Substrate for lithium ion battery separators and lithium ion battery separator

Abstract

It is an object of the present invention to provide a substrate for lithium ion battery separators which has high adhesion to an inorganic particle layer, can be made thin and is excellent in tensile strength and cuttability and a lithium ion battery separator including the substrate for lithium ion battery separators. The substrate for lithium ion battery separators which contains heat-resistant fibers and synthetic resin short fibers contains fibrillated heat-resistant fibers having a modified freeness of not more than 300 ml as the heat-resistant fibers and has a content of the fibrillated heat-resistant fibers having a modified freeness of not more than 300 ml of not less than 1.0 mass % to less than 5.0 mass % based on the total of all the fiber components contained in the substrate. The modified freeness is a value measured in accordance with JIS P8121-2:2012 except that an 80-mesh wire net having a wire diameter of 0.14 mm and an opening of 0.18 mm is used as a screening plate and the concentration of a sample is 0.1%.

1 . A substrate for lithium ion battery separators, comprising:
 heat-resistant fibers, and   synthetic resin short fibers,
 wherein the heat-resistant fibers comprise 
 first fibrillated heat-resistant fibers, having a modified freeness of not more than 300 ml and 
 second fibrillated heat-resistant fibers, having a modified freeness of more than 300 ml, 
   wherein the content of the first fibrillated heat-resistant fibers is not less than 1.0 mass % to less than 5.0 mass % based on a total of all fiber components contained in the substrate,   wherein the modified freeness is a value measured in accordance with JIS P8121-2:2012 except that an 80-mesh wire net having a wire diameter of 0.14 mm and an opening of 0.18 mm is used as a screening plate and the concentration of a sample is 0.1%, and   wherein the synthetic resin short fibers have a fiber length of 1 to 10 mm.   
     
     
         2 . The substrate for lithium ion battery separators according to  claim 1 , wherein the total content of the first fibrillated heat-resistant fibers and the second fibrillated heat-resistance fibers is not less than 2.0 mass % to less than 9.0 mass % based on the total of all fiber components contained in the substrate. 
     
     
         3 . The substrate for lithium ion battery separators according to  claim 2 , wherein the content of the second fibrillated heat-resistant fibers is not less than 1.0 mass % to less than 5.0 mass % based on the total of all fiber components contained in the substrate. 
     
     
         4 . The substrate for lithium ion battery separators according to  claim 3 , wherein the content of the synthetic resin short fibers is 90.0 to 98.0 mass % based on the total of all fiber components contained in the substrate. 
     
     
         5 . A substrate for lithium ion battery separators, comprising:
 heat-resistant fibers, and   synthetic resin short fibers,   wherein the heat-resistant fibers comprise
 fibrillated heat-resistant fibers, having a modified freeness of not more than 300 ml, and 
 fibrid made of para-aromatic polyamide, having a modified freeness of not more than 300 ml, 
   wherein the content of the heat-resistant fibers is not less than 1.0 mass % to less than 5.0 mass % based on a total of all fiber components contained in the substrate,   wherein the modified freeness is a value measured in accordance with JIS P8121-2:2012 except that an 80-mesh wire net having a wire diameter of 0.14 mm and an opening of 0.18 mm is used as a screening plate and the concentration of a sample is 0.1%, and   wherein the synthetic resin short fibers have a fiber length of 1 to 10 mm.   
     
     
         6 . The substrate for lithium ion battery separators according to  claim 5 , wherein the content of the synthetic resin short fibers is 90.0 to 99.0 mass % based on the total of all fiber components contained in the substrate. 
     
     
         7 . The substrate for lithium ion battery separators according to  claim 5 , wherein the content of the synthetic resin short fibers is more than 95.0 mass % to not more than 99.0 mass % based on the total of all fiber components contained in the substrate. 
     
     
         8 . A substrate for lithium ion battery separators, comprising:
 heat-resistant fibers, and   synthetic resin short fibers,   wherein the heat-resistant fibers comprise
 first fibrillated heat-resistant fibers, having a modified freeness of not more than 300 ml, 
 fibrid made of para-aromatic polyamide, having a modified freeness of not more than 300 ml, and 
 second fibrillated heat-resistant fibers, having a modified freeness of more than 300 ml, and 
   wherein the content of the heat-resistant fibers is not less than 2.0 mass % to less than 9.0 mass % based on a total of all fiber components contained in the substrate,   wherein the modified freeness is a value measured in accordance with JIS P8121-2:2012 except that an 80-mesh wire net having a wire diameter of 0.14 mm and an opening of 0.18 mm is used as a screening plate and the concentration of a sample is 0.1% and   wherein the synthetic resin short fibers have a fiber length of 1 to 10 mm.   
     
     
         9 . The substrate for lithium ion battery separators according to  claim 8 ,
 wherein the content of the first fibrillated heat-resistant fibers is not less than 0.6 mass % to less than 4.6 mass %,   the content of the fibrid is not less than 0.4 mass % to less than 2.5 mass %, and   the content of the second fibrillated heat-resistant fibers is not less than 1.0 mass % to less than 4.0 mass % based on the total of all fiber components contained in the substrate.   
     
     
         10 . The substrate for lithium ion battery separators according to  claim 8 , wherein the content of the synthetic resin short fibers is 90.0 to 98.0 mass % based on the total of all fiber components contained in the substrate. 
     
     
         11 . A lithium ion battery separator which is a combination of at least one composite selected from the group consisting of an inorganic particle layer containing inorganic particles, organic particle layer containing organic particles, porous film, microfiber layer, solid electrolyte and gel-like electrolyte and the substrate for lithium ion battery separators according to  claim 1 . 
     
     
         12 . A lithium ion battery separator which is a combination of at least one composite selected from the group consisting of an inorganic particle layer containing inorganic particles, organic particle layer containing organic particles, porous film, microfiber layer, solid electrolyte and gel-like electrolyte and the substrate for lithium ion battery separators according to  claim 5 . 
     
     
         13 . A lithium ion battery separator which is a combination of at least one composite selected from the group consisting of an inorganic particle layer containing inorganic particles, organic particle layer containing organic particles, porous film, microfiber layer, solid electrolyte and gel-like electrolyte and the substrate for lithium ion battery separators according to  claim 8 .