Compound, organic electroluminescence element, and electronic device
Abstract
A compound represented by the formula (12X). In the formula (12X), Py 1 and Py 2 each independently represent a substituted or unsubstituted 1-pyrenyl group, L 1 and L 2 each independently represent a substituted or unsubstituted phenylene group or a substituted or unsubstituted naphthylene group. When L 1 and L 2 each independently represent a substituted or unsubstituted phenylene group, -L 1 -L 2 - in the formula (12X) represents a group represented by one of the formulae (13-1) to (13-6), (10-1), (20-1), and (30-1). When L 1 and L 2 each independently represent a substituted or unsubstituted naphthylene group, a bonding position of the naphthylene group in L 1 is different from a bonding position of the naphthylene group in L 2 .
Claims
exact text as granted — not AI-modified1 . A compound represented by a formula (12X) below,
Py 1 -L 1 -L 2 -Py 2 (12X)
where: Py 1 and Py 2 each independently represent a substituted or unsubstituted 1-pyrenyl group, L 1 and L 2 each independently represent a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group, when L 1 and L 2 each independently represent a substituted or unsubstituted phenylene group, -L 1 -L 2 - in the formula (12X) represents a group represented by one of formulae (13-1) to (13-6), (10-1), (20-1), and (30-1) below, when L 1 and L 2 each independently represent a substituted or unsubstituted naphthylene group, a bonding position of the naphthylene group as L 1 is different from a bonding position of the naphthylene group as L 2 , when Py 1 and Py 2 each independently represent a substituted 1-pyrenyl group, a substituent E for the substituted 1-pyrenyl group each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms, a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, Rx, Ry, and Rz in the —Si(Rx)(Ry)(Rz) each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, and when a plurality of substituents E are present, the plurality of substituents E are mutually the same or different; a substituent F for the substituent E that is substituted or unsubstituted is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group,
where: R 11 to R 15 and R 11A to R 15A each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms, a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms;
Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms;
a substituent for a substituted or unsubstituted group in R 11 to R 15 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group;
at least one combination of adjacent two or more of R 11 to R 15 are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 11A to R 15A are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring; and
*1 in the formulae (13-1) to (13-6) represents a bonding position to Py 1 in the formula (12X), and *2 represents a position of bonding to Py 2 in the formula (12X),
where: in the formula (10-1):
at least one combination of a combination of R 11 and R 12 , a combination of R 13 and R 14 , a combination of R 21 and R 22 , or a combination of R 23 and R 24 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded;
R 11 , R 13 , R 21 , and R 23 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, or a group represented by a formula (4) below,
R 12 , R 14 , R 22 , and R 24 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, or a group represented by the formula (4) below, and
at least one of R 11 to R 14 or R 21 to R 24 is not a hydrogen atom,
where: in the formulae (20-1) and (30-1):
at least one combination of adjacent two or more of R 31 to R 33 , R 41 to R 43 , R 51 to R 54 , and R 61 to R 64 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded;
R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , and R 61 to R 64 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted spirobifluorenyl group, or a group represented by the formula (4) below,
at least one of R 31 to R 34 or R 41 to R 44 is not a hydrogen atom, and
at least one of R 51 to R 54 or R 61 to R 64 is not a hydrogen atom,
in a compound represented by the formula (10-1), a combination of R 11 and R 13 and a combination of R 21 and R 23 are different combinations, or a combination of R 12 and R 14 and a combination of R 22 and R 24 are different combinations,
in a compound represented by the formula (20-1), R 31 is different from R 41 , R 32 is different from R 42 , R 33 is different from R 43 , or R 34 is different from R 44 ,
in a compound represented by the formula (30-1), R 51 is different from R 61 , R 52 is different from R 62 , R 53 is different from R 63 , or R 54 is different from R 64 , and
*1 in the formulae (10-1), (20-1), and (30-1) represents a bonding position to Py 1 in the formula (12X), and *2 represents a position of bonding to Py 2 in the formula (12X),
where: X 13 represents an oxygen atom, a sulfur atom, or NR 319 ,
at least one combination of adjacent two or more of R 311 to R 318 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded;
R 311 to R 319 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group; and
any one of R 311 to R 319 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring is a single bond bonded to at least one of R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , or R 61 to R 64 ;
in the formulae (10-1), (20-1), and (30-1) and the formula (4), a substituent for a substituted or unsubstituted group in R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , R 61 to R 64 , and R 311 to R 319 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group.
2 . The compound according to claim 1 , wherein
a compound represented by the formula (12X) is represented by a formula (120) below,
where: L 1 , L 2 , a substituted or unsubstituted 1-pyrenyl group having R 102 to R 110 , a substituted or unsubstituted 1-pyrenyl group having R 111 to R 119 each independently represent the same as Py 1 and Py 2 in the formula (12X),
L 1 represents a group represented by one of formulae (11) to (13) below, and L 2 represents a group represented by one of formulae (11A) to (13A) below;
R 102 to R 119 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms,
a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms;
Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms,
a substituent for a substituted or unsubstituted group in R 102 to R 119 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group,
where: in the formulae (11) to (13) and (11A) to (13A): R 11 to R 15 , R 21 to R 27 , R 31 to R 37 , R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms, a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms;
Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent
a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms;
a substituent for a substituted or unsubstituted group in R 11 to R 15 , R 21 to R 27 , and R 31 to R 37 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group;
at least one combination of adjacent two or more of R 11 to R 15 are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 11A to R 15A are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 21 to R 27 are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 21A to R 27A are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 31 to R 37 are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 31A to R 37A are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
in the formulae (11) to (13) representing L 1 , * represents a bonding position to *a in the formula (120), and any one of R 11 to R 15 , R 21 to R 27 , and R 31 to R 37 is a single bond bonded to L 2 ;
in the formulae (11A) to (13A) representing L 2 , * represents a position of bonding to *b in the formula (120), and any one of R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A is a single bond bonded to L 1 ;
when R 12 or R 14 in L 1 is a single bond bonded to L 2 , one of R 11A , R 13A , R 15A , R 21A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 11 or R 15 in L 1 is a single bond bonded to L 2 , one of R 12A , R 13A , R 14A , R 21A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 13 in L 1 is a single bond bonded to L 2 , one of R 11A , R 12A , R 14A , R 15A , R 21A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 21 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 22A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 22 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A , R 23A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 23 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 22A , R 24A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 24 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 23A , R 25A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 25 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 24A , R 26A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 26 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 25A , R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 27 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 26A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 31 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , and R 32A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 32 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A , and R 33A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 33 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 32A , and R 34A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 34 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 33A , and R 35A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 35 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 34A , and R 36A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 36 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 35A , and R 37A in L 2 is a single bond bonded to L 1 ; and
when R 37 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , and R 31A to R 36A in L 2 is a single bond bonded to L 1 .
3 . The compound according to claim 1 , wherein
a compound represented by the formula (12X) is represented by a formula (1), (2), or (3) below,
where: a substituted or unsubstituted 1-pyrenyl group having R 211 to R 219 represents the same as the substituent E for the substituted 1-pyrenyl group in the formula (12X), and a substituted or unsubstituted 1-pyrenyl group having R 111 to R 119 represents the same as the substituent E for the substituted 1-pyrenyl group in the formula (12X);
a substituted or unsubstituted biphenylene group having R 11 to R 14 and R 21 to R 24 in the formula (1), a substituted or unsubstituted biphenylene group with R 31 to R 34 and R 41 to R 44 in the formula (2), and a substituted or unsubstituted biphenylene group having R 51 to R 54 and R 61 to R 64 in the formula (3) each independently represent the same as -L 1 -L 2 - in the formula (12X);
R 111 to R 119 and R 211 to R 219 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms,
a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms;
Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms,
in the formula (1):
at least one combination of a combination of R 1 and R 12 , a combination of R 13 and R 14 , a combination of R 21 and R 22 , or a combination of R 23 and R 24 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded;
R 11 , R 13 , R 21 , and R 23 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, or a group represented by the formula (4) in the formulae (10-1), (20-1), and (30-1);
R 12 , R 14 , R 22 , and R 24 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, or a group represented by the formula (4) in the formulae (10-1), (20-1), and (30-1); and
at least one of R 11 to R 14 or R 21 to R 24 is not a hydrogen atom,
in the formulae (2) to (3):
at least one combination of adjacent two or more of R 31 to R 33 , R 41 to R 43 , R 51 to R 54 , and R 61 to R 64 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded;
R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , and R 61 to R 64 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, substituted or unsubstituted spirobifluorenyl group, or a group represented by the following formula (4);
at least one of R 31 to R 34 or R 41 to R 44 is not a hydrogen atom; and
at least one of R 51 to R 54 or R 61 to R 64 is not a hydrogen atom;
in a compound represented by the formula (1), a combination of R 11 and R 13 and a combination of R 21 and R 23 are different combinations, or a combination of R 12 and R 14 and a combination of R 22 and R 24 are different combinations;
in a compound represented by the formula (2), a combination of R 31 and R 41 is different from at least one combination of a combination of R 32 and R 42 , a combination of R 33 and R 43 , or a combination of R 34 and R 44 ;
in a compound represented by the formula (3), a combination of R 51 and R 61 is different from at least one combination of a combination of R 52 and R 62 , a combination of R 53 and R 63 , or a combination of R 54 and R 64 ;
in the formulae (1) to (3):
a substituent for a substituted or unsubstituted group in R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , R 61 to R 64 , R 111 to R 119 , R 211 to R 219 , and R 311 to R 319 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group.
4 . An organic electroluminescence device comprising:
an anode; a cathode; and an emitting layer between the anode and the cathode, wherein the emitting layer comprises the compound according to claim 1 as a host material.
5 . (canceled)
6 . A compound represented by a formula (120) below,
where: L 1 represents a group represented by one of formulae (11) to (13) below, and L 2 represents a group represented by one of formulae (11A) to (13A) below,
R 102 to R 119 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms,
a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms;
Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms;
a substituent for a substituted or unsubstituted group in R 102 to R 119 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group,
where: in the formulae (11) to (13) and (11A) to (13A), R 11 to R 15 , R 21 to R 27 , R 31 to R 37 , R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms, a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms;
a substituent for a substituted or unsubstituted group in R 11 to R 15 , R 21 to R 27 , and R 31 to R 37 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group;
at least one combination of adjacent two or more of R 11 to R 15 are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 11A to R 15A are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 21 to R 27 are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 21A to R 27A are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 31 to R 37 are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
at least one combination of adjacent two or more of R 31A to R 37A are not mutually bonded to form no substituted or unsubstituted monocyclic ring or to form no substituted or unsubstituted fused ring;
in L 1 represented by the formulae (11) to (13), * represents a bonding position to *a in the formula (120), and any one of R 11 to R 15 , R 21 to R 27 , and R 31 to R 37 is a single bond bonded to L 2 ;
in L 2 represented by the formulae (11A) to (13A), * represents a bonding position to *b in the formula (120), and any one of R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A is a single bond bonded to L 1 ;
when R 12 or R 14 in L 1 is a single bond bonded to L 2 , one of R 11A , R 13A , R 15A , R 21A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 11 or R 15 in L 1 is a single bond bonded to L 2 , one of R 12A , R 13A , R 14A , R 21A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 13 in L 1 is a single bond bonded to L 2 , one of R 11A , R 12A , R 14A , R 15A , R 21A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 21 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 22A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 22 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A , R 23A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 23 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 22A , R 24A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 24 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 23A , R 25A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 25 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 24A , R 26A to R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 26 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 25A , R 27A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 27 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 26A , and R 31A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 31 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , and R 32A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 32 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A , and R 33A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 33 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 32A , and R 34A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 34 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 33A , and R 35A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 35 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 34A , and R 36A to R 37A in L 2 is a single bond bonded to L 1 ;
when R 36 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , R 31A to R 35A , and R 37A in L 2 is a single bond bonded to L 1 ; and
when R 37 in L 1 is a single bond bonded to L 2 , one of R 11A to R 15A , R 21A to R 27A , and R 31A to R 36A in L 2 is a single bond bonded to L 1 .
7 . The compound according to claim 6 , wherein
-L 1 -L 2 - represents a group represented by one of the following formulae (13-1) to (13-69),
in the formulae (13-1) to (13-69):
R 11 to R 15 , R 21 to R 27 , R 31 to R 37 , R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A represent the same as R 11 to R 15 , R 21 to R 27 , R 31 to R 37 , R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A , respectively, in the formulae (11) to (13) and (11A) to (13A);
*1 in the formulae (13-1) to (13-69) represents a bonding position to *a in the formula (120); and
*2 represents a position of bonding to *b in the formula (120))
8 . The compound according to claim 6 , wherein
a compound represented by the formula (120) is represented by one of formulae (121) to (131) below,
in the formula (121) to (131):
R 11 to R 15 , R 21 to R 27 , R 31 to R 37 , R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A represent the same as R 11 to R 15 , R 21 to R 27 , R 31 to R 37 , R 11A to R 15A , R 21A to R 27A , and R 31A to R 37A , respectively, in the formulae (11) to (13) and (11A) to (13A); and
R 102 to R 119 each independently represent the same as R 102 to R 119 , respectively, in the formula (120).
9 . The compound according to claim 6 , wherein
R 11 to R 15 , R 21 to R 27 , R 31 to R 37 , R 11A to R 15A , R 21A to R 27A , R 31A to R 37A , and R 102 to R 119 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted cycloalkyl group having 1 to 30 carbon atoms, a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms, Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent an unsubstituted alkyl group having 1 to 30 carbon atoms, or an unsubstituted aryl group having 6 to 30 ring carbon atoms.
10 - 14 . (canceled)
15 . An organic electroluminescence device comprising:
an anode; a cathode; and a first emitting layer between the anode and the cathode, wherein the first emitting layer comprises the compound according to claim 6 as a first host material.
16 . The organic electroluminescence device according to claim 15 , wherein
the first emitting layer further comprises a fluorescent compound.
17 . The organic electroluminescence device according to claim 16 , wherein
a singlet energy S 1 of the first host material is larger than a singlet energy S 1 of the fluorescent compound.
18 . The organic electroluminescence device according to claim 15 , wherein
the first emitting layer does not contain a metal complex.
19 - 21 . (canceled)
22 . A compound represented by a formula (1), (2) or (3),
where: R 111 to R 119 and R 211 to R 219 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 carbon atoms, a group represented by —Si(Rx)(Ry)(Rz), a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
Rx, Ry, and Rz in —Si(Rx)(Ry)(Rz) each independently represent a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms,
in the formula (1),
at least one combination of a combination of R 11 and R 12 , a combination of R 13 and R 14 , a combination of R 21 and R 22 , or a combination of R 23 and R 24 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded,
R 11 , R 13 , R 21 , and R 23 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, or a group represented by the following formula (4),
R 12 , R 14 , R 22 , and R 24 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, or a group represented by the following formula (4); and
at least one of R 11 to R 14 or R 21 to R 24 is not a hydrogen atom,
in the formulae (2) to (3),
at least one combination of adjacent two or more of R 31 to R 33 , R 41 to R 43 , R 51 to R 54 , and R 61 to R 64 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded;
R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , and R 61 to R 64 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted spirobifluorenyl group, or a group represented by the following formula (4);
at least one of R 31 to R 34 or R 41 to R 44 is not a hydrogen atom, and
at least one of R 51 to R 54 or R 61 to R 64 is not a hydrogen atom,
in a compound represented by the formula (1), a combination of R 11 and R 13 and a combination of R 21 and R 23 are different combinations, or a combination of R 12 and R 14 and a combination of R 22 and R 24 are different combinations;
in a compound represented by the formula (2), a combination of R 31 and R 41 is different from at least one combination of a combination of R 32 and R 42 , a combination of R 33 and R 43 , or a combination of R 34 and R 44 ; and
in a compound represented by the formula (3), a combination of R 51 and R 61 is different from at least one combination of a combination of R 52 and R 62 , a combination of R 53 and R 63 , or a combination of R 54 and R 64 ,
where: X 13 represents an oxygen atom, a sulfur atom, or NR 319 ,
at least one combination of adjacent two or more of R 311 to R 318 are mutually bonded to form a substituted or unsubstituted monocyclic ring, are mutually bonded to form a substituted or unsubstituted fused ring, or are not mutually bonded;
R 311 to R 319 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group; and
any one of R 311 to R 319 that do not form the substituted or unsubstituted monocyclic ring and do not form the substituted or unsubstituted fused ring is a single bond bonded to at least one of R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , or R 61 to R 64 , in the formulae (1) to (3):
a substituent for a substituted or unsubstituted group in R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , R 61 to R 64 , R 111 to R 119 , R 211 to R 219 , and R 311 to R 319 is each independently a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted terphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted chrysenyl group, a substituted or unsubstituted triphenylenyl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, or a substituted or unsubstituted 9,9-diphenylfluorenyl group.
23 - 24 . (canceled)
25 . The compound according to claim 22 ,
represented by a formula (1-1), (2-1), or (3-1) below,
where: R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , and R 61 to R 64 represent the same as R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , and R 61 to R 64 , respectively, in the formulae (1) to (3).
26 . The compound according to claim 22 , wherein
R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , and R 61 to R 64 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 8 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, a substituted or unsubstituted 9,9-diphenylfluorenyl group, a substituted or unsubstituted dibenzofuranyl group, or a substituted or unsubstituted dibenzothiophenyl group; and R 12 , R 14 , R 22 , and R 24 each are not a substituted or unsubstituted phenyl group.
27 . The compound according to claim 22 , wherein
at least one combination of a combination of R 11 and R 12 , a combination of R 13 and R 14 , a combination of R 21 and R 22 , or a combination of R 23 and R 24 are mutually bonded to form a substituted or unsubstituted monocyclic ring or a substituted or unsubstituted fused ring, and at least one combination of adjacent two or more of R 31 to R 33 , R 41 to R 43 , R 51 to R 54 , and R 61 to R 64 are mutually bonded to form a substituted or unsubstituted monocyclic ring or a substituted or unsubstituted fused ring.
28 . The compound according to claim 27 ,
represented by one of formulae (1-2), (2-2) to (2-3), and (3-2) to (3-4) below,
where: R 13 to R 14 , R 21 to R 22 , R 31 , R 33 , R 34 , R 41 , R 43 , R 44 , R 51 to R 54 , and R 61 to R 64 represent the same as R 13 to R 14 , R 21 to R 22 , R 31 , R 33 , R 34 , R 41 , R 43 , R 44 , R 51 to R 54 , and R 61 to R 64 , respectively, in the formulae (1) to (3); and
R 301 to R 308 each independently represent the same as R 11 to R 14 , R 21 to R 24 , R 31 to R 34 , R 41 to R 44 , R 51 to R 54 , and R 61 to R 64 in the formulae (1) to (3).
29 . The compound according to claim 28 , wherein
R 13 to R 14 , R 21 to R 22 , R 31 , R 33 , R 34 , R 41 , R 43 , R 44 , R 51 to R 54 , R 61 to R 64 , and R 301 to R 308 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 8 carbon atoms, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted phenanthryl group, a substituted or unsubstituted fluorenyl group, a substituted or unsubstituted 9,9′-spirobifluorenyl group, a substituted or unsubstituted 9,9-dimethylfluorenyl group, a substituted or unsubstituted 9,9-diphenylfluorenyl group, a substituted or unsubstituted dibenzofuranyl group, or a substituted or unsubstituted dibenzothiophenyl group; and R 14 and R 22 each are not a substituted or unsubstituted phenyl group.
30 . (canceled)
31 . An organic electroluminescence device comprising:
an anode; a cathode; a first emitting layer between the anode and the cathode, wherein the first emitting layer comprises the compound according to claim 22 as a first host material.
32 . The organic electroluminescence device according to claim 31 , wherein
the first emitting layer further comprises a fluorescent compound.
33 . The organic electroluminescence device according to claim 32 , wherein
a singlet energy S 1 of the first host material is larger than a singlet energy S 1 of the fluorescent compound,
S 1 ( M 2)> S 1 ( M 1) (Numerical Formula 1).
34 . The organic electroluminescence device according to claim 31 , wherein
the first emitting layer does not contain a metal complex.
35 - 37 . (canceled)
38 . The organic electroluminescence device according to claim 15 , further comprising:
a second emitting layer between the first emitting layer and the cathode.
39 . The organic electroluminescence device according to claim 38 , wherein
the second emitting layer comprises a second compound represented by a formula (2) below as a second host material,
where:
R 201 to R 208 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted haloalkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a group represented by —Si(R 901 )(R 902 )(R 903 ), a group represented by —O—(R 904 ), a group represented by —S—(R 905 ), a group represented by —N(R 906 )(R 907 ), a substituted or unsubstituted aralkyl group having 7 to 50 carbon atoms, a group represented by —C(═O)R 801 , a group represented by —COOR 802 , a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
L 201 and L 202 each independently represent a single bond, a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 50 ring atoms, and
Ar 201 and Ar 202 each independently represent a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
in the second compound, R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 , and R 802 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
when a plurality of R 901 are present, the plurality of R 901 are mutually the same or different,
when a plurality of R 902 are present, the plurality of R 902 are mutually the same or different,
when a plurality of R 903 are present, the plurality of R 903 are mutually the same or different,
when a plurality of R 904 are present, the plurality of R 904 are mutually the same or different,
when a plurality of R 905 are present, the plurality of R 905 are mutually the same or different,
when a plurality of R 906 are present, the plurality of R 906 are mutually the same or different,
when a plurality of R 907 are present, the plurality of R 907 are mutually the same or different,
when a plurality of R 801 are present, the plurality of R 801 are mutually the same or different, and
when a plurality of R 802 are present, the plurality of R 802 are mutually the same or different.
40 . The organic electroluminescence device according to claim 22 , further comprising:
a second emitting layer between the first emitting layer and the cathode.
41 . The organic electroluminescence device according to claim 40 , wherein
the second emitting layer comprises a second compound represented by a formula (2) below as a second host material,
where:
R 201 to R 208 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted haloalkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 50 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a group represented by —Si(R 901 )(R 902 )(R 903 ), a group represented by —O—(R 904 ), a group represented by —S—(R 905 ), a group represented by —N(R 906 )(R 907 ), a substituted or unsubstituted aralkyl group having 7 to 50 carbon atoms, a group represented by —C(═O)R 801 , a group represented by —COOR 802 , a halogen atom, a cyano group, a nitro group, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
L 201 and L 202 each independently represent a single bond, a substituted or unsubstituted arylene group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted divalent heterocyclic group having 5 to 50 ring atoms, and
Ar 201 and Ar 202 each independently represent a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
in the second compound, R 901 , R 902 , R 903 , R 904 , R 905 , R 906 , R 907 , R 801 , and R 802 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, or a substituted or unsubstituted heterocyclic group having 5 to 50 ring atoms,
when a plurality of R 901 are present, the plurality of R 901 are mutually the same or different,
when a plurality of R 902 are present, the plurality of R 902 are mutually the same or different,
when a plurality of R 903 are present, the plurality of R 903 are mutually the same or different,
when a plurality of R 904 are present, the plurality of R 904 are mutually the same or different,
when a plurality of R 905 are present, the plurality of R 905 are mutually the same or different,
when a plurality of R 906 are present, the plurality of R 906 are mutually the same or different,
when a plurality of R 907 are present, the plurality of R 907 are mutually the same or different,
when a plurality of R 801 are present, the plurality of R 801 are mutually the same or different, and
when a plurality of R 02 are present, the plurality of R 802 are mutually the same or different.Join the waitlist — get patent alerts
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