US2019359358A1PendingUtilityA1

Method for filling particulate water absorbing agent and method for sampling filled particulate water absorbing agent

Assignee: NIPPON CATALYTIC CHEM INDPriority: Sep 30, 2013Filed: Aug 6, 2019Published: Nov 28, 2019
Est. expirySep 30, 2033(~7.2 yrs left)· nominal 20-yr term from priority
B01J 20/28011B65B 1/06B01J 2220/68G01N 1/04B65B 1/22B01J 20/267B01J 20/28016
71
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Claims

Abstract

An object of the invention is to provide a technique in which a decrease in physical properties is suppressed or consumer complaints are diminished. A method for filling a particulate water absorbing agent includes a filling step of filling a particulate water absorbing agent into a filling container and a vibrating step of vibrating the filling container at the outside of the filling container, the vibrating step being conducted at least one time between the start and the end of the filling step, in which a vibration condition in the vibrating step satisfies the following conditions (a) and (b): (a) vibration by a vibrating body in contact with the filling container has a vertical directional component and a vibrational angle is within 90°±30°; and (b) total amplitude at no load and a vibration frequency at no load of the vibrating body are set so as to satisfy Equation 1-1 and Equation 2 or Equation 1-2 and Equation 2.

Claims

exact text as granted — not AI-modified
1 . A method for filling a particulate water absorbing agent, the method comprising:
 a filling step of filling a particulate water absorbing agent into a filling container; and   a vibrating step of vibrating the filling container at the outside of the filling container, the vibrating step being conducted at least one time between the start and the end of the filling step, wherein   a vibration condition in the vibrating step satisfies the following conditions (a) and (b):   (a) vibration by a vibrating body in contact with the filling container has a vertical directional component and a vibrational angle is within 90°±30°; and   (b) total amplitude at no load and a vibration frequency at no load of the vibrating body are set such that the following Equation 1-1 and Equation 2 or Equation 1-2 and Equation 2 are satisfied;
   [Mathematical Formula 1] 
   1≤acceleration (G)≤13 in a case in which final filling amount of particulate water absorbing agent per filling container: W2≥100 kg   (Equation 1-1)
 
   1≤acceleration (G)≤15 in a case in which final filling amount of particulate water absorbing agent per filling container: W2<100 kg   (Equation 1-2)
 
   [Mathematical Formula 2] 
   27.0≤vibration index≤44.0   (Equation 2)
 
   Incidentally, the acceleration and the vibration index are values calculated by the following Equation 3 and Equation 4, respectively;   
       
         
           
             
               
                 
                   
                     [ 
                     
                       Mathematical 
                        
                       
                           
                       
                        
                       Formula 
                        
                       
                           
                       
                        
                       3 
                     
                     ] 
                   
                 
                 
                   
                       
                   
                 
               
               
                 
                   
                     
                       Acceleration 
                        
                       
                           
                       
                       [ 
                       G 
                       ] 
                     
                     = 
                     
                       
                         
                           
                             
                               total 
                                
                               
                                   
                               
                                
                               amplitude 
                                
                               
                                   
                               
                                
                               at 
                                
                               
                                   
                               
                                
                               no 
                                
                               
                                   
                               
                                
                               
                                 load 
                                  
                                 
                                     
                                 
                                 [ 
                                 mm 
                                 ] 
                               
                               × 
                             
                           
                         
                         
                           
                             
                               
                                 ( 
                                 
                                   2 
                                    
                                   π 
                                   × 
                                   vibration 
                                    
                                   
                                       
                                   
                                    
                                   frequency 
                                    
                                   
                                       
                                   
                                    
                                   at 
                                    
                                   
                                       
                                   
                                    
                                   no 
                                    
                                   
                                       
                                   
                                    
                                   
                                     load 
                                      
                                     
                                         
                                     
                                     [ 
                                     Hz 
                                     ] 
                                   
                                 
                                 ) 
                               
                               2 
                             
                           
                         
                       
                       
                         2 
                         × 
                         1000 
                         × 
                         9.8 
                       
                     
                   
                 
                 
                   
                     ( 
                     
                       Equation 
                        
                       
                           
                       
                        
                       3 
                     
                     ) 
                   
                 
               
               
                 
                   
                     [ 
                     
                       Mathematical 
                        
                       
                           
                       
                        
                       Formula 
                        
                       
                           
                       
                        
                       4 
                     
                     ] 
                   
                 
                 
                   
                       
                   
                 
               
               
                 
                   
                     
                       Vibration 
                        
                       
                           
                       
                        
                       index 
                     
                     = 
                     
                       
                         
                           42 
                           · 
                           0.29 
                         
                         × 
                         vibration 
                          
                         
                             
                         
                          
                         frequency 
                          
                         
                             
                         
                          
                         at 
                          
                         
                             
                         
                          
                         no 
                          
                         
                             
                         
                          
                         
                           load 
                            
                           
                               
                           
                           [ 
                           Hz 
                           ] 
                         
                       
                       + 
                       
                         1.24 
                         × 
                         
                           
                             acceleration 
                              
                             
                                 
                             
                             [ 
                             G 
                             ] 
                           
                           . 
                         
                       
                     
                   
                 
                 
                   
                     ( 
                     
                       Equation 
                        
                       
                           
                       
                        
                       4 
                     
                     ) 
                   
                 
               
             
           
         
       
     
     
         2 . The filling method according to  claim 1 , wherein the acceleration is 10 G or less. 
     
     
         3 . The filling method according to  claim 1 , wherein the vibrating step is carried out when W1/W2=10% by weight to 100% by weight where a ratio of a rilling amount W1 of the particulate water absorbing agent to a final filling amount W2 of the particulate water absorbing agent is expressed as W1/W2. 
     
     
         4 . The filling method according to  claim 1 , wherein a vibration frequency at no load of the vibrating body is from 10 Hz to 90 Hz. 
     
     
         5 . The filling method according to  claim 1 , wherein a relative humidity in a space portion within 30 cm from a particulate water absorbing agent surface is from 30% RH to 65% RH. 
     
     
         6 . The billing method according to  claim 1 , wherein the pallet is a replaceable plate-like body having a mass of from 5 kg to 50 kg per 1 t of the particulate water absorbing agent. 
     
     
         7 . The filling method according to  claim 1 , wherein the W2 is 20000 kg or less in Equation 1-1 above. 
     
     
         8 . The filling method according to  claim 1 , wherein a temperature of the particulate water absorbing agent in the vibrating step is from 30° C. to 70° C. 
     
     
         9 . The filling method according to  claim 1 , wherein the particulate water absorbing agent is constituted by containing a water absorbent resin, the water absorbent resin having an irregular crushed shape. 
     
     
         10 . The filling method according to  claim 1 , wherein a bulk specific gravity of the particulate water absorbing agent is from 0.50 (g/ml) to 0.70 (g/ml). 
     
     
         11 . The filling method according to  claim 1 , wherein the particulate water absorbing agent is obtained by a production method including a step of belt polymerization. 
     
     
         12 . The filling method according to  claim 1 , wherein a vibrational direction is adjusted by disposing a plurality of unbalanced mass-type vibration generators used for generation of vibration so as to cancel amplitude in a horizontal direction. 
     
     
         13 . A filled particulate water absorbing agent filled by the filling method according to  claim 1 . 
     
     
         14 . A storage method or a transport method of the filled particulate water absorbing agent according to  claim 13 . 
     
     
         15 . An absorbent article comprising a particulate water absorbing agent subdivided at from 1 g to 100 g from the filled particulate water absorbing agent according to  claim 13 . 
     
     
         16 . A method for manufacturing an absorbent article, the method comprising a step of preparing the filled particulate water absorbing agent according to  claim 13 .

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