US2023312404A1PendingUtilityA1

Microcrystalline glass, microcrystalline glass product and manufacturing method thereof

Assignee: CDGM GLASS CO LTDPriority: Dec 31, 2020Filed: Sep 26, 2021Published: Oct 5, 2023
Est. expiryDec 31, 2040(~14.4 yrs left)· nominal 20-yr term from priority
C03C 4/00C03C 10/0027C03C 10/0009C03B 32/02C03C 4/02C03C 2204/00C03C 3/097C03C 1/04C03C 21/002C03C 10/00C03C 4/18C03C 10/0054C03C 4/0092
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Claims

Abstract

A microcrystalline glass product. The microcrystalline glass product includes the following components in percentage by weight: SiO2: 45-70%; Al2O3: 8-18%; Li2O: 10-25%; ZrO2: 5-15%; P2O5: 2-10%; and Y2O3: greater than 0 but less than or equal to 8%. Through reasonable component design, the microcrystalline glass and the microcrystalline glass product have excellent mechanical and optical properties and are suitable for electronic devices or display devices.

Claims

exact text as granted — not AI-modified
1 - 77 . (canceled) 
     
     
         78 . A microcrystalline glass product, comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%. 
     
     
         79 . The microcrystalline glass product according to  claim 78 , further comprising the following components in percentage by weight: K 2 O: 0-5%; and/or MgO: 0-2%; and/or ZnO: 0-2%; and/or Na 2 O: 0-6%; and/or SrO: 0-5%; and/or BaO: 0-5%; and/or CaO: 0-5%; and/or TiO 2 : 0-5%; and/or B 2 O 3 : 0-5%; and/or Ln 2 O 3 : 0-5%; and/or a clarifying agent: 0-2%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         80 . The microcrystalline glass product, comprising following components: SiO 2 , Al 2 O 3 , Li 2 O, ZrO 2 , P 2 O 5  and Y 2 O 3 , wherein a crystal phase of the microcrystalline glass product comprises lithium monosilicate, the lithium monosilicate has a higher weight percentage than other crystal phases. 
     
     
         81 . The microcrystalline glass product according to  claim 80 , comprising following components in percentage by weight: SiO 2 : 45-70%; and/or Al 2 O 3 : 8-18%; and/or Li 2 O: 10-25%; and/or ZrO 2 : 5-15%; and/or P 2 O 5 : 2-10%; and/or Y 2 O 3 : greater than 0 but less than or equal to 8%; and/or K 2 O: 0-5%; and/or MgO: 0-2%; and/or ZnO: 0-2%; and/or Na 2 O: 0-6%; and/or SrO: 0-5%; and/or BaO: 0-5%; and/or CaO: 0-5%; and/or TiO 2 : 0-5%; and/or B 2 O 3 : 0-5%; and/or Ln 2 O 3 : 0-5%; and/or a clarifying agent: 0-2%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         82 . The microcrystalline glass product according to  claim 80 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is greater than 0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 2.5-50.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.16-0.9;   4) Na 2 O/Y 2 O 3  is 6.0 or less;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is greater than 0 but less than or equal to 0.15.   
     
     
         83 . The microcrystalline glass product according to  claim 78 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is greater than 0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 2.5-50.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.16-0.9;   4) Na 2 O/Y 2 O 3  is 6.0 or less;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is greater than 0 but less than or equal to 0.15.   
     
     
         84 . The microcrystalline glass product according to  claim 78 , comprising the following components in percentage by weight: SiO 2 : 50-65%; and/or Al 2 O 3 : 8-15%;
 and/or Li 2 O: 13-22%; and/or ZrO 2 : 6-12%; and/or P 2 O 5 : 3.5-9%; and/or K 2 O: 0-4%; and/or   MgO: 0-1%; and/or ZnO: 0-1%; and/or Na 2 O: 1-5%; and/or Y 2 O 3 : 1-7%; and/or SrO: 0-3%; and/or BaO: 0-3%; and/or CaO: 0-3%; and/or TiO 2 : 0-3%; and/or B 2 O 3 : 0-3%; and/or   Ln 2 O 3 : 0-4%; and/or a clarifying agent: 0-1%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br.   
     
     
         85 . The microcrystalline glass product according to  claim 78 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is 0.1-1.0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 3.0-40.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.18-0.6;   4) Na 2 O/Y 2 O 3  is 0.1-5.0;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is 0.01-0.12.   
     
     
         86 . The microcrystalline glass product according to  claim 78 , comprising the following components in percentage by weight: SiO 2 : 53-63%; and/or Al 2 O 3 : 8-12%; and/or Li 2 O: 14-21%; and/or ZrO 2 : 7-12%; and/or P 2 O 5 : 4-8%; and/or K 2 O: 0-2%; and/or Y 2 O 3 : 2-6%; and/or B 2 O 3 : 0-2%; and/or Na 2 O: 1.5-4%; and/or SrO: 0-1%; and/or TiO 2 : 0-1%; and/or BaO: 0-1%; and/or CaO: 0-1%; and/or Ln 2 O 3 : 0-3%; and/or a clarifying agent: 0-0.5%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         87 . The microcrystalline glass product according to  claim 78 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of the following five situations:
 1) Y 2 O 3 /ZrO 2  is 0.2-0.6;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 4.0-21.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.19-0.5;   4) Na 2 O/Y 2 O 3  is 0.3-2.0;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is 0.03-0.09.   
     
     
         88 . The microcrystalline glass product according to  claim 78 , wherein a crystal phase of the microcrystalline glass product mainly comprises lithium monosilicate; lithium monosilicate has a higher weight percentage than other crystal phases, and lithium monosilicate accounts for 10-63.5% by weight of the microcrystalline glass product. 
     
     
         89 . The microcrystalline glass product according to  claim 78 , wherein a crystal phase of the microcrystalline glass product mainly comprises lithium monosilicate; lithium monosilicate has a higher weight percentage than other crystal phases, and lithium monosilicate accounts for 15-55% by weight of the microcrystalline glass product. 
     
     
         90 . The microcrystalline glass product according to  claim 78 , wherein the microcrystalline glass product comprises a lithium phosphate crystal phase, and the lithium phosphate crystal phase accounts for 3-15% by weight of the microcrystalline glass product. 
     
     
         91 . The microcrystalline glass product according to  claim 78 , wherein a surface stress of the microcrystalline glass product is 600 MPa or more; and/or a four-point bending strength is 600 MPa or more; and/or an ion-exchange layer depth is 20 μm or more; and/or a drop ball test height is 1300 mm or more; and/or a fracture toughness is 1 MPa·m 1/2  or more; and/or a Vickers hardness is 700 kgf/mm 2  or more; and/or a crystallinity is 50% or more; and/or a crystal grain size is 50 nm or less; and/or a haze of the microcrystalline glass product with a thickness of 1 mm or less is 0.15% or less; and/or an average transmittance of the microcrystalline glass product with the thickness of 1 mm or less at a wavelength of 400-800 nm is 89% or more; and/or a transmittance of the microcrystalline glass product with the thickness of 1 mm or less at the wavelength of 550 nm is 91% or more; and/or an average light |B value of the microcrystalline glass product with the thickness of 1 mm or less at 400-800 nm is 0.6 or less. 
     
     
         92 . The microcrystalline glass product according to  claim 78 , wherein a surface stress of the microcrystalline glass product is 700 MPa or more; and/or a four-point bending strength is 700 MPa or more; and/or an ion-exchange layer depth is 40 μm or more; and/or a drop ball test height is 1500 mm or more; and/or a fracture toughness is 1.2 MPa·m 1/2  or more; and/or a Vickers hardness is 730 kgf/mm 2  or more; and/or a crystallinity is 70% or more; and/or a crystal grain size is 30 nm or less; and/or a haze of the microcrystalline glass product with a thickness of 1 mm or less is 0.1% or less; and/or an average light |B value of the microcrystalline glass product with the thickness of 1 mm or less at 400-800 nm is 0.5 or less. 
     
     
         93 . The microcrystalline glass product according to  claim 91 , wherein the thickness of the microcrystalline glass product is 0.2-1 mm. 
     
     
         94 . The microcrystalline glass product according to  claim 78 , wherein the microcrystalline glass product includes a colorant, the colorant comprises following components in percentage by weight: NiO: 0-4%; and/or Ni 2 O 3 : 0-4%; and/or CoO: 0-2%; and/or Co 2 O 3 : 0-2%; and/or Fe 2 O 3 : 0-7%; and/or MnO 2 : 0-4%; and/or Er 2 O 3 : 0-8%; and/or Nd 2 O 3 : 0-8%; and/or Cu 2 O: 0-4%; and/or Pr 2 O 3 : 0-8%; and/or CeO 2 : 0-4%. 
     
     
         95 . Microcrystalline glass, comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%. 
     
     
         96 . The microcrystalline glass according to  claim 95 , further comprising the following components in percentage by weight: K 2 O: 0-5%; and/or MgO: 0-2%; and/or ZnO: 0-2%; and/or Na 2 O: 0-6%; and/or SrO: 0-5%; and/or BaO: 0-5%; and/or TiO 2 : 0-5%; and/or CaO: 0-5%; and/or B 2 O 3 : 0-5%; and/or Ln 2 O 3 : 0-5%; and/or a clarifying agent: 0-2%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         97 . The microcrystalline glass, comprising following components: SiO 2 , Al 2 O 3 , Li 2 O, ZrO 2 , P 2 O 5  and Y 2 O 3 , wherein a crystal phase of the microcrystalline glass comprises lithium monosilicate, the lithium monosilicate has a higher weight percentage than other crystal phases. 
     
     
         98 . The microcrystalline glass product according to  claim 97 , comprising following components in percentage by weight: SiO 2 : 45-70%; and/or Al 2 O 3 : 8-18%; and/or Li 2 O: 10-25%; and/or ZrO 2 : 5-15%; and/or P 2 O 5 : 2-10%; and/or Y 2 O 3 : greater than 0 but less than or equal to 8%; and/or K 2 O: 0-5%; and/or MgO: 0-2%; and/or ZnO: 0-2%; and/or Na 2 O: 0-6%; and/or SrO: 0-5%; and/or BaO: 0-5%; and/or CaO: 0-5%; and/or TiO 2 : 0-5%; and/or B 2 O 3 : 0-5%; and/or Ln 2 O 3 : 0-5%; and/or a clarifying agent: 0-2%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         99 . The microcrystalline glass according to  claim 97 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is greater than 0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 2.5-50.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.16-0.9;   4) Na 2 O/Y 2 O 3  is 6.0 or less;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is greater than 0 but less than or equal to 0.15.   
     
     
         100 . The microcrystalline glass according to  claim 95 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is greater than 0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 2.5-50.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.16-0.9;   4) Na 2 O/Y 2 O 3  is 6.0 or less;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is greater than 0 but less than or equal to 0.15.   
     
     
         101 . The microcrystalline glass according to  claim 95 , comprising the following components in percentage by weight: SiO 2 : 50-65%; and/or Al 2 O 3 : 8-15%; and/or Li 2 O: 13-22%; and/or ZrO 2 : 6-12%; and/or P 2 O 5 : 3.5-9%; and/or K 2 O: 0-4%; and/or MgO 0-1%; and/or ZnO: 0-1%; and/or Na 2 O: 1-5%; and/or Y 2 O 3 : 1-7%; and/or SrO: 0-3%; and/or TiO 2 : 0-3%; and/or BaO: 0-3%; and/or CaO: 0-3%; and/or B 2 O 3 : 0-3%; and/or Ln 2 O 3 : 0-4%; and/or a clarifying agent: 0-1%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         102 . The microcrystalline glass according to  claim 95 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is 0.1-1.0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 3.0-40.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.18-0.6;   4) Na 2 O/Y 2 O 3  is 0.1-5.0;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is 0.01-0.12.   
     
     
         103 . The microcrystalline glass according to  claim 95 , comprising the following components in percentage by weight: SiO 2 : 53-63%; and/or Al 2 O 3 : 8-12%; and/or Li 2 O: 14-21%; and/or ZrO 2 : 7-12%; and/or P 2 O 5 : 4-8%; and/or K 2 O: 0-2%; and/or Y 2 O 3 : 2-6%; and/or B 2 O 3 : 0-2%; and/or Na 2 O: 1.5-4%; and/or SrO: 0-1%; and/or TiO 2 : 0-1%; and/or BaO: 0-1%; and/or CaO: 0-1%; and/or Ln 2 O 3 : 0-3%; and/or a clarifying agent: 0-0.5%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         104 . The microcrystalline glass according to  claim 95 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is 0.2-0.6;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 4.0-21.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.19-0.5;   4) Na 2 O/Y 2 O 3  is 0.3-2.0;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is 0.03-0.09.   
     
     
         105 . The microcrystalline glass according to  claim 95 , wherein a crystal phase of the microcrystalline glass mainly comprises lithium monosilicate; lithium monosilicate has a higher weight percentage than other crystal phases, and lithium monosilicate accounts for 10-63.5% by weight of the microcrystalline glass. 
     
     
         106 . The microcrystalline glass according to  claim 95 , wherein a crystal phase of the microcrystalline glass mainly comprises lithium monosilicate; lithium monosilicate has a higher weight percentage than other crystal phases, and lithium monosilicate accounts for 15-55% by weight of the microcrystalline glass. 
     
     
         107 . The microcrystalline glass according to  claim 95 , wherein the microcrystalline glass comprises a lithium phosphate crystal phase, and the lithium phosphate crystal phase accounts for 3-15% by weight of the microcrystalline glass. 
     
     
         108 . The microcrystalline glass according to  claim 95 , wherein a crystallinity of the microcrystalline glass is 50% or more; and/or a crystalgrain size is 50 nm or less; and/or a coefficient of thermal expansion is 75-95×10 −7 /K; and/or a refractive index is 1.5700-1.5800; and/or a body drop height of the microcrystalline glass is 1000 mm or more; and/or a Vickers hardness is 650 kgf/mm 2  or more; and/or a haze of the microcrystalline glass with a thickness of 1 mm or less is 0.15% or less; and/or an average transmittance of the microcrystalline glass with the thickness of 1 mm or less at a wavelength of 400-800 nm is 89% or more; and/or a transmittance of the microcrystalline glass with the thickness of 1 mm or less at the wavelength of 550 nm is 91% or more; and/or an average light |B value of the microcrystalline glass with the thickness of 1 mm or less at 400-800 nm is 0.6 or less. 
     
     
         109 . The microcrystalline glass according to  claim 95 , wherein a crystallinity of the microcrystalline glass is 70% or more; and/or a crystalgrain size is 30 nm or less; and/or body drop height of the microcrystalline glass is 1200 mm or more; and/or a Vickers hardness is 700 kgf/mm 2  or more; and/or a haze of the microcrystalline glass with a thickness of 1 mm or less is 0.1% or less; and/or an average light |B value of the microcrystalline glass with the thickness of 1 mm or less at 400-800 nm is 0.5 or less. 
     
     
         110 . The microcrystalline glass according to  claim 108 , wherein the thickness of the microcrystalline glass is 0.2-1 mm. 
     
     
         111 . The microcrystalline glass according to  claim 95 , wherein the microcrystalline glass includes a colorant, the colorant comprises the following components in percentage by weight: NiO: 0-4%; and/or Ni 2 O 3 : 0-4%; and/or CoO: 0-2%; and/or Co 2 O 3 : 0-2%; and/or Fe 2 O 3 : 0-7%; and/or MnO 2 : 0-4%; and/or Er 2 O 3 : 0-8%; and/or Nd 2 O 3 : 0-8%; and/or Cu 2 O: 0-4%; and/or Pr 2 O 3 : 0-8%; and/or CeO 2 : 0-4%. 
     
     
         112 . Matrix glass, comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%. 
     
     
         113 . The matrix glass according to  claim 112 , further comprising the following components in percentage by weight: K 2 O: 0-5%; and/or MgO: 0-2%; and/or ZnO: 0-2%; and/or Na 2 O: 0-6%; and/or SrO: 0-5%; and/or BaO: 0-5%; and/or CaO: 0-5%; and/or TiO 2 : 0-5%; and/or B 2 O 3 : 0-5%; and/or Ln 2 O 3 : 0-5%; and/or a clarifying agent: 0-2%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         114 . The matrix glass according to  claim 112 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is greater than 0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 2.5-50.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.16-0.9;   4) Na 2 O/Y 2 O 3  is 6.0 or less;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is greater than 0 but less than or equal to 0.15.   
     
     
         115 . The matrix glass according to  claim 112 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is 0.1-1.0;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 3.0-40.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.18-0.6;   4) Na 2 O/Y 2 O 3  is 0.1-5.0;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is 0.01-0.12.   
     
     
         116 . The matrix glass according to  claim 112 , wherein the components are expressed in percentage by weight, and a content of each component satisfies more than one of following five situations:
 1) Y 2 O 3 /ZrO 2  is 0.2-0.6;   2) (Li 2 O+ZrO 2 +P 2 O 5 )/Y 2 O 3  is 4.0-21.0;   3) Al 2 O 3 /(Li 2 O+ZrO 2 +P 2 O 5 ) is 0.19-0.5;   4) Na 2 O/Y 2 O 3  is 0.3-2.0;   5) Y 2 O 3 /(Al 2 O 3 +SiO 2 ) is 0.03-0.09.   
     
     
         117 . The matrix glass according to  claim 112 , comprising the following components in percentage by weight: SiO 2 : 50-65%; and/or Al 2 O 3 : 8-15%; and/or Li 2 O: 13-22%; and/or ZrO 2 : 6-12%; and/or P 2 O 5 : 3.5-9%; and/or K 2 O: 0-4%; and/or MgO: 0-1%; and/or ZnO: 0-1%; and/or Na 2 O: 1-5%; and/or Y 2 O 3 : 1-7%; and/or SrO: 0-3%; and/or BaO: 0-3%; and/or TiO 2 : 0-3%; and/or CaO: 0-3%; and/or B 2 O 3 : 0-3%; and/or Ln 2 O 3 : 0-4%; and/or a clarifying agent: 0-1%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         118 . The matrix glass according to  claim 112 , comprising the following components in percentage by weight: SiO 2 : 53-63%; and/or Al 2 O 3 : 8-12%; and/or Li 2 O: 14-21%; and/or ZrO 2 : 7-12%; and/or P 2 O 5 : 4-8%; and/or K 2 O: 0-2%; and/or Na 2 O: 1.5-4%; and/or Y 2 O 3 : 2-6%; and/or SrO: 0-1%; and/or BaO: 0-1%; and/or TiO 2 : 0-1%; and/or CaO: 0-1%; and/or B 2 O 3 : 0-2%; and/or Ln 2 O 3 : 0-3%; and/or a clarifying agent: 0-0.5%, wherein Ln 2 O 3  is one or more of La 2 O 3 , Gd 2 O 3 , and Yb 2 O 3 , and the clarifying agent is one or more of Sb 2 O 3 , SnO 2 , SnO, CeO 2 , F, Cl, and Br. 
     
     
         119 . The matrix glass according to  claim 112 , wherein the matrix glass includes a colorant, the colorant comprises the following components in percentage by weight: NiO: 0-4%; and/or Ni 2 O 3 : 0-4%; and/or CoO: 0-2%; and/or Co 2 O 3 : 0-2%; and/or Fe 2 O 3 : 0-7%; and/or MnO 2 : 0-4%; and/or Er 2 O 3 : 0-8%; and/or Nd 2 O 3 : 0-8%; and/or Cu 2 O: 0-4%; and/or Pr 2 O 3 : 0-8%; and/or CeO 2 : 0-4%. 
     
     
         120 . A glass cover plate, comprising the microcrystalline glass product according to  claim 78 , and/or the microcrystalline glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%, and/or the matrix glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%. 
     
     
         121 . A glass component, comprising the microcrystalline glass product according to  claim 78 , and/or the microcrystalline glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%, and/or the matrix glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%. 
     
     
         122 . A display device, comprising the microcrystalline glass product according to  claim 78 , and/or the microcrystalline glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%, and/or the matrix glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%. 
     
     
         123 . An electronic device, comprising the microcrystalline glass product according to  claim 78 , and/or the microcrystalline glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%, and/or the matrix glass comprising following components in percentage by weight: SiO 2 : 45-70%; Al 2 O 3 : 8-18%; Li 2 O: 10-25%; ZrO 2 : 5-15%; P 2 O 5 : 2-10%; and Y 2 O 3 : greater than 0 but less than or equal to 8%.

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