Formulations with high glass transition temperatures, for laminates

Abstract

The present invention relates to curable resin compositions, to methods for producing cured compositions using said curable resin compositions, and to items, in particular molded parts, produced by means of such methods.

What is claimed is: 
     
         1 . A resin composition comprising at least one epoxy resin component at least one curing component and based on the total weight thereof,
 (A) 1-30 wt. % particles having a core-shell structure, and   (B) 1-10 wt. % inorganic particles.   
     
     
         2 . The resin composition according to  claim 1 , characterized in that the at least one epoxy resin component comprises a cycloaliphatic epoxy resin. 
     
     
         3 . The resin composition according to  claim 1 , characterized in that
 (a) the total amount of particles (A) and particles (B) is in the range of from 1 to 30 wt. % based in each case on the total weight of the resin composition; and/or   (b) the amount of inorganic particles (B) is in the range of from 4-8 wt. %; and/or   (c) the particles (A) and the particles (B) are contained in the epoxy resin component.   
     
     
         4 . The resin composition according to  claim 1 , characterized in that the at least one epoxy resin component is an epoxy compound selected from the group consisting of bis-(3,4-epoxycyclohexylmethyl) oxalate, bis-(3,4-epoxycyclohexylmethyl) adipate, bis-(3,4-epoxy-6-methylcyclohexylmethyl) adipate, bis-(3,4-epoxycyclohexylmethyl) pimelate, 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, bis-(3,4-epoxycyclohexyl) adipate, 3,4-epoxy-1-methylcyclohexylmethyl-3,4-epoxy-1-methylcyclohexane carboxylate, and mixtures thereof. 
     
     
         5 . The resin composition according to  claim 1 , characterized in that the at least one curing component comprises at least one anhydride curing agent. 
     
     
         6 . The resin composition according to  claim 5 , characterized in that the at least one anhydride curing agent is selected from bicyclo[2.2.1]-5-heptene-2,3-dicarboxylic acid anhydride, bicyclo[2.2.1]methylhept-5-ene-2,3-dicarboxylic acid anhydride, and mixtures thereof. 
     
     
         7 . A method for producing a cured composition comprising the steps of:
 (1) providing a resin composition according to  claim 1 ; and   (2) curing the resin composition in order to obtain a cured composition.   
     
     
         8 . The method according to  claim 7 , characterized in that the method is a transfer molding (RTM) method and the resin composition is a reactive injection resin. 
     
     
         9 . The method according to  claim 7 , characterized in that step (1) comprises injecting the resin composition into a die in which fibers or semi-finished fiber products (prewovens/preforms) are placed. 
     
     
         10 . The method according to  claim 7 , characterized in that
 (a) the resin composition in step (2) is cured at a temperature of between 100° C. and 240° C., for 0.01 to 10 hours; or   (b) the resin composition in step (2) is first pre-cured at a temperature of between 70° C. and 150° C., for 0.1 to 3 hours and is then post-cured at least once, in each case at a temperature of between 110° C. and 260° C., in each case for 0.1 to 3 hours.   
     
     
         11 . A cured composition obtainable according to a method to  claim 7 . 
     
     
         12 . The cured composition according to  claim 11 , characterized in that the K1c value of the cured composition is at least 0.8. 
     
     
         13 . The cured composition according to  claim 11 , characterized in that the cured composition has a glass transition temperature T g ≥250° C. 
     
     
         14 . The cured composition according to  claim 11 , characterized in that the cured composition is a molded part, in particular a fiber-reinforced molded part.