Wet Press Concrete Slab and Admixtures For Their Manufacture

Abstract

The present invention provides a wet press process and admixture components for making concrete slabs (flags), curb (kerb) units, panels, boards, and other flat shapes, whereby colloidal silica and at least one alkanolamine and optional rheology control components are employed to provide an ideal combination of pressing time, green strength, surface definition, stack-ability, final concrete strength, and permeability. Stack-ability can be expressed in terms of minimum deflection or non-eccentricity of the units while standing on thickness edges at distances apart less than width or standing height. A wet press process typically involves introducing a highly fluid concrete mix into a mold, applying hydraulic pressure to consolidate the concrete (e.g., 1000-3000 PSI) and to extract excess water, removing the pressed concrete while in a green state from the mold, and then standing the slab units immediately upon removal from the mold while in a green state, on an edge adjacent to but spaced apart from other edge-standing units. In further embodiments, rounded aggregates such as naturally occurring sand and/or gravel obtained from local sources can be incorporated into the concrete slabs without defeating (vertical) stack-ability in the green state.

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         14 . A concrete unit made from wet press process manufacturing, comprising:
 introducing, into a concrete mold having a plurality of corners to define transverse edges of a molded unit, a concrete mixture comprising (a) a hydratable cement binder, (b) aggregates comprising sand, crushed gravel, or mixture thereof, and (c) water in an amount sufficient (i) to hydrate the cement binder and (ii) to enable the mixture to flow into corners within the mold;   wet-pressing the concrete mixture within the mold, using hydraulic pressure of 400 to 3000 pounds per square inch, to consolidate the mixture into a shape having at least two edges defining therebetween a width dimension and at least two edges defining therebetween a thickness dimension, wherein the width dimension is at least five times greater than the thickness dimension, and removing excess water from the concrete mixture while in the mold;   removing the wet-pressed concrete from the mold while in a green state;   standing the wet-pressed, green state concrete unit, upon removal from the mold, onto the at least two edges which define the thickness dimension of the concrete unit: and   repeating the foregoing steps such that at least three standing wet-pressed, green state concrete units removed from molds are standing, during a curing period, adjacent to each other at a distance apart which is less than their individual width dimension:   wherein the concrete mixture introduced into and removed from the mold further comprises: (a) colloidal silica having silica particles with an average particle size of 1 nm (nanometer) to 100 nm (nanometer), the colloidal silica comprising a monosperse or multisperse suspension of silica particles having generally spherical shapes and having specific surface area (SSA) of 10-1500 square meters per gram (m 2 /g SiO 2 ); (b) at least one alkanolamine; and (c) optionally, a rheology modifying agent; wherein the colloidal silica and at least one alkanolamine are effective to increase green strength of the wet-pressed, green state concrete units as well as flexural strength of the demolded concrete units.   
     
     
         15 . An admixture composition comprising (a) colloidal silica having silica particles with an average particle size of 2 to 25 nanometers (nm); (b) at least one alkanolamine; and (c) optionally, a rheology modifying agent. 
     
     
         16 . The admixture composition of  claim 15  wherein said at least one alkanolamine is selected from tetrahydroxyethylethylenediamine, triisopropanolamine, methyldiethanolamine, or mixture thereof, optionally with triethanolamine. 
     
     
         17 . A concrete mix for making wet press concrete units, comprising: a cement binder, aggregates, and the admixture composition of  claim 15 . 
     
     
         18 . The concrete mix of  claim 15  wherein the aggregates comprise particles having rounded shapes. 
     
     
         19 . The concrete unit according to  claim 14  wherein the at least one alkanolamine is selected from tetrahydroxyethylethylenediamine, triisopropanolamine, methyldiethanola mine, or mixture thereof. 
     
     
         20 . The concrete unit according to  claim 14  wherein the at least one alkanolamine of component (b) further comprises triethanolamine. 
     
     
         21 . The concrete unit according to  claim 14  wherein the at least one alkanolamine of component (b) comprises triisopropanolamine and triethanolamine. 
     
     
         22 . The concrete unit according to  claim 14  wherein at least one alkanolamine of component (b) comprises tetrahydroxyethylethylenediamine and triethanolamine. 
     
     
         23 . The concrete unit according to  claim 14  wherein the colloidal silica is a monosperse or multisperse suspension of silica particles having generally spherical shapes and having specific surface area (SSA) of 10-1500 square meters per gram (m 2 /g SiO 2 ). 
     
     
         24 . The concrete unit according to  claim 14  wherein the colloidal silica has SSA of 100-500 square meters per gram (m 2 /g SiO 2 ). 
     
     
         25 . The concrete unit according to  claim 14  wherein the concrete mix further comprises a rheology modifying agent selected from the group consisting of a polycarboxylate type rheology modifying agent; and a biopolymer polysaccharide selected from diutan gum, welan gum, xanthan gum, or a mixture thereof. 
     
     
         26 . The concrete unit according to  claim 23  wherein the rheology modifying agent is a polycarboxylate type. 
     
     
         27 . The concrete unit according to  claim 14  wherein the concrete mix further comprises a rheology modifying agent, a surfactant, a flocculent, a set accelerating agent, a hydration control agent, a defoamer, a biocide, or a mixture thereof. 
     
     
         28 . The concrete unit according to  claim 14  wherein the aggregate contains rounded particles. 
     
     
         29 . The admixture composition of  claim 15  further comprising a rheology modifying agent selected from the group consisting of a polycarboxylate type rheology modifying agent; and a biopolymer polysaccharide selected from diutan gum, welan gum, xanthan gum, or a mixture thereof.