Method for alkaliating electrodes

Abstract

The present invention relates to a method for lithiation of an intercalation-based anode or a non-reactive plating-capable foil or a reactive alloy capable anode, whereby utilization of said lithiated intercalation-based anode or a plating-capable foil or reactive alloy capable anode in a rechargeable battery or electrochemical cell results in an increased amount of lithium available for cycling, and an improved reversible capacity during charge and discharge.

1 . A method for lithiation of a material, preferably, in a continuous process, comprising the steps of:
 (a) providing a material;   (b) providing a bath comprising a non-aqueous solvent and at least one dissolved lithium halide salt, wherein said bath contacts the material, preferably in a continuous process, and wherein a dry gas blanket covers said bath;   (c) providing an electrolytic field plate comprising an inert conductive material wherein said field plate establishes a field between the material and the field plate; and   (d) applying a reducing current to the material and an oxidizing current to the field plate, wherein lithium ions from the bath lithiate into the material.   
     
     
         2 . The method of  claim 1 , wherein the material is an anode active material selected from carbon, coke, graphite, tin, tin oxide, silicon, silicon oxide, aluminum, lithium active metals, alloying metal materials, composites and mixtures thereof. 
     
     
         3 . The method of  claim 1 , wherein the non-aqueous solvent is selected from butylene carbonate, propylene carbonate vinylene carbonate, vinyl ethylene carbonate, dimethyl carbonate, diethyl carbonate, dipropyl carbonate, methyl ethyl carbonate, acetonitrile, gamma -butyrolactone, room temperature ionic liquids, and mixtures thereof. 
     
     
         4 . The method of  claim 3 , wherein the non-aqueous solvent is gamma -butyrolactone. 
     
     
         5 . The method of  claim 1 , wherein the halogen of the dissolved lithium halide salt is selected from ionic F - , Cl - , Br - , I -  and mixtures thereof. 
     
     
         6 . The method of  claim 1 , wherein the dissolved lithium halide salt is LiCl. 
     
     
         7 . The method of  claim 1 , wherein the dissolved lithium halide salt is LiBr. 
     
     
         8 . The method of  claim 1 , wherein the dissolved lithium halide salt is LiF. 
     
     
         9 . The method of  claim 1 , wherein the electrolytic field plate is selected from platinum, gold, glassy carbon, and graphite. 
     
     
         10 . The method of  claim 1 , wherein the lithiated material and foil are used in the final assembly of a rechargeable battery. 
     
     
         11 . The method of  claim 1 , wherein the lithiated material is used in the assembly of an electrochemical cell to provide the lithium needed for cycling when paired with a cathode not initially containing lithium. 
     
     
         12 . The method of  claim 1 , comprising the step of performing a pre-charging cycle upon the anode externally prior to the assembly of an electrochemical cell. 
     
     
         13 . The method of  claim 1 , wherein the evolving gas generated at the field plate is captured by a reflux unit, a membrane contactor, a gas scrubber, and combinations thereof. 
     
     
         14 . The method of  claim 1 , comprising one or more reflux units, membrane contactors, gas scrubbers, baths, inline heaters, filters, salt dosing units, pumps, valves, and combinations thereof, connected in a loop comprising series and parallel connections. 
     
     
         15 . The method of  claim 14 , wherein said inline heaters heat a non-aqueous solvent and dissolved alkali metal halide salt to a temperature of between 30° C. and 65° C. 
     
     
         16 . The method of  claim 15 , wherein said temperature is about 40° C. 
     
     
         17 . The method as in  claim 1 , wherein a separate immersion bath is used to rinse the material in a solvent while holding the electrode in a reducing current mode. 
     
     
         18 . A method as in  claim 1 , wherein the salt is recovered periodically by distillation of the used non-aqueous solvent and subsequent rinsing of the salt in a light non -solvating fluid. 
     
     
         19 . The method of  claim 14 , wherein the rate of said continuous process can be increased and decreased. 
     
     
         20 . The method of  claim 17 , wherein the rate of continuous lithiation of the anode and foil can be increased and decreased. 
     
     
         21 . The method of  claim 17 , wherein the rate of loop circulation can be increased and decreased. 
     
     
         22 . The method of  claim 3 , wherein the non-aqueous solvent contains an additive to facilitate high quality SEI formation. 
     
     
         23 . The method of  claim 22 , wherein the additive is vinylene carbonate. 
     
     
         24 . The method of  claim 1 , wherein a dissolved gas is added. 
     
     
         25 . The method of  claim 24 , in which the dissolved gas is carbon dioxide. 
     
     
         26 . A method for alkaliation of a material, preferably, in a continuous process, comprising the steps of:
 (a) providing a material;   (b) providing a bath comprising a non-aqueous solvent, dissolved CO2 or SO2 gas and at least one dissolved alkali metal salt, wherein said bath contacts the material, preferably in a continuous process, and wherein a dry gas blanket covers said bath;   (c) providing an electrolytic field plate comprising an inert conductive material wherein said field plate establishes a field between the material and the field plate; and   (d) applying a reducing current to the material and an oxidizing current to the field plate, wherein metal ions from the bath alkaliate into the material.