Nitrification inhibitors

Abstract

Nitrification inhibitors and uses of same to prevent nitrate leaching or nitrous oxide emissions as well as increase pasture or crop production. The nitrification inhibitors and formulations including same may be used for direct or indirect application to soil or pasture.

What is claimed is: 
     
         1 . A method of manufacturing a nitrification-inhibiting composition comprising introducing into a carrier at least one nitrification inhibitor compound of Formula 1:
                       wherein X 1  and X 5  ═ N; X 2  and X 4  ═ CH; and X 3  ═ C—R; wherein R is selected from the group consisting of H and OMe; or   wherein X 1  and X 5  ═ CH; X 2  and X 4  ═ N; and X 3  ═ C—R; wherein R is selected from the group consisting of H and OMe; or   wherein X 1  and X 3  ═ N; and X 2 , X 4  and X 5  ═ CH; or   wherein X 1 , X 4 , and X 5  ═ CH; X 2  is selected from the group consisting of N and N═O; and X 3  ═ C—R; and wherein if X 2  is N═O R is H; and wherein if X 2  is N then R is OMe; or   wherein X 1  ═ N, X 2 , X 4  and X 5  ═ CH; and X 3  ═ C—R; wherein R is OMe; or   wherein X 1  and X 2  ═ N; X 3  ═ C—R; and X 4  and X 5  ═ CH; wherein R is selected from the group consisting of H and OMe; or   wherein X 1  and X 4  ═ N; X 2  and X 5  ═ CH; and X 3  ═ C—R; wherein R is selected from the group consisting of H and OMe; or   wherein X 1 , X 2 , X 4  and X 5  ═ CH; X 3  ═ C—R; wherein R is selected from the group consisting of OMe, OEt, and C≡CH.   
     
     
         2 . The method as claimed in  claim 1  wherein the carrier is a solid or liquid carrier. 
     
     
         3 . The method as claimed in  claim 2  wherein the carrier is water, effluent, animal urine or manure. 
     
     
         4 . The method as claimed in  claim 2  wherein the carrier is a solid or liquid fertilizer. 
     
     
         5 . The method as claimed in  claim 4  wherein the fertilizer comprises urea or another fertilizer that contains ammonium (or ammonia) or produces ammonium (or ammonia). 
     
     
         6 . The method as claimed in  claim 1 , wherein the compound is selected from the group consisting of:
 2-Ethynyl 1,3 Diazine;   3-Ethynyl 1,5 Diazine;   4-Ethynylpyrimidine;   2-Ethynyl-5-methoxypyrimidine;   5-Ethynyl-2-methoxypyrimidine;   2-ethynyl-5-methoxypyridine;   5-ethynyl-2-methoxypyridine;   3-ethynylpyridine 1-oxide;   2,5-diethynylpyridine;   3-Ethynylpyridazine;   3-Ethynyl-6-methoxypyridazine;   2-ethynylpyrazine;   2-Ethynyl-5-methoxypyrazine;   4-Ethynylanisole;   1-ethoxy-4-ethynylbenzene;   1,4-diethynylbenzene;   and has a dosage rate between substantially 1 kg/ha to 9 kg/ha.   
     
     
         7 . A method, as claimed in  claim 6 , wherein the compound is selected from the group consisting of:
 2-Ethynyl 1,3 Diazine;   3-Ethynyl 1,5 Diazine;   4-Ethynylpyrimidine;   2-Ethynyl-5-methoxypyrimidine;   5-Ethynyl-2-methoxypyrimidine;   2-ethynyl-5-methoxypyridine;   3-ethynylpyridine 1-oxide;   3-Ethynylpyridazine;   3-Ethynyl-6-methoxypyridazine;   2-Ethynyl-5-methoxypyrazine;   4-Ethynylanisole.   
     
     
         8 . A method, as claimed in  claim 6 , wherein the compound is selected from the group consisting of:
 2-Ethynyl 1,3 Diazine;   3-Ethynyl 1,5 Diazine;   2-ethynyl-5-methoxypyridine;   3-ethynylpyridine 1-oxide;   3-Ethynylpyridazine.