Cathode, all-solid-state battery and methods for producing them

Abstract

Provided is a cathode that is configured to decrease battery resistance when it is used in an all-solid-state battery, and a method for producing the cathode. Disclosed is a cathode comprising a cathode layer for all-solid-state batteries, wherein the cathode layer contains cathode active material particles and solid electrolyte particles; wherein at least one of the cathode active material particles and the solid electrolyte particles contain a phosphorus element; and wherein, in a photoelectron spectrum by X-ray photoelectron spectroscopy measurement of the cathode layer, a P peak intensity ratio (A/B), which is derived from the phosphorus element, of a signal intensity A at a binding energy of 131.6 eV to a signal intensity B at a binding energy of 133.1 eV, is larger than 0.58.

1 . A cathode comprising a cathode layer for all-solid-state batteries,
 wherein the cathode layer contains cathode active material particles and solid electrolyte particles;   wherein at least one of the cathode active material particles and the solid electrolyte particles contain a phosphorus element; and   wherein, in a photoelectron spectrum by X-ray photoelectron spectroscopy measurement of the cathode layer, a P peak intensity ratio (A/B), which is derived from the phosphorus element, of a signal intensity A at a binding energy of 131.6 eV to a signal intensity B at a binding energy of 133.1 eV, is larger than 0.58.   
     
     
         2 . The cathode according to  claim 1 , wherein the cathode layer contains composite active material particles comprising the cathode active material particles and a lithium ion conducting oxide, the lithium ion conducting oxide coating at least part of the surface of the cathode active material particles. 
     
     
         3 . The cathode according to  claim 2 , wherein the lithium ion conducting oxide is at least one selected from the group consisting of lithium niobate, lithium titanate, lithium lanthanum zirconate, lithium tantalate and lithium tungstate. 
     
     
         4 . The cathode according to  claim 1 , wherein the solid electrolyte particles are sulfide-based solid electrolyte particles. 
     
     
         5 . The cathode according to  claim 1 , wherein a moisture content of the cathode active material particles is 70 ppm or less. 
     
     
         6 . An all-solid-state battery comprising:
 a cathode comprising a cathode layer,   an anode comprising an anode layer, and   a solid electrolyte layer disposed between the cathode layer and the anode layer,   wherein the cathode is the cathode defined by  claim 1 .   
     
     
         7 . A method for producing a cathode comprising a cathode layer for all-solid-state batteries, the method comprising:
 preparing cathode active material particles;   vacuum-drying the cathode active material particles at a temperature of 120° C. or more and 300° C. or less for one hour or more;   mixing the cathode active material particles with solid electrolyte particles to obtain a cathode mix; and   forming the cathode mix to obtain the cathode layer,   wherein at least one of the cathode active material particles and the solid electrolyte particles contain a phosphorus element, and   wherein, in a photoelectron spectrum by a X-ray photoelectron spectroscopy measurement of the cathode layer, a P peak intensity ratio (A/B), which is derived from the phosphorus element, of a signal intensity A at a binding energy of 131.6 eV to a signal intensity B at a binding energy of 133.1 eV, is larger than 0.58.   
     
     
         8 . The method for producing the cathode according to  claim 7 , wherein, in the preparing, composite active material particles comprising the cathode active material particles and a lithium ion conducting oxide, the lithium ion conducting oxide coating at least part of the surface of the cathode active material particles, are prepared. 
     
     
         9 . The method for producing the cathode according to  claim 8 , wherein, in the preparing, a precursor of the composite active material particles is obtained by drying, on the surface of the cathode active material particles, a peroxo complex aqueous solution containing an element that will compose the lithium ion conducting oxide, and the composite active material particles are obtained by sintering the precursor. 
     
     
         10 . The method for producing the cathode according to  claim 7 , wherein the solid electrolyte particles are sulfide-based solid electrolyte particles. 
     
     
         11 . A method for producing an all-solid-state battery comprising:
 a cathode comprising a cathode layer,   an anode comprising an anode layer, and   a solid electrolyte layer disposed between the cathode layer and the anode layer,   wherein the cathode is a cathode produced by the production method defined by  claim 7 .