Silane containing high modulus urethane adhesives

Abstract

Moisture-curable, one component adhesives contain an isocyanate-terminated prepolymer, a low molecular weight polyisocyanate compound, a hydrolysable mercaptosilane, a urethane catalyst and a carbon black filler. The adhesives exhibit an excellent combination of high modulus, excellent hydrolytic and heat stability, and high sag resistance.

1 . An adhesive composition comprising urethane prepolymer resin, a reactive silane, a polyisocyanate with functionality more than 2, one or more catalysts for isocyanate reaction with hydroxyl groups; and carbon black filler. 
     
     
         2 . The adhesive composition according to  claim 1  wherein the reactive silane is mercaptosilane. 
     
     
         3 . A method of making an adhesive composition wherein a reactive silane is separately added to the composition during the mixing of various components of the composition. 
     
     
         4 . The method of  claim 3  where in the reactive silane is mercaptosilane. 
     
     
         5 . An adhesive composition made from  claim 3 . 
     
     
         6 . A moisture-curable adhesive composition comprising:
 a) an isocyanate-terminated prepolymer having free isocyanate groups and an isocyanate equivalent weight of 840 to 5,000;   b) 0.1 to 6 parts by weight, per 100 parts by weight of the adhesive composition, of at least one polyisocyanate compound having an isocyanate equivalent weight of up to 300, the at least one polyisocyanate compound having a number average isocyanate functionality of at least 2.5;   c) 0.1 to 4 parts by weight per 100 parts of the adhesive composition of at least one hydrolysable organosilane, the at least one hydrolysable organosilane including a mercaptosilane having one mercapto group and at least one hydrolysable silane group;   d) at least one urethane catalyst and   e) a carbon black filler.   
     
     
         7 . The adhesive composition of  claim 6  wherein the mercaptosilane includes at least one mercaptoalkyl(trialkoxy)silane or mercaptoalkylmethyl(dialkoxy)silane. 
     
     
         8 . The adhesive composition of  claim 6  wherein the carbon black has an oil absorption number of at least 80 cubic centimeters of dibutyl phthalate per 100 g of the carbon black, as measured according to ASTM D-2414-09. 
     
     
         9 . The adhesive composition of  claim 6 , wherein the isocyanate terminated prepolymer includes at least one reaction product of a polyether diol and a diisocyanate. 
     
     
         10 . The adhesive composition of  claim 6 , wherein the isocyanate-terminated prepolymer includes at least one reaction product of a polyester diol having a melting temperature of 40 to 85° C. and a diisocyanate. 
     
     
         11 . The adhesive composition of  claim 6 , which further includes a plasticizer. 
     
     
         12 . The adhesive composition of  claim 6 , which exhibits a press flow viscosity of 5 to 200 seconds at 23° C. 
     
     
         13 . A method of making an adhesive composition according to  claim 6 , comprising the steps of:
 A) forming the isocyanate-terminated prepolymer;   B) mixing the isocyanate-terminated prepolymer with the at least one hydrolysable silane, and then   C) combining the at least one polyisocyanate compound having an isocyanate equivalent weight of up to 210, urethane catalyst and carbon black with the mixture of the isocyanate-terminated prepolymer with the at least one hydrolysable silane.   
     
     
         14 . A method of making an adhesive composition according to  claim 6 , comprising the steps of:
 A) forming the isocyanate-terminated prepolymer;   B) mixing the isocyanate-terminated prepolymer with the at least one polyisocyanate compound having an isocyanate equivalent weight of up to 210; and then   C) combining the at least one hydrolysable silane, urethane catalyst and carbon black with the mixture of the isocyanate-terminated prepolymer with the at least one hydrolysable silane.