Varnish for photo alignment film and liquid crystal display device

Abstract

According to one embodiment, a varnish for a photo alignment film includes an imidization promotor and a first polyamic acid-based compound in an organic solvent. The first polyamic acid-based compound is a polyamic acid or a polyamic acid ester. The imidization promotor has skeleton containing no primary amino group and no secondary amino group. The first polyamic acid-based compound has terminal skeletons containing no primary amino group.

What is claimed is: 
     
         1 : A method of manufacturing a photo alignment film contacting liquid crystal material comprising:
 a step arranging a vanish over the liquid crystal material; and   a step forming the photo alignment film by imidizing the varnish formed over the liquid crystal material, and by radiating with UV light,   wherein the varnish comprises an imidization promotor and a first polyamic acid-based compound in an organic solvent an organic solvent, a first polyamic acid-based compound, and an imidization promotor for promoting dehydration and cyclization reaction to the first polyamic acid-based compound, the first polyamic acid-based compound being a polyamic acid or a polyamic acid ester,   wherein   the imidization promotor has skeleton containing no primary amino group and/or no neither a primary amino group nor a secondary amino group,   the imidization promotor is a pyridine-based compound, a quinoline-based compound, an isoquinoline-based compound, an imidazole-based compound, a benzimidazole-based compound or a tertiary amine, and   the first polyamic acid-based compound has terminal skeletons containing no primary amino group.   
     
     
         2 : The method according to  claim 1 , wherein the imidization promotor comprises an amine-reactive skeleton. 
     
     
         3 : The method according to  claim 2 , wherein the amine-reactive skeleton comprises a halogen group, a diazo group, a carboxyl group, a hydroxyl group, an isocyanate group or an acid anhydride skeleton. 
     
     
         4 : The method according to  claim 1 , wherein the imidization promotor has a molecular weight of 130 or more. 
     
     
         5 : The method according to  claim 1 , wherein the first polyamic acid-based compound has a structural unit represented by Formula (1) below: 
       
         
           
           
               
               
           
         
       
       where X is a cyclic group, each of R 1  and R 2  is independently —COOH or —COOR where R is an alkyl group, and Y 1  is an organic group. 
     
     
         6 : The method according to  claim 1 , wherein the first polyamic acid-based compound has an acid skeleton represented by Formula (2) below: 
       
         
           
           
               
               
           
         
       
       where X is a cyclic group, and each of R 1  and R 2  is independently —COOH or —COOR where R is an alkyl group. 
     
     
         7 : The method according to  claim 1 , wherein the terminal skeletons comprise an imide skeleton, an amide skeleton, an urea skeleton, a tertiary amino skeleton, an azo bond or a carboxyl group. 
     
     
         8 : The method according to  claim 1 , wherein the varnish further comprises a second polyamic acid-based compound, which is a polyamic acid or a polyamic acid ester, and the first polyamic acid-based compound has a polarity higher than that of the second polyamic acid-based compound. 
     
     
         9 : The method according to  claim 1 , further comprising a step of washing the formed photo alignment film with an organic solvent or an oxidizing solvent.