US2022306949A1PendingUtilityA1
Desalter Configuration Integrated with Steam Cracker
Assignee: EXXONMOBIL CHEMICAL PATENTS INCPriority: Jun 24, 2019Filed: Jun 17, 2020Published: Sep 29, 2022
Est. expiryJun 24, 2039(~12.9 yrs left)· nominal 20-yr term from priority
C10G 55/04C10G 31/08C10G 9/36C10G 2300/4081C10G 2300/201
43
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Claims
Abstract
The present disclosure provides for processes for producing light hydrocarbons. In an embodiment, a process includes pressurizing the hydrocarbon feed in one or more pumps producing a pressurized hydrocarbon feed and heating the pressurized hydrocarbon feed in one or more heat exchangers to produce a heated hydrocarbon feed. The process includes mixing the heated hydrocarbon feed with water and separating an inter-stage hydrocarbon feed from interstage water. The process includes mixing the inter-stage hydrocarbon feed with water and separating a desalted hydrocarbon feed from outlet water. The process includes pyrolysing the desalted hydrocarbon feed in a steam cracker.
Claims
exact text as granted — not AI-modified1 . A desalting process, the process comprising:
providing a hydrocarbon feed comprising heavy hydrocarbon; pressurizing the hydrocarbon feed to produce a pressurized hydrocarbon feed; heating the pressurized hydrocarbon feed in one or more heat exchangers producing a heated hydrocarbon feed; mixing the heated hydrocarbon feed with water and separating an inter-stage hydrocarbon feed from inter-stage water; mixing the inter-stage hydrocarbon feed with water and separating a desalted hydrocarbon feed from outlet water; dividing the desalted hydrocarbon stream into at least first and second portions, at least one hydrocarbon-recycle stream away from the desalted hydrocarbon feed; pyrolysing at least part of the first portion of the desalted hydrocarbon feed in a steam cracker; and combining at least part of the second portion of the desalted hydrocarbon feed with at least a portion of the hydrocarbon feed.
2 . The process of claim 1 , wherein the pressurization includes pressurizing the hydrocarbon feed in at least one pump to a pressure of from about 101 kPa (abs) to about 2000 kPa (abs).
3 . The process of claim 1 , wherein heating comprises heating the pressurized hydrocarbon feed to a temperature from about 100° C. to about 150° C.
4 . The process of claim 1 , further comprising storing at least a portion of the desalted hydrocarbon feed in a surge drum.
5 . The process of claim 1 , wherein 1 wt. % to 50 wt. % of the desalted hydrocarbon feed resides in the second portion, and wherein the second portion is combined with the hydrocarbon feed in at least one storage tank.
6 . The process of claim 1 , wherein the pyrolysis is performed at a temperature from about 760° C. to about 1100° C., and wherein the first portion contains ≤4 wppm of salt.
7 . The process of claim 1 , further comprising a pyrolysis pressure from about 60 kPa (gauge) to about 500 kPa (gauge).
8 . An apparatus for removing contaminants from a hydrocarbon feed containing heavy hydrocarbons, the apparatus comprising:
a first desalter; a second desalter in fluid connection with the first desalter; a steam cracker in fluid connection with the second desalter, a storage tank in fluid connection with the first desalter, and a hydrocarbon recycle line in fluid connection with the second desalter and the storage tank.
9 . The apparatus of claim 8 , further comprising, a vapor-liquid separator fluidically and thermally integrated with the steam cracker, and wherein the first and/or second desalters utilize water injection for the desalting.
10 . The apparatus of claim 8 , further comprising a surge drum in fluid connection with the second desalter and the steam cracker.
11 . The apparatus of claim 9 , further comprising a third desalter situated between the second desalter and the steam cracker and in fluidic communication with the second desalter and the steam cracker.
12 . The apparatus of claim 8 , further comprising a recycle line in fluid connection with the steam cracker and the first desalter.
13 . The apparatus claim 12 , further comprising a recycle line in fluid connection with the steam cracker and the storage tank.
14 . The apparatus of claim 11 , further comprising a recycle line in fluid connection with the steam cracker and the hydrocarbon recycle line.
15 . An apparatus for removing contaminants from a hydrocarbon feed containing heavy hydrocarbons, the apparatus comprising:
a desalter having an established electric field; a storage tank in fluid connection with the desalter; a hydrocarbon recycle line in fluid connection with the desalter and the storage tank; and a steam cracker in fluid connection with the desalter.
16 . The apparatus of claim 15 , further comprising a surge drum in fluid connection with the desalter and the steam cracker.
17 . The apparatus of claim 15 , further comprising a recycle line in fluid connection with the steam cracker and the storage tank.
18 . The apparatus of claim 15 , further comprising a recycle line in fluid connection with the steam cracker and the desalter.
19 . The apparatus of claim 15 , further comprising a recycle line in fluid connection with the steam cracker and the hydrocarbon recycle line.
20 .- 26 . (canceled)
27 . A process for producing light hydrocarbons from a hydrocarbon feed containing heavy hydrocarbons, the process comprising:
pressurizing the hydrocarbon feed to produce a pressurized hydrocarbon feed; heating the pressurized hydrocarbon feed in one or more heat exchangers producing a heated hydrocarbon feed; mixing the heated hydrocarbon feed with water to produce an emulsion, separating from the emulsion at least a desalted hydrocarbon feed; storing at least a portion of the desalted hydrocarbon feed in one or more surge drums, and pyrolysing in at least one steam cracking furnace at least a portion of the desalted hydrocarbon feed and/or at least a portion of the stored desalted hydrocarbon feed.
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