CORE-SHELL STRUCTURE POLYMER MAGNETIC NANOSPHERES WITH HIGH Cr (VI) ADSORPTION CAPACITY, PREPARATION METHOD AND APPLICATION

Abstract

The invention discloses a core-shell structure polymer magnetic nanosphere with a high Cr (VI) adsorption capacity and its preparation method and application. The preparation method includes: adding Fe3O4 powder into a mixed solution of water and ethanol, dispersing Fe3O4 powder in the solution evenly by ultrasound, sequentially adding resorcinol and formaldehyde into the suspension to adjust a pH, stirring and reacting to obtain Fe3O4@RF evenly dispersed in a chitosan solution, dropwise adding the prepared suspension into a mixed solution of paraffin and span 80, stirring for a period of time, adding a glutaraldehyde aqueous solution, stirring and reacting to obtain a magnetic chitosan nanosphere. The magnetic chitosan nanosphere prepared may be applied to adsorbing Cr (VI) in a water solution. Not only the magnetic chitosan nanospheres prepared has a high adsorption capacity for Cr (VI), but also can be quickly separated by an external magnetic field after adsorption.

What is claimed: 
     
         1 . A method for preparing a core-shell structure polymer magnetic nanosphere with a high Cr (VI) adsorption capacity, comprising:
 (1) Adding Fe 3 O 4  powder into a mixed solution of water and ethanol, dispersing Fe 3 O 4  powder in the solution evenly by ultrasound, sequentially adding resorcinol and formaldehyde into the suspension to adjust a pH, and finally stirring the mixed suspension for a period of time; washing and drying after magnetic separation to obtain Fe 3 O 4 @RF;   (2) dispersing Fe 3 O 4 @RF in a chitosan solution evenly, dropwise adding the prepared suspension into a mixed solution of paraffin and span 80, stirring for a period of time, adding a glutaraldehyde aqueous solution, stirring and reacting, and finally centrifuging, washing and drying the obtained mixed suspension to obtain the core-shell structure polymer magnetic nanosphere with a high Cr (VI) adsorption capacity.   
     
     
         2 . The method of  claim 1 , wherein, at block( 1 ), preparing the Fe 3 O 4  powder by: dissolving 2.7 parts by mass of FeCl 3 .6H 2 O in 80 parts by volume of ethylene glycol at room temperature, adding 7.2 parts by mass of NaAc after stirring until clear and transparent, and continuing stirring until the solid is completely dissolved; then moving the mixed solution into a reactor, and performing hydrothermal reaction at 200 C.° for 16 h; washing the black precipitate with ethanol after cooling to room temperature, separating and drying to obtain the Fe 3 O 4  powder. 
     
     
         3 . The method of  claim 1 , wherein, at block( 1 ), the addition amount of the Fe 3 O 4  powder being 0.5 parts by mass, the addition amount of resorcinol being 0.4 parts by mass, and the addition amount of formaldehyde being 0.8 parts by mass. 
     
     
         4 . The method of  claim 1 , wherein, at block( 1 ), stirring the mixed suspension at 30 C.° for 10 h. 
     
     
         5 . The method of  claim 1 , wherein, at block( 1 ), adjusting the pH value to 9˜11; the ultrasonic time being 10˜15 min; the volume ratio of water to ethanol in the mixed solution of water and ethanol being 1:2. 
     
     
         6 . The method of  claim 1 , comprising: at block( 2 ), the mass ratio of Fe 3 O 4 @R to chitosan being 1:1˜5. 
     
     
         7 . The method of  claim 1 , wherein, at block( 2 ), the chitosan solution being 50˜55 parts by volume, the glutaraldehyde aqueous solution being 10 parts by volume, the mixed solution of paraffin and span 80 being 80 parts by volume, the mass concentration of the chitosan solution being 1%˜5%, and the volume concentration of the glutaraldehyde aqueous solution being 5%˜15%. 
     
     
         8 . The method of  claim 1 , wherein, at block( 2 ), in the mixed solution of paraffin and span 80, the volume ratio of paraffin to span 80 being 75:5; stirring for 1 h after dropwise adding the suspension to the mixed solution of paraffin and span 80; stirring for 0.5˜2 h after adding the glutaraldehyde aqueous solution. 
     
     
         9 . (canceled) 
     
     
         10 . (canceled)