Polymer Plastic Front Plate And Method For Manufacturing The Same

Abstract

A polymer plastic front plate comprises: a plastic substrate and a hard coating layer formed on an adhesion surface of the plastic substrate. The hard coating layer comprises: organic-inorganic hybrid UV oligomer, high Tg UV resin additive, a plurality of dispersed flaky nano inorganic material, and photo initiator, so as to form a gas barrier hard coating layer with high surface dyne value (>44 dyne) on the adhesion surface of the plastic substrate. It not only has good ink printability and OCA adhesiveness, but also inhibits the diffusion of fugitive gas from polymer plastic front plates during high-temperature, high-temperature and high-humidity, high-low temperature thermal shocks and other harsh automotive industry environmental tests. The gas can be avoided from entering the OCA layer, thereby solving the problems of bubbles and delamination after the environmental tests are performed.

What is claimed is: 
     
         1 . A polymer plastic front plate for bonding on a touch panel, comprising:
 a plastic substrate, having an operation surface and a bonding surface;   a protective layer, furnished on the operation surface; and   a hard coating layer, furnished on the bonding surface;   characterized by that:   said hard coating layer comprising: a first weight percentage of organic-inorganic hybrid UV-curable oligomer, a second weight percentage of UV-curable resin additives with high glass transition temperature (Tg) value, a plurality of dispersed nano-scale flaky inorganic substances, and a photo initiator; wherein, the plurality of dispersed nano-scale flaky inorganic substances are arranged in a randomly distributed horizontal direction in the hard coating layer to form a discontinuously layered dispersed gas barrier layer in the hard coating layer.   
     
     
         2 . The polymer plastic front plate of  claim 1 , wherein the organic-inorganic hybrid UV-curable oligomer includes a polyurethane resin and a sol-gel silica hybrid mixture. 
     
     
         3 . The polymer plastic front plate of  claim 1 , wherein the glass transition temperature (Tg) value of the UV-curable resin additives is not less than 120° C. ; in addition, the UV-curable resin additives contain at least one of the following: UV-curable oligomer with high glass transition temperature (high Tg UV oligomer) and UV-curable monomer with high glass transition temperature (high Tg UV monomer). 
     
     
         4 . The polymer plastic front plate of  claim 3 , wherein the UV-curable oligomer with high glass transition temperature is polyurethane acrylate, which has a glass transition temperature (Tg) value not less than 120° C.; in addition, the UV-curable monomer with high glass transition temperature is Tris(2-hydroxy ethyl) isocyanuratetriacrylate (THEICTA), which has a glass transition temperature (Tg) value not less than 240° C. . 
     
     
         5 . The polymer plastic front plate of  claim 1 , wherein the nano-scale flaky inorganic substances are composed of at least one of the following materials: SiO 2 , Al 2 O 3 , Si 3 N 4 , SiO x N y , and AlO x N y . 
     
     
         6 . The polymer plastic front plate of  claim 1 , wherein each of the nano-scale flaky inorganic substances has a thickness (t), a longitudinal width (w 1 ) and a lateral width (w 2 ); wherein, the measuring directions of the thickness (t), the longitudinal width (w 1 ) and the lateral width (w 2 ) are perpendicular to each other, and w 1  w 2  wherein, the thickness (t) is between 0.1 nm and 50 nm, the longitudinal width (w 1 ) is between 100 nm and 1000 nm, and the ratio of the lateral width to the longitudinal width (w 2 /w 1 ) is between 0.01 and 1. 
     
     
         7 . The polymer plastic front plate of  claim 6 , wherein 10 nm≤t≤30 nm, 300 nm≤w 1 ≤800 nm, and 0.1≤(w 2 /w 1 )≤1. 
     
     
         8 . The polymer plastic front plate of  claim 1 , wherein the value of the first weight percentage is ranged between 50% and 70%, the value of the second weight percentage is ranged between 30% and 50%, and the value of the weight percentage of the nano-scale flaky inorganic substances in the hard coating layer is between 5% and 15%. 
     
     
         9 . The polymer plastic front plate of  claim 1 , wherein the plastic substrate is one of the following: polymethyl methacrylate (PMMA) plate, polycarbonate (PC) plate, PMMA/PC double-layer composite plate, and PMMA/PC/PMMA three-layer composite plate; in addition, the surface of the hard coating layer can be applied with an ink layer and an optical clear adhesive (OCA) layer for attaching to the surface of the touch panel. 
     
     
         10 . A method for manufacturing a polymer plastic front plate, comprising:
 Step (A): providing a plastic substrate and a coating material; the plastic substrate having a bonding surface; said coating material including: a first weight percentage of organic-inorganic hybrid UV-curable oligomer, a second weight percentage of UV-curable resin additives with high glass transition temperature (Tg) value, a plurality of dispersed nano-scale flaky inorganic substances, and a photo initiator;   Step (B): applying the coating material onto the bonding surface of the plastic substrate;   Step (C): curing the coating material to form a hard coating layer on the bonding surface of the plastic substrate; wherein, during the curing process, the plurality of dispersed nano-scale flaky inorganic substances will be affected by the gravity and hydrodynamics, and randomly dispersed and arranged along a horizontal direction in a parallel manner within the hard coating layer, such that the plurality of dispersed nano-scale flaky inorganic substances can form a discontinuously layered dispersed gas barrier layer in the hard coating layer.   
     
     
         11 . The method for manufacturing a polymer plastic front plate of  claim 10 , wherein the process for providing the coating material described in Step (A) comprises the following steps:
 Step (A1): forming an inorganic layer on a carrier plate;   Step (A2): detaching and braking the inorganic layer into a plurality of tiny inorganic fragments;   Step (A3): smoothing and dispersing the plurality of tiny inorganic fragments in order to transform the plurality of tiny inorganic fragments into the plurality of dispersed nano-scale flaky inorganic substances; and   Step (A4): adding and mixing the plurality of dispersed nano-scale flaky inorganic substances into a solution of the organic-inorganic hybrid UV-curable oligomer, the UV-curable resin additive and the photo initiator to form the coating material.   
     
     
         12 . The method for manufacturing a polymer plastic front plate of  claim 11 , wherein:
 in Step (A1), the carrier plate is a glass carrier plate, and a release film is provided on a surface of the glass carrier plate; an inorganic material is plated on the release film by a vacuum sputtering process in order to form a whole piece of the inorganic layer on the surface of the release film;   in Step (A2), the inorganic layer is broken by shaking, vibrating or striking the carrier plate, such that the broken inorganic layer can be detached from the release film of the carrier plate and be broken into the plurality of tiny inorganic fragments;   in Step (A3), the plurality of tiny inorganic fragments are mixed and stirred by a nano dispersion equipment, so that the plurality of tiny inorganic fragments can collide with each other to gradually smooth their sharp edges and also disperse them evenly and individually, so as to form the plurality of dispersed nano-scale flaky inorganic substances.   
     
     
         13 . The method for manufacturing a polymer plastic front plate of  claim 10 , wherein the organic-inorganic hybrid UV-curable oligomer includes a polyurethane resin and a sol-gel silica hybrid mixture. 
     
     
         14 . The method for manufacturing a polymer plastic front plate of  claim 10 , wherein the glass transition temperature (Tg) value of the UV-curable resin additives is not less than 120° C.; in addition, the UV-curable resin additives contain at least one of the following: UV-curable oligomer with high glass transition temperature (high Tg UV oligomer) and UV-curable monomer with high glass transition temperature (high Tg UV monomer). 
     
     
         15 . The method for manufacturing a polymer plastic front plate of  claim 14 , wherein the UV-curable oligomer with high glass transition temperature is polyurethane acrylate, which has a glass transition temperature (Tg) value not less than 120° C. ; in addition, the UV-curable monomer with high glass transition temperature is Tris(2-hydroxy ethyl) isocyanuratetriacrylate (THEICTA), which has a glass transition temperature (Tg) value not less than 240° C. 
     
     
         16 . The method for manufacturing a polymer plastic front plate of  claim 10 , wherein the nano-scale flaky inorganic substances are composed of at least one of the following materials: SiO 2 , Al 2 O 3 , Si 3 N 4 , SiO x N y , and AlO x N y . 
     
     
         17 . The method for manufacturing a polymer plastic front plate of  claim 10 , wherein each of the nano-scale flaky inorganic substances has a thickness (t), a longitudinal width (w 1 ) and a lateral width (w 2 ); wherein, the measuring directions of the thickness (t), the longitudinal width (w 1 ) and the lateral width (w 2 ) are perpendicular to each other, and w 1 ≥w 2 ≥t; wherein, the thickness (t) is between 0.1 nm and 50 nm, the longitudinal width (w 1 ) is between 100 nm and 1000 nm, and the ratio of the lateral width to the longitudinal width (w 2 /w 1 ) is between 0.01 and 1. 
     
     
         18 . The method for manufacturing a polymer plastic front plate of  claim 17 , wherein 100 nm≤t≤30 nm, 300 nm≤w 1 ≤800 nm, and 0.1≤(w 2 /w 1 )≤1. 
     
     
         19 . The method for manufacturing a polymer plastic front plate of  claim 10 , wherein the value of the first weight percentage is ranged between 50% and 70%, the value of the second weight percentage is ranged between 30% and 50%, and the value of the weight percentage of the nano-scale flaky inorganic substances in the hard coating layer is between 5% and 15%. 
     
     
         20 . The method for manufacturing a polymer plastic front plate of  claim 10 , wherein the plastic substrate is one of the following: polymethyl methacrylate (PMMA) plate, polycarbonate (PC) plate, PMMA/PC double-layer composite plate, and PMMA/PC/PMMA three-layer composite plate; in addition, the surface of the hard coating layer can be applied with an ink layer and an optical clear adhesive (OCA) layer for attaching to the surface of the touch panel.