Tough shrinkable films

Abstract

The present disclosure relates to a shrink film comprising a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (i) about 0.01 to about 26 mole % neopentyl glycol residues; (ii) about less than 10 mole % 1,4-cyclohexanedimethanol residues; (iii) about 50 to 90 mole % ethylene glycol residues; and (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.

What is claimed is: 
     
         1 . A shrink film comprising a polyester composition comprising:
 (1) at least one polyester which comprises:
 (a) a dicarboxylic acid component comprising:
 (i) about 70 to about 100 mole % of terephthalic acid residues; 
 (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and 
 
 (b) a diol component comprising:
 (i) about 0.01 to about 26 mole % neopentyl glycol residues; 
 (ii) about less than 10 mole % 1,4-cyclohexanedimethanol residues; 
 (iii) about 50 to 90 mole % ethylene glycol residues; and 
 (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; 
 
   wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.   
     
     
         2 . The shrink film of  claim 1 , wherein the inherent viscosity of the polyester is from 0.50 to 0.80 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C. 
     
     
         3 . The shrink film of  claim 1 , wherein the polyester has a Tg of from 60° C. to 80° C. as determined using a TA DSC 2920 from Thermal Analyst Instrument at a scan rate of 20° C./min. 
     
     
         4 . The shrink film of  claim 1 , wherein the sum of one or more diol monomer components capable of forming an amorphous component in the final polyester composition is from 20 to 45 mole % wherein the total diol component is 100 mole %. 
     
     
         5 . The shrink film of  claim 1 , wherein the sum of the residues of 1,4-cyclohexanedimethanol and neopentyl glycol in the final polyester composition is from 10 to 40 mole % wherein the total diol component is 100 mole %. 
     
     
         6 . The shrink film of  claim 1 , wherein the ethylene glycol residues are present in an amount of 65 to 75 mole %. 
     
     
         7 . The shrink film of  claim 1 , wherein the diethylene glycol residues are present in an amount of 2 to 12 mole %. 
     
     
         8 . The shrink film of  claim 1 , wherein the diethylene glycol residues are present in an amount of 2 to 9 mole %. 
     
     
         9 . The shrink film of  claim 1 , wherein the 1,4-cyclohexanedimethanol residues are present in an amount of less than 10 mole %, diethylene glycol residues are present in an amount of 2 to 9 mole %, neopentyl glycol residues in an amount of 5 to 25 mole %, and ethylene glycol residues are present in an amount of 65 mole % or greater. 
     
     
         10 . The shrink film of  claim 1 , wherein the 1,4-cyclohexanedimethanol residues are present in an amount of less than 10 mole %, diethylene glycol residues are present in an amount of less than 10 mole %, neopentyl glycol residues in an amount of 10 to 20 mole %, and ethylene glycol residues are present in an amount of greater than 60 mole %. 
     
     
         11 . The shrink film of  claim 1 , wherein the residues of 1,4-butanediol are present in an amount of less than 10 mole %. 
     
     
         12 . The shrink film of  claim 1 , further comprising at least one voiding agent. 
     
     
         13 . The shrink film of  claim 1 , wherein the film is oriented in one or more directions. 
     
     
         14 . The shrink film of  claim 13 , wherein the film has a break strain percentage of 200 to 600% at 500 mm/min as measured according to ASTM Method D882. 
     
     
         15 . The shrink film of  claim 13 , wherein the film has shrinkage in the machine direction of 4% or less when immersed in water at 65 C for 10 seconds; or wherein the film has shrinkage in the transverse direction of 60% or greater when immersed in water at 85° C. for 10 seconds. 
     
     
         16 . The shrink film of  claim 13 , wherein the film has a shrink force of 5 MPa or greater. 
     
     
         17 . The shrink film of  claim 13 , wherein the film has a pre-oriented thickness of about 50 to 400 microns and is oriented on a tenter frame at a ratio of 6.5:1 to 3:1 at a temperature from the Tg of the film to the Tg plus 55° C. to a thickness from about 10 to about 80 microns. 
     
     
         18 . The shrink film of  claim 13 , wherein the film has shrinkage in the transverse direction in the amount of 50 to 90% and shrinkage in the machine direction of 4% or less when immersed in water at 95 C for 10 seconds. 
     
     
         19 . A label or a sleeve applied to an article of manufacture, a shaped article, a container, a plastic bottle, a glass bottle, packaging, a battery, a hot fill container, or an industrial article comprising the shrink film of  claim 1 .