Associative polymers for mist-control

Abstract

Polymeric mist control materials, methods of forming polymeric mist control materials, and methods of using such materials for mist control are provided. The polymeric mist control additives are formed of molecules comprised predominantly of monomers that confer high solubility in fuel and include associative groups that attract each other in donor-acceptor manner, and are incorporated such that multiple associative groups are in close proximity (“clusters”), such that the clusters are separated by very long non-associative sequences.

1 . A material comprising:
 a mixture of polymers each having:
 at least one non-associative chain having a weight average molar mass comprised between 100 to 1000 kg/mol, said non-associative chain being selected to confer solubility to the polymer in a particular medium such that the medium and the material remain as a homogeneous single phase during storage and transport; 
 a plurality of associative groups disposed on at least one end of each of said non-associative chains, wherein the associative groups are selected such that the polymer does not self-associate, and wherein a plurality of associative groups separate each of said non-associative chains; 
 wherein the associative groups are selected from the group of hydrogen bond donor/acceptor pairs, charge transfer donor/acceptor pairs and ionic bond donor/acceptor pairs; 
 wherein the associative groups of said polymers reversibly associate with an association strength less than that of a covalent bond to form supramolecules. 
   
     
     
         2 . The material of  claim 1 , wherein the mixture of polymers comprises at least two different complementary polymers each of said polymers comprising:
 at least one non-associative chain, and   a plurality of associative groups dispose at either end of each of said non-associative chains; and   wherein the associative groups of the at least two different complementary polymers reversibly associate with an association strength less than that of a covalent bond to form supramolecules.   
     
     
         3 . The material of  claim 1 , wherein the plurality of associative groups are disposed in close proximity to form associative clusters at either end of said non-associative chain. 
     
     
         4 . The material of  claim 3 , wherein each of said clusters comprises at least twenty associating groups. 
     
     
         5 . The material of  claim 3 , wherein the clusters are formed using a mode selected from the group consisting of comonomers, dendrimers, nanoparticies and specially designed chemical units that confer polyvalent association. 
     
     
         6 . (canceled) 
     
     
         7 . The material of  claim 1 , wherein the medium is fuel and the non-associative chains confer solubility in fuel over a wide temperature range −40° C. to +60° C. 
     
     
         8 . The material of  claim 7 , wherein the solubility in fuel is conferred to the middle chains by unsaturated hydrocarbon groups attached thereto. 
     
     
         9 . The material of  claim 2 , wherein the at least different complementary polymers form a donor/acceptor pair. 
     
     
         10 . (canceled) 
     
     
         11 . The material of  claim 10 , wherein the associative groups include a carboxylic acid/tertiary amine acid/base pair. 
     
     
         12 . The material of  claim 11 , wherein the tertiary amine is selected from the group consisting of dialkylamino groups connected via a linker that includes methylene carbons adjacent to the amine, including, (dimethylamino) alkyl groups, (diethylamino) alkyl groups, (methylethylamino) alkyl groups, and pyridyl groups. 
     
     
         13 . The material of  claim 1 , wherein the associative groups include a hydrogen bond pair selected from the group consisting of hydroxyphenyl/pyridyl pairs, and 2,4-Bis(propylamido)pyridine/Hydrouracil pair. 
     
     
         14 . The material of  claim 1 , wherein the associative groups include a charge transfer pair, and wherein the electron donor is selected from the group consisting of carbazole derivatives and N,N-dimethylanilino derivatives, and wherein the electron acceptor is selected from the group consisting of dinitrophenyl group, 3,6-dinitro-carbazolyl group, buckminsterfullerene (C 60 ), 4-bromo-1-naphthyl group, dansyl group, anthracene, pyrene, 2,3,5,6-tetrafluorophenyl group, and cyanophenyl group. 
     
     
         15 . The material of  claim 1 , wherein the long chains are homopolymers or copolymers of different monomers. 
     
     
         16 . The material of  claim 15 , wherein the monomers are selected from the group of isoprene, butadiene, ethylene, propylene, butene, norbornene derivatives, cyclobutene, cyclopentene, cyclooctene, cyclooctadiene, and trans,trans,cis-1,5,9-cyclododecatriene. 
     
     
         17 . The material of  claim 1 , wherein the association of the complementary polymers is sufficiently strong to provide association of the polymers into supramolecules at temperatures up to 60° C. 
     
     
         18 . The material of  claim 2 , wherein the mixture comprises two complementary polymers, and wherein the associative groups at each end of each of the complementary polymers is different such that each end of each of the complementary polymers is designed to associate with only one end of the other complementary polymer. 
     
     
         19 . The material of  claim 18 , wherein the associative groups at the first end of both complementary polymers associate by an acid/base interaction, and wherein the associative groups at the second end of both complementary polymers associate by an electron donor/acceptor interaction. 
     
     
         20 . The material of  claim 19 , wherein the complementary polymers selectively associate to form supramolecules that are linear pentamers. 
     
     
         21 . The material of  claim 1 , wherein the polymers are provided in the mixture in a concentration of from 100 to 1000 ppm. 
     
     
         22 - 36 . (canceled) 
     
     
         37 . The material of  claim 1 , wherein the at least one non-associative chain comprises acrylate repeat units. 
     
     
         38 . The material of  claim 37 , wherein each acrylate repeat unit is a methacrylate or a tert-butyl acrylate. 
     
     
         39 . The material of  claim 1 , wherein the supramolecules can reversibly dissociate without chemical degradation. 
     
     
         40 . A material comprising:
 a mixture of polymers each having:
 at least one non-associative chain selected to confer solubility to the polymer in a particular medium such that the medium and the material remain as a homogeneous single phase during storage and transport; wherein the at least one non-associative chain comprises acrylate repeat units; 
 a plurality of associative groups disposed on at least one end of each of said non-associative chains, wherein the associative groups are selected such that the polymer does not self-associate, and wherein a plurality of associative groups separate each of said non-associative chains; 
 wherein the associative groups are selected from the group of hydrogen bond donor/acceptor pairs, charge transfer donor/acceptor pairs and ionic bond donor/acceptor pairs; 
   wherein the associative groups of said polymers reversibly associate with an association strength less than that of a covalent bond to form supramolecules.   
     
     
         41 . The material of  claim 40 , wherein the at least one non-associative chain having a weight average molar mass comprised between 100 to 1000 kg/mol.