Electrolyte, anode free rechargeable battery, method of forming anode-free rechargeable battery, battery, and method of forming battery

Abstract

An electrolyte includes an ionic liquid and an electrolyte salt dispersed in the ionic liquid. The ionic liquid includes organic nitrogen cations and charge-delocalized organic anions. The electrolyte salt is selected from alkali metal salt and/or alkaline earth metal salt.

1 - 22 . (canceled) 
     
     
         23 . An electrolyte, comprising
 an electrolyte salt dispersed in an ionic liquid, wherein the electrolyte salt is an alkali metal salt or alkaline earth metal salt; and   a polymer obtained by curing or crosslinking one or more cross-linkable components selected from the group consisting of:   
       
         
           
           
               
               
           
         
       
       wherein R 1  is selected from the group consisting of: 
       
         
           
           
               
               
           
         
       
       wherein n is an integer between 1 and 10,000, inclusively; m is an integer between 1 and 5,000, inclusively; R 2 , R 3 , R 4 , R 5 , and R 6  are each independently selected from the group consisting of: 
       
         
           
           
               
               
           
         
       
       and 
       * indicates a point of attachment. 
     
     
         24 . The electrolyte of  claim 23 , wherein the ionic liquid comprises an organic nitrogen cation selected from the group consisting of 1-ethyl-3-methylimidazolium (Im12 + ), (N,N-diethyl-N-methyl-N(2-methoxyethyl)ammonium, 1,3-dimethylimidazolium, 1-(4-sulfobutyl)-3-methylimidazolium, 1-butyl-1-methylpyrrolidinium, 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, 1-methyl-1-(2-methoxyethyl)pyrrolidinium, 1-methyl-1-octylpyrrolidinium, 3-methyl-1-propylimidazolium, N,N-diethyl-N-methyl-N-propylammonium, N-butyl-Nmethylpiperidinium, N-propyl-N-methylpiperidinium, 1-ethyl-3-methylimidazolium (EMI), 1-butyl-3-methylimidazolium (BMI), 1-octyl-3-methylimidazolium (C8MI), 1-decyl-3-methylimidazolium (C10MI), 1-methyl-3-[2,6-(S)-dimethylocten-2-yl]imidazolium (MDI), 1,2-dimethyl-3-ethylimidazolium (M1,2E3I), 1,2-dimethyl-3-propylimidazolium (DMPI), N-methyl-N-propylpyrrolidinium (P13), N-methyl-N-butyl-pyrrolidinium (P14), imidazolium, pyrrolidinium, quaternary ammonium, alicyclic cation, pyrrolidine cation, iminazole cation, ethylmethylimidazolium cation, and quaternary ammonium cation. 
     
     
         25 . The electrolyte of  claim 23 , wherein the ionic liquid comprises a charge-delocalized organic anion selected from the group consisting of Cl − , bis(fluorosulfonyl)imide (FSI − ), BF 4   − , difluoro(oxalato)borate (DFOB − ), bisperfluoroethylsulfonyl imide (BETI), bis(methanesulfonyl)imide (MSI), trifluoromethanesulfonate (OTf), trifluoroacetate (TA), CF 3 SO 3   − , [(CF 3 SO 2 ) 2 N] − , [(FSO 2 ) 2 N] − , bis(trifluoromethanesulfonyl)imide (TFSI − ), iodied, methyl-phosphate, trifluoromethanesulfonate, bis(oxalate)borate (BOB), acetate, dicyanamide, diethyl phosphate, and hexafluorophosphate. 
     
     
         26 . The electrolyte of  claim 23 , wherein the electrolyte salt comprises a lithium (Li) salt, a sodium (Na) salt, a potassium (K) salt, a calcium (Ca) salt, or a magnesium (Mg) salt. 
     
     
         27 . The electrolyte of  claim 26 , wherein the lithium salt is selected from the group consisting of lithium perchlorate (LiClO 4 ), lithium hexafluorophosphate (LiPF 6 ), lithiumborofluoride (LiBF 4 ), lithium hexafluoroarsenide (LiAsF 6 ), lithium trifluoro-metasulfonate (LiCF 3 SO 3 ), bis-trifluorom-ethyl sulfonylimide lithium (LiN(CF 3 SO 2 ) 2 ), lithium bis(oxalato)borate (LiBOB), lithium oxalyldifluoroborate (LiBF 2 C 2 O 4 ), lithium nitrate(LiNO 3 ), Li-fluoroalkyl-phosphates (LiPF 3 (CF 2 CF 3 ) 3 ), lithium bisperfluoro-ethysulfo-nylimide (LiBETI) lithium bis(trifluoromethanesulphonyl) imide, lithium bis(fuorosulphonyl)imide, lithium trifluoromethanesulfonimide (LiTFSI), lithium bis(fluo-rosulfonyl)imide (LiFSI), lithium difluoro(oxalato)borate (LiDFOB), lithium perchlorate (LiClO 4 ), LiC(CF 3 SO 2 ) 3 , LiF, LiCl, LiBr, LiI, Li 2 SO 4 , LiNO 3 , Li 3 PO 4 , Li 2 CO 3 , LiOH, lithium acetate, lithium trifluoromethyl acetate, lithium oxalate, and a combination thereof. 
     
     
         28 . The electrolyte of  claim 23 , wherein the electrolyte salt has a concentration of between 0.5 M and 8 M in the electrolyte. 
     
     
         29 . The electrolyte of  claim 23 , further comprising an ionomer having a backbone group, an anionic substituent, and a cation. 
     
     
         30 . The electrolyte of  claim 29 , wherein the ionomer is selected from the group consisting of: 
       
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
       
     
     
         31 . The electrolyte of  claim 23 , wherein the polymer has a concentration is between 1 wt % and 40 wt % based on a total weight of the electrolyte. 
     
     
         32 . The electrolyte of  claim 23 , further comprising a plasticizer. 
     
     
         33 . The electrolyte of  claim 23 , wherein the one or more cross-linkable components are cured or crosslinked in the presence of an initiator or crosslinking agent, wherein the initiator or crosslinking agent comprises 2,2′-azobis(2-methylpropionitrile), ammonium persulfate, or azobisisobutyronitrile. 
     
     
         34 . The electrolyte of  claim 23 , further comprising an additive selected from the group consisting of LiBOB, LiDFOB, fluoroethylene carbonate (FEC), vinylene carbonate (VC), Py13TFSI, Li[(FSO 2 ) (n-C 4 F 9 SO 2 )N], 1,4-dioxane, bromide ionomers, methyl viologen, poly(ethyl α-cyanoacrylate), AlCl 3 , H 2 O, diglyme, triglyme, tetraglyme, diethyl ether, 1,3-dioxolane, tetrahydrofuran, 2,5-dimethyltetrahydrofuran, ethylene carbonate (EC), diethylene carbonate (DEC), 1,2-dimethoxyethane(DME), propylene carbonate, dimethyl carbonate, ethyl methyl carbonate, diethyl carbonate, vinyl ethylene carbonate, trimethyl phosphate, triethyl phosphate, triphenyl phosphate, tris(2,2,2-trifluoroethyl)phosphate, tris(2,2,2-trifluoroethyl)phosphite, dimethyl sulfone, ethyl methyl sulfone, sulfolane, sulfoxide, acetonitrile, propionitrile, butyronitrile, diphenyl sulfone, methyl phenyl sulfone, isopropyl sulfone, trimethylene sulfone, methyl difluoroacetate, difluoroethyl acetate, hexafluoroisopropyl triphosphate, triisopropyl ethylsulfonyl (pentafluorophenyl) phosphine, hydrofluoroether, 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropyl ether, bis(2,2,2-trifluoroethyl) ether, oligo ethylene glycol methyl ether, tetraethylene glycol dimethyl ether, bis(2,2,2-trifluoroethyl) ether, oligoethylene glycol, 1,2-dimethoxyethane carbonate, fluoromethylene-ethylene carbonate, prop-1-ene-1,3-sultone, succinic anhydride, and a mixture thereof. 
     
     
         35 . The electrolyte of  claim 34 , wherein the additive has a concentration of between 1 wt % and 20 wt % based on a total weight of the electrolyte. 
     
     
         36 . An anode-free rechargeable battery comprising:
 a current collector;   a cathode with an electroactive material, and   the electrolyte of  claim 23 .   
     
     
         37 . The anode-free rechargeable battery of  claim 36 , further comprising a cathode current collector, wherein the cathode current collector comprises aluminum, nickel, titanium, stainless steel, or carbon paper. 
     
     
         38 . The anode-free rechargeable battery of  claim 36 , wherein the electroactive material is selected from the group consisting of lithium nickel cobalt manganese oxide, lithium nickel cobalt aluminum oxide, lithium titanate, metallic lithium, lithium metal oxide, lithium manganese oxide, lithium cobalt oxide, and lithium iron phosphate. 
     
     
         39 . A battery, comprising:
 the electrolyte of  claim 23 ;   an anode; and   a cathode with an electroactive material.   
     
     
         40 . The battery according to  claim 39 , wherein the anode is lithium metal or graphite. 
     
     
         41 . The battery according to  claim 39 , wherein the electroactive material is selected from the group consisting of lithium nickel cobalt manganese oxide, lithium nickel cobalt aluminum oxide, lithium titanate, metallic lithium, lithium metal oxide, lithium manganese oxide, lithium cobalt oxide and lithium iron phosphate. 
     
     
         42 . The electrolyte of  claim 23 , wherein the electrolyte has an ionic conductivity of at least 0.7×10 −3  S/cm at room temperature.