionally of at least 170 MPa √{square root over (m)} .   
     
     
         8 . Method according to  claim 1 , wherein, at the end of f, forming is carried out at a temperature that lies in the range 300° C. to 350° C. 
     
     
         9 . Aircraft fuselage element obtainable according to the method according to  claim 8 , wherein
 (a) the tensile yield stress thereof measured at 0.2% elongation in the LT direction of at least 250 MPa, and optionally of at least 260 MPa and/or   (b) the tensile yield stress thereof measured at 0.2% elongation in the L direction of at least 260 MPa, and optionally of at least 270 MPa.

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