Cyclic organosilicon compounds as electron donors in zeigler ?natta catalyst systems for producing propylene polymer having high melt-flowability

Abstract

Cyclic organosilicon compounds having a structure represented by the general formulaand a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.

1 . A catalyst system for the polymerization or co-polymerization of alpha-olefin comprising a solid Ziegler-Natta type catalyst component, a co-catalyst component, and an electron donor component comprising at least one cyclic organosilicon compound represented by the formula: 
       
         
           
           
               
               
           
         
         wherein R 1  is a hydrocarbon group with 1-20 carbon atoms; 
         wherein R 2  is a bridging group with a backbone chain of 1-9 atoms, wherein the backbone of said bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic radicals; 
         wherein R 3  is a hydrocarbon group with 1-6 carbon atoms; 
         wherein m is 0 or 1; and 
         wherein R 4  is an aliphatic, alicycylic, or aromatic group. 
       
     
     
         2 . The catalyst system according to  claim 1 , wherein R 2  comprises one or more C1-C20 linear or branched, saturated or unsaturated substituents extending off the backbone chain. 
     
     
         3 . The catalyst system according to  claim 1 , wherein the backbone chain length of the bridging group R 2  is from 2 to 4 atoms. 
     
     
         4 . The catalyst system according to  claim 1 , wherein R 3  is a methyl or ethyl group. 
     
     
         5 . The catalyst system according to  claim 1 , wherein R 4  comprises one or more C1-C20 linear or branched, saturated or unsaturated substituents. 
     
     
         6 . The catalyst system according to  claim 1 , wherein two or more of said R 1 , R 2 , R 3 , and R 4  are linked to form one or more saturated or unsaturated ring structures. 
     
     
         7 . The catalyst system according to  claim 1 , wherein at least one of carbon atoms or hydrogen atoms of R 1 , R 2 , R 3 , and R 4 , including any substituents thereof, is replaced by a hetero-atom selected from the group consisting of N, O, S, Si, B, P, and halogen atoms. 
     
     
         8 . The catalyst system according to  claim 1 , wherein the at least one cyclic organosilicon compound is selected from the list: 
       
         
           
           
               
               
           
         
       
     
     
         9 . A method for producing olefin homo-polymer or copolymer, comprising:
 a. providing a composition comprising at least one compound of the formula:   
       
         
           
           
               
               
           
         
         wherein R 1  is a hydrocarbon group with 1-20 carbon atoms; 
         wherein R 2  is a bridging group with a backbone chain of 1-9 atoms, wherein the backbone of said bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic radicals; 
         wherein R 3  is a hydrocarbon group with 1-6 carbon atoms; 
         wherein m is 0 or 1; and 
         wherein R 4  is an aliphatic, alicycylic, or aromatic group; and 
         b. reacting monomer in the presence of the composition to produce the olefin homo-polymer or copolymer. 
       
     
     
         10 . The method according to  claim 9 , wherein two or more of said R 1 , R 2 , R 3 , and R 4  are linked to form one or more saturated or unsaturated ring structures. 
     
     
         11 . The method according to  claim 9 , wherein R 2  comprises one or more C1-C20 linear or branched, saturated or unsaturated substituents extending off the backbone chain. 
     
     
         12 . The method according to  claim 9 , wherein R 4  comprises one or more C1-C20 linear or branched, saturated or unsaturated substituents. 
     
     
         13 . The method according to  claim 9 , wherein said R 3  is a methyl or ethyl group. 
     
     
         14 . The method according to  claim 9 , wherein at least one of carbon atoms or hydrogen atoms of R 1 , R 2 , R 3 , and R 4 , including any substituents thereof, is replaced by a hetero-atom selected from the group consisting of N, O, S, Si, B, P, and halogen atoms. 
     
     
         15 . A composition comprising at least one compound of the formula: 
       
         
           
           
               
               
           
         
         wherein R 1  is a hydrocarbon group with 1-20 carbon atoms; 
         wherein R 2  is a bridging group with a backbone chain of 1-9 atoms, wherein the backbone of said bridging group is selected from the group consisting of aliphatic, alicyclic, and aromatic radicals; 
         wherein R 3  is a hydrocarbon group with 1-6 carbon atoms; 
         wherein m is 0 or 1; and 
         wherein R 4  is an aliphatic, alicycylic, or aromatic group. 
       
     
     
         16 . The composition according to  claim 15 , wherein two or more of said R 1 , R 2 , R 3 , and R 4  are linked to form one or more saturated or unsaturated ring structures. 
     
     
         17 . The composition according to  claim 15 , wherein R 2  comprises one or more C1-C20 linear or branched, saturated or unsaturated substituents extending off the backbone chain. 
     
     
         18 . The composition according to  claim 15 , wherein R 4  comprises one or more C1-C20 linear or branched, saturated or unsaturated substituents. 
     
     
         19 . The composition according to  claim 15 , wherein said R 3  is a methyl or ethyl group. 
     
     
         20 . The composition according to  claim 15 , wherein at least one of carbon atoms or hydrogen atoms of R 1 , R 2 , R 3 , and R 4 , including any substituents thereof, is replaced by a hetero-atom selected from the group consisting of N, O, S, Si, B, P, and halogen atoms.