US2020222442A1PendingUtilityA1

2'-substituted-n6-substituted purine nucleotides for rna virus treatment

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Assignee: ATEA PHARMACEUTICALS INCPriority: Sep 7, 2016Filed: Mar 17, 2020Published: Jul 16, 2020
Est. expirySep 7, 2036(~10.2 yrs left)· nominal 20-yr term from priority
C07H 19/20C07H 19/16A61P 31/14A61K 31/7076C07H 23/00C07H 19/207Y02A50/30A61P 1/00A61K 31/675A61K 9/0043
66
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Claims

Abstract

The use of described compounds or pharmaceutically acceptable salts or compositions thereof for the treatment of a host infected with an RNA virus other than HCV, or other disorder more fully described herein.

Claims

exact text as granted — not AI-modified
We claim: 
     
         1 . A method to treat or prevent a Coronaviridae viral infection in a human in need thereof comprising administering an effective amount of a compound of the formula: 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof, optionally in a pharmaceutically acceptable carrier, 
         wherein
 R 1  is C 1 -C 5 alkyl, —(C 0 -C 2 alkyl)(C 3 -C 6 cycloalkyl), or —C(O)R 3C ; 
 R 3C  is alkyl; 
 R 7  is hydrogen, C 1-6 alkyl, C 3-7 cycloalkyl, heteroaryl, heterocyclyl, or aryl; 
 R 8  is hydrogen or C 1-6 alkyl; 
 R 9a  and R 9b  are independently selected from hydrogen, C 1-6 alkyl, and cycloalkyl; and 
 R 10  is hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 3-7 cycloalkyl, heterocycloalkyl, aminoacyl, aryl, heteroaryl, aryl, or heteroaryl. 
 
       
     
     
         2 . The method of  claim 1 , wherein R 1  is C 1 -C 5 alkyl. 
     
     
         3 . The method of  claim 2 , wherein R 1  is selected from methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl and pentyl. 
     
     
         4 . The method of  claim 3 , wherein R 1  is selected from methyl and ethyl. 
     
     
         5 . The method of  claim 1 , wherein R 1  is —(C 0 -C 2 alkyl)(C 3 -C 6 cycloalkyl). 
     
     
         6 . The method of  claim 5 , wherein R 1  is cyclopropyl. 
     
     
         7 . The method of  claim 1 , wherein R 1  is —C(O)R 3C . 
     
     
         8 . The method of  claim 7 , wherein R 1  is selected from —C(O)CH 3 , —C(O)CH 2 CH 3 —C(O)CH(CH 3 ) 2 , —C(O)OCH 3 , —C(O)OC 2 H 5 , —C(O)OC 3 H 7 , —C(O)OC 4 H 9 , and —C(O)OC 5 H 11 . 
     
     
         9 . The method of  claim 1 , wherein R 7  is phenyl. 
     
     
         10 . The method of  claim 1 , wherein R 7  is napthyl. 
     
     
         11 . The method of  claim 1 , wherein R 8  is hydrogen. 
     
     
         12 . The method of  claim 1 , wherein R 9a  is methyl and R 9b  is hydrogen. 
     
     
         13 . The method of  claim 1 , wherein R 10  is methyl, ethyl, or iso-propyl. 
     
     
         14 . The method of  claim 13 , wherein R 10  is isopropyl. 
     
     
         15 . The method of  claim 1 ,
 wherein   R 7  is aryl;   R 8  is hydrogen;   R 9a  and R 9b  are independently selected from methyl and hydrogen; and   R 10  is alkyl.   
     
     
         16 . The method of  claim 15 ,
 wherein   R 7  is phenyl;   R 8  is hydrogen;   R 9a  and R 9b  are independently selected from methyl and hydrogen; and   R 10  is isopropyl.   
     
     
         17 . The method of  claim 1 , wherein the Coronaviridae viral infection is a virus of the genus Alphacoronavirus. 
     
     
         18 . The method of  claim 1 , wherein the Coronaviridae viral infection is a virus of the genus Betacoronavirus. 
     
     
         19 . The method of  claim 1 , wherein the Coronaviridae viral infection is a virus of the genus Gammacoronavirus. 
     
     
         20 . The method of  claim 1 , wherein the Coronaviridae viral infection is a virus of the genuses Deltacoronavirus. 
     
     
         21 . The method of  claim 1 , wherein the compound is administered in a dosage form suitable for oral administration. 
     
     
         22 . The method of  claim 21 , wherein the dosage form is a solid oral dosage form. 
     
     
         23 . The method of  claim 22 , wherein the solid oral dosage form is a tablet or capsule. 
     
     
         24 . The method of  claim 21 , wherein the dosage form is a liquid oral dosage form. 
     
     
         25 . The method of  claim 24 , wherein the liquid oral dosage form is a solution or a suspension. 
     
     
         26 . The method of  claim 1 , wherein the compound is administered in a dosage form suitable for intravenous administration. 
     
     
         27 . The method of  claim 1 , wherein the compound is administered in a dosage form suitable for parenteral administration. 
     
     
         28 . The method of  claim 1  comprising administering an effective amount of a compound of the formula: 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof. 
       
     
     
         29 . The method of  claim 28 , comprising administering an effective amount of a compound of the formula 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof. 
       
     
     
         30 . The method of  claim 28 , comprising administering an effective amount of a compound 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof. 
       
     
     
         31 . The method of  claim 28 , wherein the Coronaviridae viral infection is a virus of the genus Alphacoronavirus. 
     
     
         32 . The method of  claim 28 , wherein the Coronaviridae viral infection is a virus of the genus Betacoronavirus. 
     
     
         33 . The method of  claim 28 , wherein the Coronaviridae viral infection is a virus of the genus Gammacoronavirus. 
     
     
         34 . The method of  claim 28 , wherein the Coronaviridae viral infection is a virus of the genuses Deltacoronavirus. 
     
     
         35 . The method of  claim 28 , wherein the compound is administered in a dosage form suitable for oral administration. 
     
     
         36 . The method of  claim 35 , wherein the dosage form is a solid oral dosage form. 
     
     
         37 . The method of  claim 36 , wherein the solid oral dosage form is a tablet or capsule. 
     
     
         38 . The method of  claim 35 , wherein the dosage form is a liquid oral dosage form. 
     
     
         39 . The method of  claim 38 , wherein the liquid oral dosage form is a solution or a suspension. 
     
     
         40 . The method of  claim 28 , wherein the compound is administered in a dosage form suitable for intravenous administration. 
     
     
         41 . The method of  claim 28 , wherein the compound is administered in a dosage form suitable for parenteral administration. 
     
     
         42 . The method of  claim 1  comprising administering an effective amount of a compound of the formula: 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof. 
       
     
     
         43 . The method of  claim 42 , comprising administering an effective amount of a compound of the formula 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof. 
       
     
     
         44 . The method of  claim 42 , comprising administering an effective amount of a compound 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof. 
       
     
     
         45 . The method of  claim 42 , wherein the Coronaviridae viral infection is a virus of the genuses Alphacoronavirus. 
     
     
         46 . The method of  claim 42 , wherein the Coronaviridae viral infection is a virus of the genuses Betacoronavirus. 
     
     
         47 . The method of  claim 42 , wherein the Coronaviridae viral infection is a virus of the genuses Gammacoronavirus. 
     
     
         48 . The method of  claim 42 , wherein the Coronaviridae viral infection is a virus of the genuses Deltacoronavirus. 
     
     
         49 . The method of  claim 42 , wherein the compound is administered in a dosage form suitable for oral administration. 
     
     
         50 . The method of  claim 49 , wherein the dosage form is a solid oral dosage form. 
     
     
         51 . The method of  claim 50 , wherein the solid oral dosage form is a tablet or capsule. 
     
     
         52 . The method of  claim 49 , wherein the dosage form is a liquid oral dosage form. 
     
     
         53 . The method of  claim 52 , wherein the liquid oral dosage form is a solution or a suspension. 
     
     
         54 . The method of  claim 42 , wherein the compound is administered in a dosage form suitable for intravenous administration. 
     
     
         55 . The method of  claim 42 , wherein the compound is administered in a dosage form suitable for parenteral administration.

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