US2022098715A1PendingUtilityA1

Method of manufacturing an almgsc-series alloy product

Assignee: ALERIS ROLLED PROD GERMANY GMBHPriority: Jan 17, 2019Filed: Jan 13, 2020Published: Mar 31, 2022
Est. expiryJan 17, 2039(~12.5 yrs left)· nominal 20-yr term from priority
C22C 21/06C22F 1/047B21B 2003/001B22D 21/04B21B 2003/006
51
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Claims

Abstract

The invention relates to a method of manufacturing an AIMgSc-series aluminium alloy product, the method comprising the step of cooling said AIMgSc-series aluminium alloy product from a final annealing temperature to below 150° C., wherein the cooling in a first temperature range of about 250° C. to about 200° C. is at an equivalent time of more than 4 hours, and wherein the cooling in a second temperature range from about 200° C. to about 150° C. is at an equivalent time of more than 0.2 hours, and wherein the equivalent time (t(eq)) is defined as (I) wherein T (in degrees Kelvin) indicates the temperature of the heat treatment, which changes over the time t (in hours) and Tref (in degrees Kelvin) is the reference temperature selected at 473K.t⁡(eq)=∫exp⁡(-16000/T)⁢dtexp⁡(-16000/Tref)(I)

Claims

exact text as granted — not AI-modified
1 . A method of manufacturing an AlMgSc-series aluminium alloy product, the method comprising the step of cooling said AlMgSc-series aluminium alloy product from a final annealing temperature to below 150° C., wherein the cooling in a first temperature range of about 250° C. to about 200° C. is at an equivalent time of more than 4 hours, and wherein the cooling in a second temperature range from about 200° C. to about 150° C. is at an equivalent time of more than 0.2 hours, and wherein the equivalent time (t(eq)) is defined as 
       
         
           
             
               
                 t 
                 ⁡ 
                 
                   ( 
                   eq 
                   ) 
                 
               
               = 
               
                 
                   ∫ 
                   
                     
                       exp 
                       ⁡ 
                       
                         ( 
                         
                           
                             - 
                             16000 
                           
                           / 
                           T 
                         
                         ) 
                       
                     
                     ⁢ 
                     dt 
                   
                 
                 
                   exp 
                   ⁡ 
                   
                     ( 
                     
                       
                         - 
                         16000 
                       
                       / 
                       
                         T 
                         ref 
                       
                     
                     ) 
                   
                 
               
             
           
         
         wherein T (in degrees Kelvin) indicates the temperature of the heat treatment, which changes over the time t (in hours) and T ref  (in degrees Kelvin) is the reference temperature selected at 473K (200° C.). 
       
     
     
         2 . The method according to  claim 1 , wherein the equivalent time in the first temperature range is longer than 6.5 hours. 
     
     
         3 . The method according to  claim 1 , wherein the equivalent time in the second temperature range is longer than 0.4 hours. 
     
     
         4 . The method according to  claim 1 , wherein the final annealing temperature is in a range of 250° C. to 400° C. 
     
     
         5 . The method according to  claim 1 , wherein said AlMgSc-series aluminium alloy product is in a form selected from the group consisting of a rolled product, an extruded product, a forged product, a powder-metallurgy product. 
     
     
         6 . The method according to  claim 1 , wherein said AlMgSc-series aluminium alloy product is a rolled product. 
     
     
         7 . The method according to  claim 6 , wherein the rolled product has a thickness of up to 25.4 mm. 
     
     
         8 . The method according to  claim 1 , wherein the method comprises the steps of casting an AlMgSc-series aluminium alloy ingot, rolling the ingot to final gauge into a rolled product, and heat-treating by annealing of the rolled product at the final annealing temperature, followed by cooling in accordance with  claim 1 . 
     
     
         9 . The method according to  claim 1 , wherein the method comprises the steps of a high temperature forming operation of an AlMgSc-series aluminium alloy product into a single- or double-curved shape product at the final annealing temperature followed by cooling in accordance with  claim 1 . 
     
     
         10 . The method according to  claim 9 , wherein the high temperature forming operation at the final annealing temperature is by a creep forming operation or a relaxation forming operation. 
     
     
         11 . The method according to  claim 1 , wherein the AlMgSc-series aluminium alloy product has a composition comprising of, in wt. %:
 Mg 3.0% to 6.0%,   Sc 0.02% to 0.5%,   Mn up to 1%,   Zr up to 0.3%,   impurities and balance aluminium.   
     
     
         12 . The method according to  claim 1 , wherein the AlMgSc-series aluminium alloy product has a composition comprising of, in wt. %:
 Mg 3.0% to 6.0%,   Sc 0.02% to 0.5%,   Mn up to 1%,   Zr up to 0.3%,   Cr up to 0.3%,   Ti up to 0.2%,   Cu up to 0.2%,   Zn up to 1.5%,   Fe up to 0.4%,   Si up to 0.3%,   impurities and balance aluminium.   
     
     
         13 . The method according to  claim 1 , wherein the AlMgSc-series aluminium alloy product achieves a measured mass loss per ASTM G67-13 not greater than 15 mg/cm 2 , both before and after being sensitized. 
     
     
         14 . The method according to  claim 13 , wherein the measured mass loss is not greater than 12 mg/cm 2 . 
     
     
         15 . The method according to  claim 13 , wherein the measured mass loss is not greater than 9 mg/cm 2 . 
     
     
         16 . The method according to  claim 12 , wherein the Mg content is from 3.2% to 4.8%. 
     
     
         17 . The method according to  claim 12 , wherein the Sc content is from 0.02% to 0.40%. 
     
     
         18 . The method according to  claim 12 , wherein the Mn content is from 0.3% to 1.0%. 
     
     
         19 . The method according to  claim 12 , wherein the Zr content is from 0.05% to 0.3%. 
     
     
         20 . The method according to  claim 12 , wherein the Ti content is from 0.01% to 0.2%.

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