US2023374050A1PendingUtilityA1
Organic electroluminescent materials and devices
Est. expiryJan 9, 2037(~10.5 yrs left)· nominal 20-yr term from priority
C07F 15/0033C09K 11/06H10K 50/81H10K 50/82H10K 85/342C09K 2211/185H10K 50/11C07D 495/04H10K 85/626H10K 85/631H10K 85/654H10K 85/6572H10K 85/657H10K 2101/10Y02E10/549H10K 50/12H10K 50/15
77
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Claims
Abstract
Novel ligands for metal complexes that are useful as phosphorescent emitters in OLEDs are disclosed. The ligands contain an aryl covalently bonded to the coordinating metal where the aryl group has at least two different alkyl side chains that are linked ortho and para compared to the linkage of the coordinating metal on that aryl group.
Claims
exact text as granted — not AI-modified1 . A compound having a formula M(L A ) x (L B ) y (L C ) z :
wherein the ligand L A has Formula I,
wherein the ligand L B has Formula II,
wherein the ligand L C has Formula III,
wherein M is a metal having an atomic weight greater than 40;
wherein x is 1, 2, or 3;
wherein y is 0, 1, or 2;
wherein z is 0, 1, or 2;
wherein x+y+z is the oxidation state of the metal M;
wherein X 1 to X 5 are each independently a carbon or nitrogen;
wherein ring A is a 5- or 6-membered aromatic ring fused to the ring having X 1 ;
wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring;
wherein R 3 , R 4 , R C , and R D each independently represents none to a maximum possible number of substitutions;
wherein each of R 3 , R 4 , R C , and R D , R X , —R Y , and R Z are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any adjacent substituents of R 3 , R 4 , R C , and R D , R X , R Y , and R Z are optionally joined or fused into a ring;
wherein R 1 and R 2 are each independently selected from the group consisting of alkyl, cycloalkyl, silyl, germanyl, and substituted variants thereof; and
wherein R 1 is different from R 2 .
2 . The compound of claim 1 , wherein M is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Au, and Cu.
3 . The compound of claim 1 , wherein the compound has a formula M(L A ) 2 (L C ) or M(L A )(L B ) 2 .
4 . The compound of claim 1 , wherein X 1 to X 4 are each a carbon.
5 . The compound of claim 1 , wherein ring A is a 5-membered aromatic ring or a 6-membered aromatic ring.
6 . The compound of claim 1 , wherein R 1 and R 2 are each independently selected from the group consisting of methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, cyclopentyl, cyclohexyl, norbornyl, adamantyl, trimethylsilyl, triethylsilyl, triisopropylsilyl, trimethylgermyl, triethylgermyl, and triisopropylgermyl, partially or fully deuterated variants thereof, partially or fully fluorinated variants thereof, and combinations thereof.
7 . The compound of claim 1 , wherein R 2 has at least two more carbon atoms than R 1 .
8 . The compound of claim 1 , wherein each of R 3 , R 4 , R C , and R D , R X , R Y , and R Z are independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, and combinations thereof.
9 . The compound of claim 1 , wherein ring C is benzene, and ring D is pyridine of which X 9 is N.
10 . The compound of claim 1 , wherein the ligand L A is selected from the group consisting of:
wherein Y is selected from the group consisting of S, O, Se, and N(CH 3 ).
11 . The compound of claim 1 , wherein the ligand L A is selected from the group consisting of L A1 through L A544 , that are based on a structure of Formula Ia,
in each of which R 1 , R 2 , R 4 , and R 5 are defined as follows:
R 1
R 2
R 4
R 5
L A1
R B1
R B3
H
H
L A2
R B1
R B3
R B1
H
L A3
R B1
R B3
R B3
H
L A4
R B1
R B3
R B4
H
L A5
R B1
R B3
R B7
H
L A6
R B1
R B3
R B12
H
L A7
R B1
R B3
R B18
H
L A8
R B1
R B3
R A3
H
L A9
R B1
R B3
R A34
H
L A10
R B1
R B4
H
H
L A11
R B1
R B4
R B1
H
L A12
R B1
R B4
R B3
H
L A13
R B1
R B4
R B4
H
L A14
R B1
R B4
R B7
H
L A15
R B1
R B4
R B12
H
L A16
R B1
R B4
R B18
H
L A17
R B1
R B4
R A3
H
L A18
R B1
R B4
R A34
H
L A19
R B1
R B5
H
H
L A20
R B1
R B5
R B1
H
L A21
R B1
R B5
R B3
H
L A22
R B1
R B5
R B4
H
L A23
R B1
R B5
R B7
H
L A24
R B1
R B5
R B12
H
L A25
R B1
R B5
R B18
H
L A26
R B1
R B5
R A3
H
L A27
R B1
R B5
R A34
H
L A28
R B1
R B6
H
H
L A29
R B1
R B6
R B1
H
L A30
R B1
R B6
R B3
H
L A31
R B1
R B6
R B4
H
L A32
R B1
R B6
R B7
H
L A33
R B1
R B6
R B12
H
L A34
R B1
R B6
R B18
H
L A35
R B1
R B6
R A3
H
L A36
R B1
R B6
R A34
H
L A37
R B1
R B7
H
H
L A38
R B1
R B7
R B1
H
L A39
R B1
R B7
R B3
H
L A40
R B1
R B7
R B4
H
L A41
R B1
R B7
R B7
H
L A42
R B1
R B7
R B12
H
L A43
R B1
R B7
R B18
H
L A44
R B1
R B7
R A3
H
L A45
R B1
R B7
R A34
H
L A46
R B1
R B12
H
H
L A47
R B1
R B12
R B1
H
L A48
R B1
R B12
R B3
H
L A49
R B1
R B12
R B4
H
L A50
R B1
R B12
R B7
H
L A51
R B1
R B12
R B12
H
L A52
R B1
R B12
R B18
H
L A53
R B1
R B12
R A3
H
L A54
R B1
R B12
R A34
H
L A55
R B1
R A34
H
H
L A56
R B1
R A34
R B1
H
L A57
R B1
R A34
R B3
H
L A58
R B1
R A34
R B4
H
L A59
R B1
R A34
R B7
H
L A60
R B1
R A34
R B12
H
L A61
R B1
R A34
R B18
H
L A62
R B1
R A34
R A3
H
L A63
R B1
R A34
R A34
H
L A64
R B3
R B4
H
H
L A65
R B3
R B4
R B1
H
L A66
R B3
R B4
R B3
H
L A67
R B3
R B4
R B4
H
L A68
R B3
R B4
R B7
H
L A69
R B3
R B4
R B12
H
L A70
R B3
R B4
R B18
H
L A71
R B3
R B4
R A3
H
L A72
R B3
R B4
R A34
H
L A73
R B3
R B5
H
H
L A74
R B3
R B5
R B1
H
L A75
R B3
R B5
R B3
H
L A76
R B3
R B5
R B4
H
L A77
R B3
R B5
R B7
H
L A78
R B3
R B5
R B12
H
L A79
R B3
R B5
R B18
H
L A80
R B3
R B5
R A3
H
L A81
R B3
R B5
R A34
H
L A82
R B3
R B6
H
H
L A83
R B3
R B6
R B1
H
L A84
R B3
R B6
R B3
H
L A85
R B3
R B6
R B4
H
L A86
R B3
R B6
R B7
H
L A87
R B3
R B6
R B12
H
L A88
R B3
R B6
R B18
H
L A89
R B3
R B6
R A3
H
L A90
R B3
R B6
R A34
H
L A91
R B3
R B7
H
H
L A92
R B3
R B7
R B1
H
L A93
R B3
R B7
R B3
H
L A94
R B3
R B7
R B4
H
L A95
R B3
R B7
R B7
H
L A96
R B3
R B7
R B12
H
L A97
R B3
R B7
R B18
H
L A98
R B3
R B7
R A3
H
L A99
R B3
R B7
R A34
H
L A100
R B3
R B12
H
H
L A101
R B3
R B12
R B1
H
L A102
R B3
R B12
R B3
H
L A103
R B3
R B12
R B4
H
L A104
R B3
R B12
R B7
H
L A105
R B3
R B12
R B12
H
L A106
R B3
R B12
R B18
H
L A107
R B3
R B12
R A3
H
L A108
R B3
R B12
R A34
H
L A109
R B3
R A34
H
H
L A110
R B3
R A34
R B1
H
L A111
R B3
R A34
R B3
H
L A112
R B3
R A34
R B4
H
L A113
R B3
R A34
R B7
H
L A114
R B3
R A34
R B12
H
L A115
R B3
R A34
R B18
H
L A116
R B3
R A34
R A3
H
L A117
R B3
R A34
R A34
H
L A118
R B4
R B3
H
H
L A119
R B4
R B3
R B1
H
L A120
R B4
R B3
R B3
H
L A121
R B4
R B3
R B4
H
L A122
R B4
R B3
R B7
H
L A123
R B4
R B3
R B12
H
L A124
R B4
R B3
R B18
H
L A125
R B4
R B3
R A3
H
L A126
R B4
R B3
R A34
H
L A127
R B4
R B5
H
H
L A128
R B4
R B5
R B1
H
L A129
R B4
R B5
R B3
H
L A130
R B4
R B5
R B4
H
L A131
R B4
R B5
R B7
H
L A132
R B4
R B5
R B12
H
L A133
R B4
R B5
R B18
H
L A134
R B4
R B5
R A3
H
L A135
R B4
R B5
R A34
H
L A136
R B4
R B6
H
H
L A137
R B4
R B6
R B1
H
L A138
R B4
R B6
R B3
H
L A139
R B4
R B6
R B4
H
L A140
R B4
R B6
R B7
H
L A141
R B4
R B6
R B12
H
L A142
R B4
R B6
R B18
H
L A143
R B4
R B6
R A3
H
L A144
R B4
R B6
R A34
H
L A145
R B4
R B7
H
H
L A146
R B4
R B7
R B1
H
L A147
R B4
R B7
R B3
H
L A148
R B4
R B7
R B4
H
L A149
R B4
R B7
R B7
H
L A150
R B4
R B7
R B12
H
L A151
R B4
R B7
R B18
H
L A152
R B4
R B7
R A3
H
L A153
R B4
R B7
R A34
H
L A154
R B4
R B12
H
H
L A155
R B4
R B12
R B1
H
L A156
R B4
R B12
R B3
H
L A157
R B4
R B12
R B4
H
L A158
R B4
R B12
R B7
H
L A159
R B4
R B12
R B12
H
L A160
R B4
R B12
R B18
H
L A161
R B4
R B12
R A3
H
L A162
R B4
R B12
R A34
H
L A163
R B4
R A34
H
H
L A164
R B4
R A34
R B1
H
L A165
R B4
R A34
R B3
H
L A166
R B4
R A34
R B4
H
L A167
R B4
R A34
R B7
H
L A168
R B4
R A34
R B12
H
L A169
R B4
R A34
R B18
H
L A170
R B4
R A34
R A3
H
L A171
R B4
R A34
R A34
H
L A172
R B7
R B3
H
H
L A173
R B7
R B3
R B1
H
L A174
R B7
R B3
R B3
H
L A175
R B7
R B3
R B4
H
L A176
R B7
R B3
R B7
H
L A177
R B7
R B3
R B12
H
L A178
R B7
R B3
R B18
H
L A179
R B7
R B3
R A3
H
L A180
R B7
R B3
R A34
H
L A181
R B7
R B4
H
H
L A182
R B7
R B4
R B1
H
L A183
R B7
R B4
R B3
H
L A184
R B7
R B4
R B4
H
L A185
R B7
R B4
R B7
H
L A186
R B7
R B4
R B12
H
L A187
R B7
R B4
R B18
H
L A188
R B7
R B4
R A3
H
L A189
R B7
R B4
R A34
H
L A190
R B7
R B5
H
H
L A191
R B7
R B5
R B1
H
L A192
R B7
R B5
R B3
H
L A193
R B7
R B5
R B4
H
L A194
R B7
R B5
R B7
H
L A195
R B7
R B5
R B12
H
L A196
R B7
R B5
R B18
H
L A197
R B7
R B5
R A3
H
L A198
R B7
R B5
R A34
H
L A199
R B7
R B6
H
H
L A200
R B7
R B6
R B1
H
L A201
R B7
R B6
R B3
H
L A202
R B7
R B6
R B4
H
L A203
R B7
R B6
R B7
H
L A204
R B7
R B6
R B12
H
L A205
R B7
R B6
R B18
H
L A206
R B7
R B6
R A3
H
L A207
R B7
R B6
R A34
H
L A208
R B7
R B12
H
H
L A209
R B7
R B12
R B1
H
L A210
R B7
R B12
R B3
H
L A211
R B7
R B12
R B4
H
L A212
R B7
R B12
R B7
H
L A213
R B7
R B12
R B12
H
L A214
R B7
R B12
R B18
H
L A215
R B7
R B12
R A3
H
L A216
R B7
R B12
R A34
H
L A217
R B7
R A34
H
H
L A218
R B7
R A34
R B1
H
L A219
R B7
R A34
R B3
H
L A220
R B7
R A34
R B4
H
L A221
R B7
R A34
R B7
H
L A222
R B7
R A34
R B12
H
L A223
R B7
R A34
R B18
H
L A224
R B7
R A34
R A3
H
L A225
R B7
R A34
R A34
H
L A226
R B43
R B3
H
H
L A227
R B43
R B3
R B1
H
L A228
R B43
R B3
R B3
H
L A229
R B43
R B3
R B4
H
L A230
R B43
R B3
R B7
H
L A231
R B43
R B3
R B12
H
L A232
R B43
R B3
R B18
H
L A233
R B43
R B3
R A3
H
L A234
R B43
R B3
R A34
H
L A235
R B43
R B4
H
H
L A236
R B43
R B4
R B1
H
L A237
R B43
R B4
R B3
H
L A238
R B43
R B4
R B4
H
L A239
R B43
R B4
R B7
H
L A240
R B43
R B4
R B12
H
L A241
R B43
R B4
R B18
H
L A242
R B43
R B4
R A3
H
L A243
R B43
R B4
R A34
H
L A244
R B43
R B5
H
H
L A245
R B43
R B5
R B1
H
L A246
R B43
R B5
R B3
H
L A247
R B43
R B5
R B4
H
L A248
R B43
R B5
R B7
H
L A249
R B43
R B5
R B12
H
L A250
R B43
R B5
R B18
H
L A251
R B43
R B5
R A3
H
L A252
R B43
R B5
R A34
H
L A253
R B43
R B6
H
H
L A254
R B43
R B6
R B1
H
L A255
R B43
R B6
R B3
H
L A256
R B43
R B6
R B4
H
L A257
R B43
R B6
R B7
H
L A258
R B43
R B6
R B12
H
L A259
R B43
R B6
R B18
H
L A260
R B43
R B6
R A3
H
L A261
R B43
R B6
R A34
H
L A262
R B43
R B7
H
H
L A263
R B43
R B7
R B1
H
L A264
R B43
R B7
R B3
H
L A265
R B43
R B7
R B4
H
L A266
R B43
R B7
R B7
H
L A267
R B43
R B7
R B12
H
L A268
R B43
R B7
R B18
H
L A269
R B43
R B7
R A3
H
L A270
R B43
R B7
R A34
H
L A271
R B43
R B12
H
H
L A272
R B43
R B12
R B1
H
L A273
R B43
R B12
R B3
H
L A274
R B43
R B12
R B4
H
L A275
R B43
R B12
R B7
H
L A276
R B43
R B12
R B12
H
L A277
R B43
R B12
R B18
H
L A278
R B43
R B12
R A3
H
L A279
R B43
R B12
R A34
H
L A280
R B43
R A34
H
H
L A281
R B43
R A34
R B1
H
L A282
R B43
R A34
R B3
H
L A283
R B43
R A34
R B4
H
L A284
R B43
R A34
R B7
H
L A285
R B43
R A34
R B12
H
L A286
R B43
R A34
R B18
H
L A287
R B43
R A34
R A3
H
L A288
R B43
R A34
R A34
H
L A289
R B1
R B3
H
R B1
L A290
R B1
R B3
H
R B3
L A291
R B1
R B3
H
R B4
L A292
R B1
R B3
H
R B7
L A293
R B1
R B3
H
R B12
L A294
R B1
R B3
H
R B18
L A295
R B1
R B3
H
R A3
L A296
R B1
R B3
H
R A34
L A297
R B1
R B4
H
R B1
L A298
R B1
R B4
H
R B3
L A299
R B1
R B4
H
R B4
L A300
R B1
R B4
H
R B7
L A301
R B1
R B4
H
R B12
L A302
R B1
R B4
H
R B18
L A303
R B1
R B4
H
R A3
L A304
R B1
R B4
H
R A34
L A305
R B1
R B5
H
R B1
L A306
R B1
R B5
H
R B3
L A307
R B1
R B5
H
R B4
L A308
R B1
R B5
H
R B7
L A309
R B1
R B5
H
R B12
L A310
R B1
R B5
H
R B18
L A311
R B1
R B5
H
R A3
L A312
R B1
R B5
H
R A34
L A313
R B1
R B6
H
R B1
L A314
R B1
R B6
H
R B3
L A315
R B1
R B6
H
R B4
L A316
R B1
R B6
H
R B7
L A317
R B1
R B6
H
R B12
L A318
R B1
R B6
H
R B18
L A319
R B1
R B6
H
R A3
L A320
R B1
R B6
H
R A34
L A321
R B1
R B7
H
R B1
L A322
R B1
R B7
H
R B3
L A323
R B1
R B7
H
R B4
L A324
R B1
R B7
H
R B7
L A325
R B1
R B7
H
R B12
L A326
R B1
R B7
H
R B18
L A327
R B1
R B7
H
R A3
L A328
R B1
R B7
H
R A34
L A329
R B1
R B12
H
R B1
L A330
R B1
R B12
H
R B3
L A331
R B1
R B12
H
R B4
L A332
R B1
R B12
H
R B7
L A333
R B1
R B12
H
R B12
L A334
R B1
R B12
H
R B18
L A335
R B1
R B12
H
R A3
L A336
R B1
R B12
H
R A34
L A337
R B1
R A34
H
R B1
L A338
R B1
R A34
H
R B3
L A339
R B1
R A34
H
R B4
L A340
R B1
R A34
H
R B7
L A341
R B1
R A34
H
R B12
L A342
R B1
R A34
H
R B18
L A343
R B1
R A34
H
R A3
L A344
R B1
R A34
H
R A34
L A345
R B3
R B4
H
R B1
L A346
R B3
R B4
H
R B3
L A347
R B3
R B4
H
R B4
L A348
R B3
R B4
H
R B7
L A349
R B3
R B4
H
R B12
L A350
R B3
R B4
H
R B18
L A351
R B3
R B4
H
R A3
L A352
R B3
R B4
H
R A34
L A353
R B3
R B5
H
R B1
L A354
R B3
R B5
H
R B3
L A355
R B3
R B5
H
R B4
L A356
R B3
R B5
H
R B7
L A357
R B3
R B5
H
R B12
L A358
R B3
R B5
H
R B18
L A359
R B3
R B5
H
R A3
L A360
R B3
R B5
H
R A34
L A361
R B3
R B6
H
R B1
L A362
R B3
R B6
H
R B3
L A363
R B3
R B6
H
R B4
L A364
R B3
R B6
H
R B7
L A365
R B3
R B6
H
R B12
L A366
R B3
R B6
H
R B18
L A367
R B3
R B6
H
R A3
L A368
R B3
R B6
H
R A34
L A369
R B3
R B7
H
R B1
L A370
R B3
R B7
H
R B3
L A371
R B3
R B7
H
R B4
L A372
R B3
R B7
H
R B7
L A373
R B3
R B7
H
R B12
L A374
R B3
R B7
H
R B18
L A375
R B3
R B7
H
R A3
L A376
R B3
R B7
H
R A34
L A377
R B3
R B12
H
R B1
L A378
R B3
R B12
H
R B3
L A379
R B3
R B12
H
R B4
L A380
R B3
R B12
H
R B7
L A381
R B3
R B12
H
R B12
L A382
R B3
R B12
H
R B18
L A383
R B3
R B12
H
R A3
L A384
R B3
R B12
H
R A34
L A385
R B3
R A34
H
R B1
L A386
R B3
R A34
H
R B3
L A387
R B3
R A34
H
R B4
L A388
R B3
R A34
H
R B7
L A389
R B3
R A34
H
R B12
L A390
R B3
R A34
H
R B18
L A391
R B3
R A34
H
R A3
L A392
R B3
R A34
H
R A34
L A393
R B4
R B3
H
R B1
L A394
R B4
R B3
H
R B3
L A395
R B4
R B3
H
R B4
L A396
R B4
R B3
H
R B7
L A397
R B4
R B3
H
R B12
L A398
R B4
R B3
H
R B18
L A399
R B4
R B3
H
R A3
L A400
R B4
R B3
H
R A34
L A401
R B4
R B5
H
R B1
L A402
R B4
R B5
H
R B3
L A403
R B4
R B5
H
R B4
L A404
R B4
R B5
H
R B7
L A405
R B4
R B5
H
R B12
L A406
R B4
R B5
H
R B18
L A407
R B4
R B5
H
R A3
L A408
R B4
R B5
H
R A34
L A409
R B4
R B6
H
R B1
L A410
R B4
R B6
H
R B3
L A411
R B4
R B6
H
R B4
L A412
R B4
R B6
H
R B7
L A413
R B4
R B6
H
R B12
L A414
R B4
R B6
H
R B18
L A415
R B4
R B6
H
R A3
L A416
R B4
R B6
H
R A34
L A417
R B4
R B7
H
R B1
L A418
R B4
R B7
H
R B3
L A419
R B4
R B7
H
R B4
L A420
R B4
R B7
H
R B7
L A421
R B4
R B7
H
R B12
L A422
R B4
R B7
H
R B18
L A423
R B4
R B7
H
R A3
L A424
R B4
R B7
H
R A34
L A425
R B4
R B12
H
R B1
L A426
R B4
R B12
H
R B3
L A427
R B4
R B12
H
R B4
L A428
R B4
R B12
H
R B7
L A429
R B4
R B12
H
R B12
L A430
R B4
R B12
H
R B18
L A431
R B4
R B12
H
R A3
L A432
R B4
R B12
H
R A34
L A433
R B4
R A34
H
R B1
L A434
R B4
R A34
H
R B3
L A435
R B4
R A34
H
R B4
L A436
R B4
R A34
H
R B7
L A437
R B4
R A34
H
R B12
L A438
R B4
R A34
H
R B18
L A439
R B4
R A34
H
R A3
L A440
R B4
R A34
H
R A34
L A441
R B7
R B3
H
R B1
L A442
R B7
R B3
H
R B3
L A443
R B7
R B3
H
R B4
L A444
R B7
R B3
H
R B7
L A445
R B7
R B3
H
R B12
L A446
R B7
R B3
H
R B18
L A447
R B7
R B3
H
R A3
L A448
R B7
R B3
H
R A34
L A449
R B7
R B4
H
R B1
L A450
R B7
R B4
H
R B3
L A451
R B7
R B4
H
R B4
L A452
R B7
R B4
H
R B7
L A453
R B7
R B4
H
R B12
L A454
R B7
R B4
H
R B18
L A455
R B7
R B4
H
R A3
L A456
R B7
R B4
H
R A34
L A457
R B7
R B5
H
R B1
L A458
R B7
R B5
H
R B3
L A459
R B7
R B5
H
R B4
L A460
R B7
R B5
H
R B7
L A461
R B7
R B5
H
R B12
L A462
R B7
R B5
H
R B18
L A463
R B7
R B5
H
R A3
L A464
R B7
R B5
H
R A34
L A465
R B7
R B6
H
R B1
L A466
R B7
R B6
H
R B3
L A467
R B7
R B6
H
R B4
L A468
R B7
R B6
H
R B7
L A469
R B7
R B6
H
R B12
L A470
R B7
R B6
H
R B18
L A471
R B7
R B6
H
R A3
L A472
R B7
R B6
H
R A34
L A473
R B7
R B12
H
R B1
L A474
R B7
R B12
H
R B3
L A475
R B7
R B12
H
R B4
L A476
R B7
R B12
H
R B7
L A477
R B7
R B12
H
R B12
L A478
R B7
R B12
H
R B18
L A479
R B7
R B12
H
R A3
L A480
R B7
R B12
H
R A34
L A481
R B7
R A34
H
R B1
L A482
R B7
R A34
H
R B3
L A483
R B7
R A34
H
R B4
L A484
R B7
R A34
H
R B7
L A485
R B7
R A34
H
R B12
L A486
R B7
R A34
H
R B18
L A487
R B7
R A34
H
R A3
L A488
R B7
R A34
H
R A34
L A489
R B43
R B3
H
R B1
L A490
R B43
R B3
H
R B3
L A491
R B43
R B3
H
R B4
L A492
R B43
R B3
H
R B7
L A493
R B43
R B3
H
R B12
L A494
R B43
R B3
H
R B18
L A495
R B43
R B3
H
R A3
L A496
R B43
R B3
H
R A34
L A497
R B43
R B4
H
R B1
L A498
R B43
R B4
H
R B3
L A499
R B43
R B4
H
R B4
L A500
R B43
R B4
H
R B7
L A501
R B43
R B4
H
R B12
L A502
R B43
R B4
H
R B18
L A503
R B43
R B4
H
R A3
L A504
R B43
R B4
H
R A34
L A505
R B43
R B5
H
R B1
L A506
R B43
R B5
H
R B3
L A507
R B43
R B5
H
R B4
L A508
R B43
R B5
H
R B7
L A509
R B43
R B5
H
R B12
L A510
R B43
R B5
H
R B18
L A511
R B43
R B5
H
R A3
L A512
R B43
R B5
H
R A34
L A513
R B43
R B6
H
R B1
L A514
R B43
R B6
H
R B3
L A515
R B43
R B6
H
R B4
L A516
R B43
R B6
H
R B7
L A517
R B43
R B6
H
R B12
L A518
R B43
R B6
H
R B18
L A519
R B43
R B6
H
R A3
L A520
R B43
R B6
H
R A34
L A521
R B43
R B7
H
R B1
L A522
R B43
R B7
H
R B3
L A523
R B43
R B7
H
R B4
L A524
R B43
R B7
H
R B7
L A525
R B43
R B7
H
R B12
L A526
R B43
R B7
H
R B18
L A527
R B43
R B7
H
R A3
L A528
R B43
R B7
H
R A34
L A529
R B43
R B12
H
R B1
L A530
R B43
R B12
H
R B3
L A531
R B43
R B12
H
R B4
L A532
R B43
R B12
H
R B7
L A533
R B43
R B12
H
R B12
L A534
R B43
R B12
H
R B18
L A535
R B43
R B12
H
R A3
L A536
R B43
R B12
H
R A34
L A537
R B43
R A34
H
R B1
L A538
R B43
R A34
H
R B3
L A539
R B43
R A34
H
R B4
L A540
R B43
R A34
H
R B7
L A541
R B43
R A34
H
R B12
L A542
R B43
R A34
H
R B18
L A543
R B43
R A34
H
R A3
L A544
R B43
R A34
H
R A34
L A545 through L A1088 , that are based on a structure of Formula Ib,
in each of which R 1 , R 2 , R 4 , and R 5 are defined as follows:
R 1
R 2
R 4
R 5
L A545
R B1
R B3
H
H
L A546
R B1
R B3
R B1
H
L A547
R B1
R B3
R B3
H
L A548
R B1
R B3
R B4
H
L A549
R B1
R B3
R B7
H
L A550
R B1
R B3
R B12
H
L A551
R B1
R B3
R B18
H
L A552
R B1
R B3
R A3
H
L A553
R B1
R B3
R A34
H
L A554
R B1
R B4
H
H
L A555
R B1
R B4
R B1
H
L A556
R B1
R B4
R B3
H
L A557
R B1
R B4
R B4
H
L A558
R B1
R B4
R B7
H
L A559
R B1
R B4
R B12
H
L A560
R B1
R B4
R B18
H
L A561
R B1
R B4
R A3
H
L A562
R B1
R B4
R A34
H
L A563
R B1
R B5
H
H
L A564
R B1
R B5
R B1
H
L A565
R B1
R B5
R B3
H
L A566
R B1
R B5
R B4
H
L A567
R B1
R B5
R B7
H
L A568
R B1
R B5
R B12
H
L A569
R B1
R B5
R B18
H
L A570
R B1
R B5
R A3
H
L A571
R B1
R B5
R A34
H
L A572
R B1
R B6
H
H
L A573
R B1
R B6
R B1
H
L A574
R B1
R B6
R B3
H
L A575
R B1
R B6
R B4
H
L A576
R B1
R B6
R B7
H
L A577
R B1
R B6
R B12
H
L A578
R B1
R B6
R B18
H
L A579
R B1
R B6
R A3
H
L A580
R B1
R B6
R A34
H
L A581
R B1
R B7
H
H
L A582
R B1
R B7
R B1
H
L A583
R B1
R B7
R B3
H
L A584
R B1
R B7
R B4
H
L A585
R B1
R B7
R B7
H
L A586
R B1
R B7
R B12
H
L A587
R B1
R B7
R B18
H
L A588
R B1
R B7
R A3
H
L A589
R B1
R B7
R A34
H
L A590
R B1
R B12
H
H
L A591
R B1
R B12
R B1
H
L A592
R B1
R B12
R B3
H
L A593
R B1
R B12
R B4
H
L A594
R B1
R B12
R B7
H
L A595
R B1
R B12
R B12
H
L A596
R B1
R B12
R B18
H
L A597
R B1
R B12
R A3
H
L A598
R B1
R B12
R A34
H
L A599
R B1
R A34
H
H
L A600
R B1
R A34
R B1
H
L A601
R B1
R A34
R B3
H
L A602
R B1
R A34
R B4
H
L A603
R B1
R A34
R B7
H
L A604
R B1
R A34
R B12
H
L A605
R B1
R A34
R B18
H
L A606
R B1
R A34
R A3
H
L A607
R B1
R A34
R A34
H
L A608
R B3
R B4
H
H
L A609
R B3
R B4
R B1
H
L A610
R B3
R B4
R B3
H
L A611
R B3
R B4
R B4
H
L A612
R B3
R B4
R B7
H
L A613
R B3
R B4
R B12
H
L A614
R B3
R B4
R B18
H
L A615
R B3
R B4
R A3
H
L A616
R B3
R B4
R A34
H
L A617
R B3
R B5
H
H
L A618
R B3
R B5
R B1
H
L A619
R B3
R B5
R B3
H
L A620
R B3
R B5
R B4
H
L A621
R B3
R B5
R B7
H
L A622
R B3
R B5
R B12
H
L A623
R B3
R B5
R B18
H
L A624
R B3
R B5
R A3
H
L A625
R B3
R B5
R A34
H
L A626
R B3
R B6
H
H
L A627
R B3
R B6
R B1
H
L A628
R B3
R B6
R B3
H
L A629
R B3
R B6
R B4
H
L A630
R B3
R B6
R B7
H
L A631
R B3
R B6
R B12
H
L A632
R B3
R B6
R B18
H
L A633
R B3
R B6
R A3
H
L A634
R B3
R B6
R A34
H
L A635
R B3
R B7
H
H
L A636
R B3
R B7
R B1
H
L A637
R B3
R B7
R B3
H
L A638
R B3
R B7
R B4
H
L A639
R B3
R B7
R B7
H
L A640
R B3
R B7
R B12
H
L A641
R B3
R B7
R B18
H
L A642
R B3
R B7
R A3
H
L A643
R B3
R B7
R A34
H
L A644
R B3
R B12
H
H
L A645
R B3
R B12
R B1
H
L A646
R B3
R B12
R B3
H
L A647
R B3
R B12
R B4
H
L A648
R B3
R B12
R B7
H
L A649
R B3
R B12
R B12
H
L A650
R B3
R B12
R B18
H
L A651
R B3
R B12
R A3
H
L A652
R B3
R B12
R A34
H
L A653
R B3
R A34
H
H
L A654
R B3
R A34
R B1
H
L A655
R B3
R A34
R B3
H
L A656
R B3
R A34
R B4
H
L A657
R B3
R A34
R B7
H
L A658
R B3
R A34
R B12
H
L A659
R B3
R A34
R B18
H
L A660
R B3
R A34
R A3
H
L A661
R B3
R A34
R A34
H
L A662
R B4
R B3
H
H
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R B4
R B3
R B1
H
L A664
R B4
R B3
R B3
H
L A665
R B4
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H
L A666
R B4
R B3
R B7
H
L A667
R B4
R B3
R B12
H
L A668
R B4
R B3
R B18
H
L A669
R B4
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R A3
H
L A670
R B4
R B3
R A34
H
L A671
R B4
R B5
H
H
L A672
R B4
R B5
R B1
H
L A673
R B4
R B5
R B3
H
L A674
R B4
R B5
R B4
H
L A675
R B4
R B5
R B7
H
L A676
R B4
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R B12
H
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R B4
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R B18
H
L A678
R B4
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R A3
H
L A679
R B4
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R A34
H
L A680
R B4
R B6
H
H
L A681
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R B6
R B1
H
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R B3
H
L A683
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R B6
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H
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H
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R B6
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H
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H
L A687
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R B6
R A3
H
L A688
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R B6
R A34
H
L A689
R B4
R B7
H
H
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R B7
R B1
H
L A691
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R B7
R B3
H
L A692
R B4
R B7
R B4
H
L A693
R B4
R B7
R B7
H
L A694
R B4
R B7
R B12
H
L A695
R B4
R B7
R B18
H
L A696
R B4
R B7
R A3
H
L A697
R B4
R B7
R A34
H
L A698
R B4
R B12
H
H
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R B4
R B12
R B1
H
L A700
R B4
R B12
R B3
H
L A701
R B4
R B12
R B4
H
L A702
R B4
R B12
R B7
H
L A703
R B4
R B12
R B12
H
L A704
R B4
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R B18
H
L A705
R B4
R B12
R A3
H
L A706
R B4
R B12
R A34
H
L A707
R B4
R A34
H
H
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R B4
R A34
R B1
H
L A709
R B4
R A34
R B3
H
L A710
R B4
R A34
R B4
H
L A711
R B4
R A34
R B7
H
L A712
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R A34
R B12
H
L A713
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R A34
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H
L A714
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R A34
R A3
H
L A715
R B4
R A34
R A34
H
L A716
R B7
R B3
H
H
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R B7
R B3
R B1
H
L A718
R B7
R B3
R B3
H
L A719
R B7
R B3
R B4
H
L A720
R B7
R B3
R B7
H
L A721
R B7
R B3
R B12
H
L A722
R B7
R B3
R B18
H
L A723
R B7
R B3
R A3
H
L A724
R B7
R B3
R A34
H
L A725
R B7
R B4
H
H
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R B7
R B4
R B1
H
L A727
R B7
R B4
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H
L A728
R B7
R B4
R B4
H
L A729
R B7
R B4
R B7
H
L A730
R B7
R B4
R B12
H
L A731
R B7
R B4
R B18
H
L A732
R B7
R B4
R A3
H
L A733
R B7
R B4
R A34
H
L A734
R B7
R B5
H
H
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R B7
R B5
R B1
H
L A736
R B7
R B5
R B3
H
L A737
R B7
R B5
R B4
H
L A738
R B7
R B5
R B7
H
L A739
R B7
R B5
R B12
H
L A740
R B7
R B5
R B18
H
L A741
R B7
R B5
R A3
H
L A742
R B7
R B5
R A34
H
L A743
R B7
R B6
H
H
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R B7
R B6
R B1
H
L A745
R B7
R B6
R B3
H
L A746
R B7
R B6
R B4
H
L A747
R B7
R B6
R B7
H
L A748
R B7
R B6
R B12
H
L A749
R B7
R B6
R B18
H
L A750
R B7
R B6
R A3
H
L A751
R B7
R B6
R A34
H
L A752
R B7
R B12
H
H
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R B7
R B12
R B1
H
L A754
R B7
R B12
R B3
H
L A755
R B7
R B12
R B4
H
L A756
R B7
R B12
R B7
H
L A757
R B7
R B12
R B12
H
L A758
R B7
R B12
R B18
H
L A759
R B7
R B12
R A3
H
L A760
R B7
R B12
R A34
H
L A761
R B7
R A34
H
H
L A762
R B7
R A34
R B1
H
L A763
R B7
R A34
R B3
H
L A764
R B7
R A34
R B4
H
L A765
R B7
R A34
R B7
H
L A766
R B7
R A34
R B12
H
L A767
R B7
R A34
R B18
H
L A768
R B7
R A34
R A3
H
L A769
R B7
R A34
R A34
H
L A770
R B43
R B3
H
H
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R B43
R B3
R B1
H
L A772
R B43
R B3
R B3
H
L A773
R B43
R B3
R B4
H
L A774
R B43
R B3
R B7
H
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R B43
R B3
R B12
H
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R B43
R B3
R B18
H
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R B43
R B3
R A3
H
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R B43
R B3
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H
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R B43
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H
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R B4
R B1
H
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R B4
R B3
H
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R B4
H
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R B43
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H
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H
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R B4
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H
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R B4
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R B43
R B4
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H
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R B43
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H
H
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R B5
R B1
H
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R B43
R B5
R B3
H
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R B43
R B5
R B4
H
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R B43
R B5
R B7
H
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R B43
R B5
R B12
H
L A794
R B43
R B5
R B18
H
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R B43
R B5
R A3
H
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R B43
R B5
R A34
H
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R B43
R B6
H
H
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R B43
R B6
R B1
H
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R B43
R B6
R B3
H
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R B43
R B6
R B4
H
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R B43
R B6
R B7
H
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R B43
R B6
R B12
H
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R B43
R B6
R B18
H
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R B43
R B6
R A3
H
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R B43
R B6
R A34
H
L A806
R B43
R B7
H
H
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R B43
R B7
R B1
H
L A808
R B43
R B7
R B3
H
L A809
R B43
R B7
R B4
H
L A810
R B43
R B7
R B7
H
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R B43
R B7
R B12
H
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R B43
R B7
R B18
H
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R B43
R B7
R A3
H
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R B43
R B7
R A34
H
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R B43
R B12
H
H
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R B43
R B12
R B1
H
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R B43
R B12
R B3
H
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R B12
R B4
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R B12
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H
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R B3
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R B3
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R B3
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R B3
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R B3
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R B4
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R B1
R B4
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R B4
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R B4
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R B4
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R B1
R B4
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R B1
R B4
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R B1
R B4
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R B5
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R B1
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R B1
R B5
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R B3
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R B1
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R B4
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R B1
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L A854
R B1
R B5
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R B1
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R A3
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R B5
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R B1
R B6
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R B1
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R B1
R B6
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R B3
L A859
R B1
R B6
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R B4
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R B1
R B6
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L A861
R B1
R B6
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R B12
L A862
R B1
R B6
H
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L A863
R B1
R B6
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R A3
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R B1
R B6
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R B1
R B7
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R B1
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R B1
R B7
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R B3
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R B7
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R B7
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R B7
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R B7
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R B7
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R B7
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R B12
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R B12
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R B3
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R B12
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R B12
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R B12
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R B12
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R B12
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R B12
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R A34
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R A34
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R A34
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R B4
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R B4
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R B4
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R B4
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R B4
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R B3
R B4
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R B4
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R B4
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R B5
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R B5
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R B5
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R B5
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R B5
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R B5
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R B5
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R B5
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R B3
R B6
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R B1
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R B3
R B6
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R B3
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R B3
R B6
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R B4
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R B3
R B6
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R B7
L A909
R B3
R B6
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R B12
L A910
R B3
R B6
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R B18
L A911
R B3
R B6
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R A3
L A912
R B3
R B6
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R B3
R B7
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R B1
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R B3
R B7
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R B3
L A915
R B3
R B7
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R B4
L A916
R B3
R B7
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R B7
L A917
R B3
R B7
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R B3
R B7
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R B7
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R B3
R B7
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R B12
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R B12
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R B3
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R B3
R B12
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R B12
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R B12
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R B12
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R B12
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R A34
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R A34
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R A34
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R A34
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R A34
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R B3
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R B3
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R B3
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R B3
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R B3
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R B3
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R B3
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R B3
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R B5
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R B5
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R B3
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R B5
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R B5
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R B5
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L A950
R B4
R B5
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R B18
L A951
R B4
R B5
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R A3
L A952
R B4
R B5
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L A953
R B4
R B6
H
R B1
L A954
R B4
R B6
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R B3
L A955
R B4
R B6
H
R B4
L A956
R B4
R B6
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R B7
L A957
R B4
R B6
H
R B12
L A958
R B4
R B6
H
R B18
L A959
R B4
R B6
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R A3
L A960
R B4
R B6
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R A34
L A961
R B4
R B7
H
R B1
L A962
R B4
R B7
H
R B3
L A963
R B4
R B7
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R B4
L A964
R B4
R B7
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R B7
L A965
R B4
R B7
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R B12
L A966
R B4
R B7
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R B18
L A967
R B4
R B7
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R A3
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R B4
R B7
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L A969
R B4
R B12
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R B1
L A970
R B4
R B12
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R B3
L A971
R B4
R B12
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R B4
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R B4
R B12
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L A973
R B4
R B12
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R B4
R B12
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L A975
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R B12
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R B12
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R B4
R A34
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R B4
R A34
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R B3
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R A34
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R A34
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R B4
R A34
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L A982
R B4
R A34
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R B18
L A983
R B4
R A34
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R A3
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R B4
R A34
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L A985
R B7
R B3
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R B1
L A986
R B7
R B3
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R B3
L A987
R B7
R B3
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R B4
L A988
R B7
R B3
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R B7
L A989
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R B3
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R B12
L A990
R B7
R B3
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R B18
L A991
R B7
R B3
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R A3
L A992
R B7
R B3
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L A993
R B7
R B4
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R B1
L A994
R B7
R B4
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R B3
L A995
R B7
R B4
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R B4
L A996
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R B4
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L A997
R B7
R B4
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R B12
L A998
R B7
R B4
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R B18
L A999
R B7
R B4
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R A3
L A1000
R B7
R B4
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R A34
L A1001
R B7
R B5
H
R B1
L A1002
R B7
R B5
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R B3
L A1003
R B7
R B5
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R B4
L A1004
R B7
R B5
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R B7
L A1005
R B7
R B5
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R B12
L A1006
R B7
R B5
H
R B18
L A1007
R B7
R B5
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R A3
L A1008
R B7
R B5
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R A34
L A1009
R B7
R B6
H
R B1
L A1010
R B7
R B6
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R B3
L A1011
R B7
R B6
H
R B4
L A1012
R B7
R B6
H
R B7
L A1013
R B7
R B6
H
R B12
L A1014
R B7
R B6
H
R B18
L A1015
R B7
R B6
H
R A3
L A1016
R B7
R B6
H
R A34
L A1017
R B7
R B12
H
R B1
L A1018
R B7
R B12
H
R B3
L A1019
R B7
R B12
H
R B4
L A1020
R B7
R B12
H
R B7
L A1021
R B7
R B12
H
R B12
L A1022
R B7
R B12
H
R B18
L A1023
R B7
R B12
H
R A3
L A1024
R B7
R B12
H
R A34
L A1025
R B7
R A34
H
R B1
L A1026
R B7
R A34
H
R B3
L A1027
R B7
R A34
H
R B4
L A1028
R B7
R A34
H
R B7
L A1029
R B7
R A34
H
R B12
L A1030
R B7
R A34
H
R B18
L A1031
R B7
R A34
H
R A3
L A1032
R B7
R A34
H
R A34
L A1033
R B43
R B3
H
R B1
L A1034
R B43
R B3
H
R B3
L A1035
R B43
R B3
H
R B4
L A1036
R B43
R B3
H
R B7
L A1037
R B43
R B3
H
R B12
L A1038
R B43
R B3
H
R B18
L A1039
R B43
R B3
H
R A3
L A1040
R B43
R B3
H
R A34
L A1041
R B43
R B4
H
R B1
L A1042
R B43
R B4
H
R B3
L A1043
R B43
R B4
H
R B4
L A1044
R B43
R B4
H
R B7
L A1045
R B43
R B4
H
R B12
L A1046
R B43
R B4
H
R B18
L A1047
R B43
R B4
H
R A3
L A1048
R B43
R B4
H
R A34
L A1049
R B43
R B5
H
R B1
L A1050
R B43
R B5
H
R B3
L A1051
R B43
R B5
H
R B4
L A1052
R B43
R B5
H
R B7
L A1053
R B43
R B5
H
R B12
L A1054
R B43
R B5
H
R B18
L A1055
R B43
R B5
H
R A3
L A1056
R B43
R B5
H
R A34
L A1057
R B43
R B6
H
R B1
L A1058
R B43
R B6
H
R B3
L A1059
R B43
R B6
H
R B4
L A1060
R B43
R B6
H
R B7
L A1061
R B43
R B6
H
R B12
L A1062
R B43
R B6
H
R B18
L A1063
R B43
R B6
H
R A3
L A1064
R B43
R B6
H
R A34
L A1065
R B43
R B7
H
R B1
L A1066
R B43
R B7
H
R B3
L A1067
R B43
R B7
H
R B4
L A1068
R B43
R B7
H
R B7
L A1069
R B43
R B7
H
R B12
L A1070
R B43
R B7
H
R B18
L A1071
R B43
R B7
H
R A3
L A1072
R B43
R B7
H
R A34
L A1073
R B43
R B12
H
R B1
L A1074
R B43
R B12
H
R B3
L A1075
R B43
R B12
H
R B4
L A1076
R B43
R B12
H
R B7
L A1077
R B43
R B12
H
R B12
L A1078
R B43
R B12
H
R B18
L A1079
R B43
R B12
H
R A3
L A1080
R B43
R B12
H
R A34
L A1081
R B43
R A34
H
R B1
L A1082
R B43
R A34
H
R B3
L A1083
R B43
R A34
H
R B4
L A1084
R B43
R A34
H
R B7
L A1085
R B43
R A34
H
R B12
L A1086
R B43
R A34
H
R B18
L A1087
R B43
R A34
H
R A3
L A1088
R B43
R A34
H
R A34
L A1089 through L A1632 , that are based on a structure of Formula Ic,
in each of which R 1 , R 2 , R 4 , and R 5 are defined as follows:
R 1
R 2
R 4
R 5
L A1089
R B1
R B3
H
H
L A1090
R B1
R B3
R B1
H
L A1091
R B1
R B3
R B3
H
L A1092
R B1
R B3
R B4
H
L A1093
R B1
R B3
R B7
H
L A1094
R B1
R B3
R B12
H
L A1095
R B1
R B3
R B18
H
L A1096
R B1
R B3
R A3
H
L A1097
R B1
R B3
R A34
H
L A1098
R B1
R B4
H
H
L A1099
R B1
R B4
R B1
H
L A1100
R B1
R B4
R B3
H
L A1101
R B1
R B4
R B4
H
L A1102
R B1
R B4
R B7
H
L A1103
R B1
R B4
R B12
H
L A1104
R B1
R B4
R B18
H
L A1105
R B1
R B4
R A3
H
L A1106
R B1
R B4
R A34
H
L A1107
R B1
R B5
H
H
L A1108
R B1
R B5
R B1
H
L A1109
R B1
R B5
R B3
H
L A1110
R B1
R B5
R B4
H
L A1111
R B1
R B5
R B7
H
L A1112
R B1
R B5
R B12
H
L A1113
R B1
R B5
R B18
H
L A1114
R B1
R B5
R A3
H
L A1115
R B1
R B5
R A34
H
L A1116
R B1
R B6
H
H
L A1117
R B1
R B6
R B1
H
L A1118
R B1
R B6
R B3
H
L A1119
R B1
R B6
R B4
H
L A1120
R B1
R B6
R B7
H
L A1121
R B1
R B6
R B12
H
L A1122
R B1
R B6
R B18
H
L A1123
R B1
R B6
R A3
H
L A1124
R B1
R B6
R A34
H
L A1125
R B1
R B7
H
H
L A1126
R B1
R B7
R B1
H
L A1127
R B1
R B7
R B3
H
L A1128
R B1
R B7
R B4
H
L A1129
R B1
R B7
R B7
H
L A1130
R B1
R B7
R B12
H
L A1131
R B1
R B7
R B18
H
L A1132
R B1
R B7
R A3
H
L A1133
R B1
R B7
R A34
H
L A1134
R B1
R B12
H
H
L A1135
R B1
R B12
R B1
H
L A1136
R B1
R B12
R B3
H
L A1137
R B1
R B12
R B4
H
L A1138
R B1
R B12
R B7
H
L A1139
R B1
R B12
R B12
H
L A1140
R B1
R B12
R B18
H
L A1141
R B1
R B12
R A3
H
L A1142
R B1
R B12
R A34
H
L A1143
R B1
R A34
H
H
L A1144
R B1
R A34
R B1
H
L A1145
R B1
R A34
R B3
H
L A1146
R B1
R A34
R B4
H
L A1147
R B1
R A34
R B7
H
L A1148
R B1
R A34
R B12
H
L A1149
R B1
R A34
R B18
H
L A1150
R B1
R A34
R A3
H
L A1151
R B1
R A34
R A34
H
L A1152
R B3
R B4
H
H
L A1153
R B3
R B4
R B1
H
L A1154
R B3
R B4
R B3
H
L A1155
R B3
R B4
R B4
H
L A1156
R B3
R B4
R B7
H
L A1157
R B3
R B4
R B12
H
L A1158
R B3
R B4
R B18
H
L A1159
R B3
R B4
R A3
H
L A1160
R B3
R B4
R A34
H
L A1161
R B3
R B5
H
H
L A1162
R B3
R B5
R B1
H
L A1163
R B3
R B5
R B3
H
L A1164
R B3
R B5
R B4
H
L A1165
R B3
R B5
R B7
H
L A1166
R B3
R B5
R B12
H
L A1167
R B3
R B5
R B18
H
L A1168
R B3
R B5
R A3
H
L A1169
R B3
R B5
R A34
H
L A1170
R B3
R B6
H
H
L A1171
R B3
R B6
R B1
H
L A1172
R B3
R B6
R B3
H
L A1173
R B3
R B6
R B4
H
L A1174
R B3
R B6
R B7
H
L A1175
R B3
R B6
R B12
H
L A1176
R B3
R B6
R B18
H
L A1177
R B3
R B6
R A3
H
L A1178
R B3
R B6
R A34
H
L A1179
R B3
R B7
H
H
L A1180
R B3
R B7
R B1
H
L A1181
R B3
R B7
R B3
H
L A1182
R B3
R B7
R B4
H
L A1183
R B3
R B7
R B7
H
L A1184
R B3
R B7
R B12
H
L A1185
R B3
R B7
R B18
H
L A1186
R B3
R B7
R A3
H
L A1187
R B3
R B7
R A34
H
L A1188
R B3
R B12
H
H
L A1189
R B3
R B12
R B1
H
L A1190
R B3
R B12
R B3
H
L A1191
R B3
R B12
R B4
H
L A1192
R B3
R B12
R B7
H
L A1193
R B3
R B12
R B12
H
L A1194
R B3
R B12
R B18
H
L A1195
R B3
R B12
R A3
H
L A1196
R B3
R B12
R A34
H
L A1197
R B3
R A34
H
H
L A1198
R B3
R A34
R B1
H
L A1199
R B3
R A34
R B3
H
L A1200
R B3
R A34
R B4
H
L A1201
R B3
R A34
R B7
H
L A1202
R B3
R A34
R B12
H
L A1203
R B3
R A34
R B18
H
L A1204
R B3
R A34
R A3
H
L A1205
R B3
R A34
R A34
H
L A1206
R B4
R B3
H
H
L A1207
R B4
R B3
R B1
H
L A1208
R B4
R B3
R B3
H
L A1209
R B4
R B3
R B4
H
L A1210
R B4
R B3
R B7
H
L A1211
R B4
R B3
R B12
H
L A1212
R B4
R B3
R B18
H
L A1213
R B4
R B3
R A3
H
L A1214
R B4
R B3
R A34
H
L A1215
R B4
R B5
H
H
L A1216
R B4
R B5
R B1
H
L A1217
R B4
R B5
R B3
H
L A1218
R B4
R B5
R B4
H
L A1219
R B4
R B5
R B7
H
L A1220
R B4
R B5
R B12
H
L A1221
R B4
R B5
R B18
H
L A1222
R B4
R B5
R A3
H
L A1223
R B4
R B5
R A34
H
L A1224
R B4
R B6
H
H
L A1225
R B4
R B6
R B1
H
L A1226
R B4
R B6
R B3
H
L A1227
R B4
R B6
R B4
H
L A1228
R B4
R B6
R B7
H
L A1229
R B4
R B6
R B12
H
L A1230
R B4
R B6
R B18
H
L A1231
R B4
R B6
R A3
H
L A1232
R B4
R B6
R A34
H
L A1233
R B4
R B7
H
H
L A1234
R B4
R B7
R B1
H
L A1235
R B4
R B7
R B3
H
L A1236
R B4
R B7
R B4
H
L A1237
R B4
R B7
R B7
H
L A1238
R B4
R B7
R B12
H
L A1239
R B4
R B7
R B18
H
L A1240
R B4
R B7
R A3
H
L A1241
R B4
R B7
R A34
H
L A1242
R B4
R B12
H
H
L A1243
R B4
R B12
R B1
H
L A1244
R B4
R B12
R B3
H
L A1245
R B4
R B12
R B4
H
L A1246
R B4
R B12
R B7
H
L A1247
R B4
R B12
R B12
H
L A1248
R B4
R B12
R B18
H
L A1249
R B4
R B12
R A3
H
L A1250
R B4
R B12
R A34
H
L A1251
R B4
R A34
H
H
L A1252
R B4
R A34
R B1
H
L A1253
R B4
R A34
R B3
H
L A1254
R B4
R A34
R B4
H
L A1255
R B4
R A34
R B7
H
L A1256
R B4
R A34
R B12
H
L A1257
R B4
R A34
R B18
H
L A1258
R B4
R A34
R A3
H
L A1259
R B4
R A34
R A34
H
L A1260
R B7
R B3
H
H
L A1261
R B7
R B3
R B1
H
L A1262
R B7
R B3
R B3
H
L A1263
R B7
R B3
R B4
H
L A1264
R B7
R B3
R B7
H
L A1265
R B7
R B3
R B12
H
L A1266
R B7
R B3
R B18
H
L A1267
R B7
R B3
R A3
H
L A1268
R B7
R B3
R A34
H
L A1269
R B7
R B4
H
H
L A1270
R B7
R B4
R B1
H
L A1271
R B7
R B4
R B3
H
L A1272
R B7
R B4
R B4
H
L A1273
R B7
R B4
R B7
H
L A1274
R B7
R B4
R B12
H
L A1275
R B7
R B4
R B18
H
L A1276
R B7
R B4
R A3
H
L A1277
R B7
R B4
R A34
H
L A1278
R B7
R B5
H
H
L A1279
R B7
R B5
R B1
H
L A1280
R B7
R B5
R B3
H
L A1281
R B7
R B5
R B4
H
L A1282
R B7
R B5
R B7
H
L A1283
R B7
R B5
R B12
H
L A1284
R B7
R B5
R B18
H
L A1285
R B7
R B5
R A3
H
L A1286
R B7
R B5
R A34
H
L A1287
R B7
R B6
H
H
L A1288
R B7
R B6
R B1
H
L A1289
R B7
R B6
R B3
H
L A1290
R B7
R B6
R B4
H
L A1291
R B7
R B6
R B7
H
L A1292
R B7
R B6
R B12
H
L A1293
R B7
R B6
R B18
H
L A1294
R B7
R B6
R A3
H
L A1295
R B7
R B6
R A34
H
L A1296
R B7
R B12
H
H
L A1297
R B7
R B12
R B1
H
L A1298
R B7
R B12
R B3
H
L A1299
R B7
R B12
R B4
H
L A1300
R B7
R B12
R B7
H
L A1301
R B7
R B12
R B12
H
L A1302
R B7
R B12
R B18
H
L A1303
R B7
R B12
R A3
H
L A1304
R B7
R B12
R A34
H
L A1305
R B7
R A34
H
H
L A1306
R B7
R A34
R B1
H
L A1307
R B7
R A34
R B3
H
L A1308
R B7
R A34
R B4
H
L A1309
R B7
R A34
R B7
H
L A1310
R B7
R A34
R B12
H
L A1311
R B7
R A34
R B18
H
L A1312
R B7
R A34
R A3
H
L A1313
R B7
R A34
R A34
H
L A1314
R B43
R B3
H
H
L A1315
R B43
R B3
R B1
H
L A1316
R B43
R B3
R B3
H
L A1317
R B43
R B3
R B4
H
L A1318
R B43
R B3
R B7
H
L A1319
R B43
R B3
R B12
H
L A1320
R B43
R B3
R B18
H
L A1321
R B43
R B3
R A3
H
L A1322
R B43
R B3
R A34
H
L A1323
R B43
R B4
H
H
L A1324
R B43
R B4
R B1
H
L A1325
R B43
R B4
R B3
H
L A1326
R B43
R B4
R B4
H
L A1327
R B43
R B4
R B7
H
L A1328
R B43
R B4
R B12
H
L A1329
R B43
R B4
R B18
H
L A1330
R B43
R B4
R A3
H
L A1331
R B43
R B4
R A34
H
L A1332
R B43
R B5
H
H
L A1333
R B43
R B5
R B1
H
L A1334
R B43
R B5
R B3
H
L A1335
R B43
R B5
R B4
H
L A1336
R B43
R B5
R B7
H
L A1337
R B43
R B5
R B12
H
L A1338
R B43
R B5
R B18
H
L A1339
R B43
R B5
R A3
H
L A1340
R B43
R B5
R A34
H
L A1341
R B43
R B6
H
H
L A1342
R B43
R B6
R B1
H
L A1343
R B43
R B6
R B3
H
L A1344
R B43
R B6
R B4
H
L A1345
R B43
R B6
R B7
H
L A1346
R B43
R B6
R B12
H
L A1347
R B43
R B6
R B18
H
L A1348
R B43
R B6
R A3
H
L A1349
R B43
R B6
R A34
H
L A1350
R B43
R B7
H
H
L A1351
R B43
R B7
R B1
H
L A1352
R B43
R B7
R B3
H
L A1353
R B43
R B7
R B4
H
L A1354
R B43
R B7
R B7
H
L A1355
R B43
R B7
R B12
H
L A1356
R B43
R B7
R B18
H
L A1357
R B43
R B7
R A3
H
L A1358
R B43
R B7
R A34
H
L A1359
R B43
R B12
H
H
L A1360
R B43
R B12
R B1
H
L A1361
R B43
R B12
R B3
H
L A1362
R B43
R B12
R B4
H
L A1363
R B43
R B12
R B7
H
L A1364
R B43
R B12
R B12
H
L A1365
R B43
R B12
R B18
H
L A1366
R B43
R B12
R A3
H
L A1367
R B43
R B12
R A34
H
L A1368
R B43
R A34
H
H
L A1369
R B43
R A34
R B1
H
L A1370
R B43
R A34
R B3
H
L A1371
R B43
R A34
R B4
H
L A1372
R B43
R A34
R B7
H
L A1373
R B43
R A34
R B12
H
L A1374
R B43
R A34
R B18
H
L A1375
R B43
R A34
R A3
H
L A1376
R B43
R A34
R A34
H
L A1377
R B1
R B3
H
R B1
L A1378
R B1
R B3
H
R B3
L A1379
R B1
R B3
H
R B4
L A1380
R B1
R B3
H
R B7
L A1381
R B1
R B3
H
R B12
L A1382
R B1
R B3
H
R B18
L A1383
R B1
R B3
H
R A3
L A1384
R B1
R B3
H
R A34
L A1385
R B1
R B4
H
R B1
L A1386
R B1
R B4
H
R B3
L A1387
R B1
R B4
H
R B4
L A1388
R B1
R B4
H
R B7
L A1389
R B1
R B4
H
R B12
L A1390
R B1
R B4
H
R B18
L A1391
R B1
R B4
H
R A3
L A1392
R B1
R B4
H
R A34
L A1393
R B1
R B5
H
R B1
L A1394
R B1
R B5
H
R B3
L A1395
R B1
R B5
H
R B4
L A1396
R B1
R B5
H
R B7
L A1397
R B1
R B5
H
R B12
L A1398
R B1
R B5
H
R B18
L A1399
R B1
R B5
H
R A3
L A1400
R B1
R B5
H
R A34
L A1401
R B1
R B6
H
R B1
L A1402
R B1
R B6
H
R B3
L A1403
R B1
R B6
H
R B4
L A1404
R B1
R B6
H
R B7
L A1405
R B1
R B6
H
R B12
L A1406
R B1
R B6
H
R B18
L A1407
R B1
R B6
H
R A3
L A1408
R B1
R B6
H
R A34
L A1409
R B1
R B7
H
R B1
L A1410
R B1
R B7
H
R B3
L A1411
R B1
R B7
H
R B4
L A1412
R B1
R B7
H
R B7
L A1413
R B1
R B7
H
R B12
L A1414
R B1
R B7
H
R B18
L A1415
R B1
R B7
H
R A3
L A1416
R B1
R B7
H
R A34
L A1417
R B1
R B12
H
R B1
L A1418
R B1
R B12
H
R B3
L A1419
R B1
R B12
H
R B4
L A1420
R B1
R B12
H
R B7
L A1421
R B1
R B12
H
R B12
L A1422
R B1
R B12
H
R B18
L A1423
R B1
R B12
H
R A3
L A1424
R B1
R B12
H
R A34
L A1425
R B1
R A34
H
R B1
L A1426
R B1
R A34
H
R B3
L A1427
R B1
R A34
H
R B4
L A1428
R B1
R A34
H
R B7
L A1429
R B1
R A34
H
R B12
L A1430
R B1
R A34
H
R B18
L A1431
R B1
R A34
H
R A3
L A1432
R B1
R A34
H
R A34
L A1433
R B3
R B4
H
R B1
L A1434
R B3
R B4
H
R B3
L A1435
R B3
R B4
H
R B4
L A1436
R B3
R B4
H
R B7
L A1437
R B3
R B4
H
R B12
L A1438
R B3
R B4
H
R B18
L A1439
R B3
R B4
H
R A3
L A1440
R B3
R B4
H
R A34
L A1441
R B3
R B5
H
R B1
L A1442
R B3
R B5
H
R B3
L A1443
R B3
R B5
H
R B4
L A1444
R B3
R B5
H
R B7
L A1445
R B3
R B5
H
R B12
L A1446
R B3
R B5
H
R B18
L A1447
R B3
R B5
H
R A3
L A1448
R B3
R B5
H
R A34
L A1449
R B3
R B6
H
R B1
L A1450
R B3
R B6
H
R B3
L A1451
R B3
R B6
H
R B4
L A1452
R B3
R B6
H
R B7
L A1453
R B3
R B6
H
R B12
L A1454
R B3
R B6
H
R B18
L A1455
R B3
R B6
H
R A3
L A1456
R B3
R B6
H
R A34
L A1457
R B3
R B7
H
R B1
L A1458
R B3
R B7
H
R B3
L A1459
R B3
R B7
H
R B4
L A1460
R B3
R B7
H
R B7
L A1461
R B3
R B7
H
R B12
L A1462
R B3
R B7
H
R B18
L A1463
R B3
R B7
H
R A3
L A1464
R B3
R B7
H
R A34
L A1465
R B3
R B12
H
R B1
L A1466
R B3
R B12
H
R B3
L A1467
R B3
R B12
H
R B4
L A1468
R B3
R B12
H
R B7
L A1469
R B3
R B12
H
R B12
L A1470
R B3
R B12
H
R B18
L A1471
R B3
R B12
H
R A3
L A1472
R B3
R B12
H
R A34
L A1473
R B3
R A34
H
R B1
L A1474
R B3
R A34
H
R B3
L A1475
R B3
R A34
H
R B4
L A1476
R B3
R A34
H
R B7
L A1477
R B3
R A34
H
R B12
L A1478
R B3
R A34
H
R B18
L A1479
R B3
R A34
H
R A3
L A1480
R B3
R A34
H
R A34
L A1481
R B4
R B3
H
R B1
L A1482
R B4
R B3
H
R B3
L A1483
R B4
R B3
H
R B4
L A1484
R B4
R B3
H
R B7
L A1485
R B4
R B3
H
R B12
L A1486
R B4
R B3
H
R B18
L A1487
R B4
R B3
H
R A3
L A1488
R B4
R B3
H
R A34
L A1489
R B4
R B5
H
R B1
L A1490
R B4
R B5
H
R B3
L A1491
R B4
R B5
H
R B4
L A1492
R B4
R B5
H
R B7
L A1493
R B4
R B5
H
R B12
L A1494
R B4
R B5
H
R B18
L A1495
R B4
R B5
H
R A3
L A1496
R B4
R B5
H
R A34
L A1497
R B4
R B6
H
R B1
L A1498
R B4
R B6
H
R B3
L A1499
R B4
R B6
H
R B4
L A1500
R B4
R B6
H
R B7
L A1501
R B4
R B6
H
R B12
L A1502
R B4
R B6
H
R B18
L A1503
R B4
R B6
H
R A3
L A1504
R B4
R B6
H
R A34
L A1505
R B4
R B7
H
R B1
L A1506
R B4
R B7
H
R B3
L A1507
R B4
R B7
H
R B4
L A1508
R B4
R B7
H
R B7
L A1509
R B4
R B7
H
R B12
L A1510
R B4
R B7
H
R B18
L A1511
R B4
R B7
H
R A3
L A1512
R B4
R B7
H
R A34
L A1513
R B4
R B12
H
R B1
L A1514
R B4
R B12
H
R B3
L A1515
R B4
R B12
H
R B4
L A1516
R B4
R B12
H
R B7
L A1517
R B4
R B12
H
R B12
L A1518
R B4
R B12
H
R B18
L A1519
R B4
R B12
H
R A3
L A1520
R B4
R B12
H
R A34
L A1521
R B4
R A34
H
R B1
L A1522
R B4
R A34
H
R B3
L A1523
R B4
R A34
H
R B4
L A1524
R B4
R A34
H
R B7
L A1525
R B4
R A34
H
R B12
L A1526
R B4
R A34
H
R B18
L A1527
R B4
R A34
H
R A3
L A1528
R B4
R A34
H
R A34
L A1529
R B7
R B3
H
R B1
L A1530
R B7
R B3
H
R B3
L A1531
R B7
R B3
H
R B4
L A1532
R B7
R B3
H
R B7
L A1533
R B7
R B3
H
R B12
L A1534
R B7
R B3
H
R B18
L A1535
R B7
R B3
H
R A3
L A1536
R B7
R B3
H
R A34
L A1537
R B7
R B4
H
R B1
L A1538
R B7
R B4
H
R B3
L A1539
R B7
R B4
H
R B4
L A1540
R B7
R B4
H
R B7
L A1541
R B7
R B4
H
R B12
L A1542
R B7
R B4
H
R B18
L A1543
R B7
R B4
H
R A3
L A1544
R B7
R B4
H
R A34
L A1545
R B7
R B5
H
R B1
L A1546
R B7
R B5
H
R B3
L A1547
R B7
R B5
H
R B4
L A1548
R B7
R B5
H
R B7
L A1549
R B7
R B5
H
R B12
L A1550
R B7
R B5
H
R B18
L A1551
R B7
R B5
H
R A3
L A1552
R B7
R B5
H
R A34
L A1553
R B7
R B6
H
R B1
L A1554
R B7
R B6
H
R B3
L A1555
R B7
R B6
H
R B4
L A1556
R B7
R B6
H
R B7
L A1557
R B7
R B6
H
R B12
L A1558
R B7
R B6
H
R B18
L A1559
R B7
R B6
H
R A3
L A1560
R B7
R B6
H
R A34
L A1561
R B7
R B12
H
R B1
L A1562
R B7
R B12
H
R B3
L A1563
R B7
R B12
H
R B4
L A1564
R B7
R B12
H
R B7
L A1565
R B7
R B12
H
R B12
L A1566
R B7
R B12
H
R B18
L A1567
R B7
R B12
H
R A3
L A1568
R B7
R B12
H
R A34
L A1569
R B7
R A34
H
R B1
L A1570
R B7
R A34
H
R B3
L A1571
R B7
R A34
H
R B4
L A1572
R B7
R A34
H
R B7
L A1573
R B7
R A34
H
R B12
L A1574
R B7
R A34
H
R B18
L A1575
R B7
R A34
H
R A3
L A1576
R B7
R A34
H
R A34
L A1577
R B43
R B3
H
R B1
L A1578
R B43
R B3
H
R B3
L A1579
R B43
R B3
H
R B4
L A1580
R B43
R B3
H
R B7
L A1581
R B43
R B3
H
R B12
L A1582
R B43
R B3
H
R B18
L A1583
R B43
R B3
H
R A3
L A1584
R B43
R B3
H
R A34
L A1585
R B43
R B4
H
R B1
L A1586
R B43
R B4
H
R B3
L A1587
R B43
R B4
H
R B4
L A1588
R B43
R B4
H
R B7
L A1589
R B43
R B4
H
R B12
L A1590
R B43
R B4
H
R B18
L A1591
R B43
R B4
H
R A3
L A1592
R B43
R B4
H
R A34
L A1593
R B43
R B5
H
R B1
L A1594
R B43
R B5
H
R B3
L A1595
R B43
R B5
H
R B4
L A1596
R B43
R B5
H
R B7
L A1597
R B43
R B5
H
R B12
L A1598
R B43
R B5
H
R B18
L A1599
R B43
R B5
H
R A3
L A1600
R B43
R B5
H
R A34
L A1601
R B43
R B6
H
R B1
L A1602
R B43
R B6
H
R B3
L A1603
R B43
R B6
H
R B4
L A1604
R B43
R B6
H
R B7
L A1605
R B43
R B6
H
R B12
L A1606
R B43
R B6
H
R B18
L A1607
R B43
R B6
H
R A3
L A1608
R B43
R B6
H
R A34
L A1609
R B43
R B7
H
R B1
L A1610
R B43
R B7
H
R B3
L A1611
R B43
R B7
H
R B4
L A1612
R B43
R B7
H
R B7
L A1613
R B43
R B7
H
R B12
L A1614
R B43
R B7
H
R B18
L A1615
R B43
R B7
H
R A3
L A1616
R B43
R B7
H
R A34
L A1617
R B43
R B12
H
R B1
L A1618
R B43
R B12
H
R B3
L A1619
R B43
R B12
H
R B4
L A1620
R B43
R B12
H
R B7
L A1621
R B43
R B12
H
R B12
L A1622
R B43
R B12
H
R B18
L A1623
R B43
R B12
H
R A3
L A1624
R B43
R B12
H
R A34
L A1625
R B43
R A34
H
R B1
L A1626
R B43
R A34
H
R B3
L A1627
R B43
R A34
H
R B4
L A1628
R B43
R A34
H
R B7
L A1629
R B43
R A34
H
R B12
L A1630
R B43
R A34
H
R B18
L A1631
R B43
R A34
H
R A3
L A1632
R B43
R A34
H
R A34
L A1633 through L A2176 , that are based on a structure of Formula Id,
in each of which R 1 , R 2 , R 4 , and R 5 are defined as follows:
R 1
R 2
R 4
R 5
L A1633
R B1
R B3
H
H
L A1634
R B1
R B3
R B1
H
L A1635
R B1
R B3
R B3
H
L A1636
R B1
R B3
R B4
H
L A1637
R B1
R B3
R B7
H
L A1638
R B1
R B3
R B12
H
L A1639
R B1
R B3
R B18
H
L A1640
R B1
R B3
R A3
H
L A1641
R B1
R B3
R A34
H
L A1642
R B1
R B4
H
H
L A1643
R B1
R B4
R B1
H
L A1644
R B1
R B4
R B3
H
L A1645
R B1
R B4
R B4
H
L A1646
R B1
R B4
R B7
H
L A1647
R B1
R B4
R B12
H
L A1648
R B1
R B4
R B18
H
L A1649
R B1
R B4
R A3
H
L A1650
R B1
R B4
R A34
H
L A1651
R B1
R B5
H
H
L A1652
R B1
R B5
R B1
H
L A1653
R B1
R B5
R B3
H
L A1654
R B1
R B5
R B4
H
L A1655
R B1
R B5
R B7
H
L A1656
R B1
R B5
R B12
H
L A1657
R B1
R B5
R B18
H
L A1658
R B1
R B5
R A3
H
L A1659
R B1
R B5
R A34
H
L A1660
R B1
R B6
H
H
L A1661
R B1
R B6
R B1
H
L A1662
R B1
R B6
R B3
H
L A1663
R B1
R B6
R B4
H
L A1664
R B1
R B6
R B7
H
L A1665
R B1
R B6
R B12
H
L A1666
R B1
R B6
R B18
H
L A1667
R B1
R B6
R A3
H
L A1668
R B1
R B6
R A34
H
L A1669
R B1
R B7
H
H
L A1670
R B1
R B7
R B1
H
L A1671
R B1
R B7
R B3
H
L A1672
R B1
R B7
R B4
H
L A1673
R B1
R B7
R B7
H
L A1674
R B1
R B7
R B12
H
L A1675
R B1
R B7
R B18
H
L A1676
R B1
R B7
R A3
H
L A1677
R B1
R B7
R A34
H
L A1678
R B1
R B12
H
H
L A1679
R B1
R B12
R B1
H
L A1680
R B1
R B12
R B3
H
L A1681
R B1
R B12
R B4
H
L A1682
R B1
R B12
R B7
H
L A1683
R B1
R B12
R B12
H
L A1684
R B1
R B12
R B18
H
L A1685
R B1
R B12
R A3
H
L A1686
R B1
R B12
R A34
H
L A1687
R B1
R A34
H
H
L A1688
R B1
R A34
R B1
H
L A1689
R B1
R A34
R B3
H
L A1690
R B1
R A34
R B4
H
L A1691
R B1
R A34
R B7
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L A1692
R B1
R A34
R B12
H
L A1693
R B1
R A34
R B18
H
L A1694
R B1
R A34
R A3
H
L A1695
R B1
R A34
R A34
H
L A1696
R B3
R B4
H
H
L A1697
R B3
R B4
R B1
H
L A1698
R B3
R B4
R B3
H
L A1699
R B3
R B4
R B4
H
L A1700
R B3
R B4
R B7
H
L A1701
R B3
R B4
R B12
H
L A1702
R B3
R B4
R B18
H
L A1703
R B3
R B4
R A3
H
L A1704
R B3
R B4
R A34
H
L A1705
R B3
R B5
H
H
L A1706
R B3
R B5
R B1
H
L A1707
R B3
R B5
R B3
H
L A1708
R B3
R B5
R B4
H
L A1709
R B3
R B5
R B7
H
L A1710
R B3
R B5
R B12
H
L A1711
R B3
R B5
R B18
H
L A1712
R B3
R B5
R A3
H
L A1713
R B3
R B5
R A34
H
L A1714
R B3
R B6
H
H
L A1715
R B3
R B6
R B1
H
L A1716
R B3
R B6
R B3
H
L A1717
R B3
R B6
R B4
H
L A1718
R B3
R B6
R B7
H
L A1719
R B3
R B6
R B12
H
L A1720
R B3
R B6
R B18
H
L A1721
R B3
R B6
R A3
H
L A1722
R B3
R B6
R A34
H
L A1723
R B3
R B7
H
H
L A1724
R B3
R B7
R B1
H
L A1725
R B3
R B7
R B3
H
L A1726
R B3
R B7
R B4
H
L A1727
R B3
R B7
R B7
H
L A1728
R B3
R B7
R B12
H
L A1729
R B3
R B7
R B18
H
L A1730
R B3
R B7
R A3
H
L A1731
R B3
R B7
R A34
H
L A1732
R B3
R B12
H
H
L A1733
R B3
R B12
R B1
H
L A1734
R B3
R B12
R B3
H
L A1735
R B3
R B12
R B4
H
L A1736
R B3
R B12
R B7
H
L A1737
R B3
R B12
R B12
H
L A1738
R B3
R B12
R B18
H
L A1739
R B3
R B12
R A3
H
L A1740
R B3
R B12
R A34
H
L A1741
R B3
R A34
H
H
L A1742
R B3
R A34
R B1
H
L A1743
R B3
R A34
R B3
H
L A1744
R B3
R A34
R B4
H
L A1745
R B3
R A34
R B7
H
L A1746
R B3
R A34
R B12
H
L A1747
R B3
R A34
R B18
H
L A1748
R B3
R A34
R A3
H
L A1749
R B3
R A34
R A34
H
L A1750
R B4
R B3
H
H
L A1751
R B4
R B3
R B1
H
L A1752
R B4
R B3
R B3
H
L A1753
R B4
R B3
R B4
H
L A1754
R B4
R B3
R B7
H
L A1755
R B4
R B3
R B12
H
L A1756
R B4
R B3
R B18
H
L A1757
R B4
R B3
R A3
H
L A1758
R B4
R B3
R A34
H
L A1759
R B4
R B5
H
H
L A1760
R B4
R B5
R B1
H
L A1761
R B4
R B5
R B3
H
L A1762
R B4
R B5
R B4
H
L A1763
R B4
R B5
R B7
H
L A1764
R B4
R B5
R B12
H
L A1765
R B4
R B5
R B18
H
L A1766
R B4
R B5
R A3
H
L A1767
R B4
R B5
R A34
H
L A1768
R B4
R B6
H
H
L A1769
R B4
R B6
R B1
H
L A1770
R B4
R B6
R B3
H
L A1771
R B4
R B6
R B4
H
L A1772
R B4
R B6
R B7
H
L A1773
R B4
R B6
R B12
H
L A1774
R B4
R B6
R B18
H
L A1775
R B4
R B6
R A3
H
L A1776
R B4
R B6
R A34
H
L A1777
R B4
R B7
H
H
L A1778
R B4
R B7
R B1
H
L A1779
R B4
R B7
R B3
H
L A1780
R B4
R B7
R B4
H
L A1781
R B4
R B7
R B7
H
L A1782
R B4
R B7
R B12
H
L A1783
R B4
R B7
R B18
H
L A1784
R B4
R B7
R A3
H
L A1785
R B4
R B7
R A34
H
L A1786
R B4
R B12
H
H
L A1787
R B4
R B12
R B1
H
L A1788
R B4
R B12
R B3
H
L A1789
R B4
R B12
R B4
H
L A1790
R B4
R B12
R B7
H
L A1791
R B4
R B12
R B12
H
L A1792
R B4
R B12
R B18
H
L A1793
R B4
R B12
R A3
H
L A1794
R B4
R B12
R A34
H
L A1795
R B4
R A34
H
H
L A1796
R B4
R A34
R B1
H
L A1797
R B4
R A34
R B3
H
L A1798
R B4
R A34
R B4
H
L A1799
R B4
R A34
R B7
H
L A1800
R B4
R A34
R B12
H
L A1801
R B4
R A34
R B18
H
L A1802
R B4
R A34
R A3
H
L A1803
R B4
R A34
R A34
H
L A1804
R B7
R B3
H
H
L A1805
R B7
R B3
R B1
H
L A1806
R B7
R B3
R B3
H
L A1807
R B7
R B3
R B4
H
L A1808
R B7
R B3
R B7
H
L A1809
R B7
R B3
R B12
H
L A1810
R B7
R B3
R B18
H
L A1811
R B7
R B3
R A3
H
L A1812
R B7
R B3
R A34
H
L A1813
R B7
R B4
H
H
L A1814
R B7
R B4
R B1
H
L A1815
R B7
R B4
R B3
H
L A1816
R B7
R B4
R B4
H
L A1817
R B7
R B4
R B7
H
L A1818
R B7
R B4
R B12
H
L A1819
R B7
R B4
R B18
H
L A1820
R B7
R B4
R A3
H
L A1821
R B7
R B4
R A34
H
L A1822
R B7
R B5
H
H
L A1823
R B7
R B5
R B1
H
L A1824
R B7
R B5
R B3
H
L A1825
R B7
R B5
R B4
H
L A1826
R B7
R B5
R B7
H
L A1827
R B7
R B5
R B12
H
L A1828
R B7
R B5
R B18
H
L A1829
R B7
R B5
R A3
H
L A1830
R B7
R B5
R A34
H
L A1831
R B7
R B6
H
H
L A1832
R B7
R B6
R B1
H
L A1833
R B7
R B6
R B3
H
L A1834
R B7
R B6
R B4
H
L A1835
R B7
R B6
R B7
H
L A1836
R B7
R B6
R B12
H
L A1837
R B7
R B6
R B18
H
L A1838
R B7
R B6
R A3
H
L A1839
R B7
R B6
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H
L A1840
R B7
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H
H
L A1841
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R B12
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H
L A1842
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R B12
R B3
H
L A1843
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R B12
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L A1844
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R B7
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L A1845
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R B12
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L A1846
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H
L A1847
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H
L A1848
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H
L A1849
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H
L A1850
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H
L A1851
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L A1852
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L A1853
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L A1854
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H
L A1855
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L A1856
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L A1857
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L A1858
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H
L A1859
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L A1860
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R B3
R B3
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L A1861
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R B3
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L A1862
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L A1863
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L A1864
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L A1865
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L A1866
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L A1867
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H
L A1868
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L A1869
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R B4
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L A1870
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L A1871
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L A1872
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L A1873
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L A1874
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L A1875
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L A1876
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H
L A1877
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L A1878
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L A1879
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L A1880
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L A1881
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L A1882
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L A1884
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L A1885
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H
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L A1887
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L A1888
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L A1889
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R B7
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L A1890
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L A1891
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L A1892
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L A1893
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H
L A1894
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H
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L A1896
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R B7
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L A1897
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R B7
R B4
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L A1898
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R B7
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L A1899
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H
L A1900
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H
L A1901
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H
L A1902
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H
L A1903
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H
L A1904
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R B1
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L A1905
R B43
R B12
R B3
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L A1906
R B43
R B12
R B4
H
L A1907
R B43
R B12
R B7
H
L A1908
R B43
R B12
R B12
H
L A1909
R B43
R B12
R B18
H
L A1910
R B43
R B12
R A3
H
L A1911
R B43
R B12
R A34
H
L A1912
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R A34
H
H
L A1913
R B43
R A34
R B1
H
L A1914
R B43
R A34
R B3
H
L A1915
R B43
R A34
R B4
H
L A1916
R B43
R A34
R B7
H
L A1917
R B43
R A34
R B12
H
L A1918
R B43
R A34
R B18
H
L A1919
R B43
R A34
R A3
H
L A1920
R B43
R A34
R A34
H
L A1921
R B1
R B3
H
R B1
L A1922
R B1
R B3
H
R B3
L A1923
R B1
R B3
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R B4
L A1924
R B1
R B3
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R B7
L A1925
R B1
R B3
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R B12
L A1926
R B1
R B3
H
R B18
L A1927
R B1
R B3
H
R A3
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R B1
R B3
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R A34
L A1929
R B1
R B4
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R B1
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R B1
R B4
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R B3
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R B4
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R B4
L A1932
R B1
R B4
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R B7
L A1933
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R B4
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R B12
L A1934
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R B4
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R B18
L A1935
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R B4
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R A3
L A1936
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R B4
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R A34
L A1937
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R B5
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R B1
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R B1
R B5
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R B3
L A1939
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R B5
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R B4
L A1940
R B1
R B5
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R B7
L A1941
R B1
R B5
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R B12
L A1942
R B1
R B5
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R B18
L A1943
R B1
R B5
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R A3
L A1944
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R B5
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R A34
L A1945
R B1
R B6
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R B1
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R B6
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R B3
L A1947
R B1
R B6
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R B4
L A1948
R B1
R B6
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R B7
L A1949
R B1
R B6
H
R B12
L A1950
R B1
R B6
H
R B18
L A1951
R B1
R B6
H
R A3
L A1952
R B1
R B6
H
R A34
L A1953
R B1
R B7
H
R B1
L A1954
R B1
R B7
H
R B3
L A1955
R B1
R B7
H
R B4
L A1956
R B1
R B7
H
R B7
L A1957
R B1
R B7
H
R B12
L A1958
R B1
R B7
H
R B18
L A1959
R B1
R B7
H
R A3
L A1960
R B1
R B7
H
R A34
L A1961
R B1
R B12
H
R B1
L A1962
R B1
R B12
H
R B3
L A1963
R B1
R B12
H
R B4
L A1964
R B1
R B12
H
R B7
L A1965
R B1
R B12
H
R B12
L A1966
R B1
R B12
H
R B18
L A1967
R B1
R B12
H
R A3
L A1968
R B1
R B12
H
R A34
L A1969
R B1
R A34
H
R B1
L A1970
R B1
R A34
H
R B3
L A1971
R B1
R A34
H
R B4
L A1972
R B1
R A34
H
R B7
L A1973
R B1
R A34
H
R B12
L A1974
R B1
R A34
H
R B18
L A1975
R B1
R A34
H
R A3
L A1976
R B1
R A34
H
R A34
L A1977
R B3
R B4
H
R B1
L A1978
R B3
R B4
H
R B3
L A1979
R B3
R B4
H
R B4
L A1980
R B3
R B4
H
R B7
L A1981
R B3
R B4
H
R B12
L A1982
R B3
R B4
H
R B18
L A1983
R B3
R B4
H
R A3
L A1984
R B3
R B4
H
R A34
L A1985
R B3
R B5
H
R B1
L A1986
R B3
R B5
H
R B3
L A1987
R B3
R B5
H
R B4
L A1988
R B3
R B5
H
R B7
L A1989
R B3
R B5
H
R B12
L A1990
R B3
R B5
H
R B18
L A1991
R B3
R B5
H
R A3
L A1992
R B3
R B5
H
R A34
L A1993
R B3
R B6
H
R B1
L A1994
R B3
R B6
H
R B3
L A1995
R B3
R B6
H
R B4
L A1996
R B3
R B6
H
R B7
L A1997
R B3
R B6
H
R B12
L A1998
R B3
R B6
H
R B18
L A1999
R B3
R B6
H
R A3
L A2000
R B3
R B6
H
R A34
L A2001
R B3
R B7
H
R B1
L A2002
R B3
R B7
H
R B3
L A2003
R B3
R B7
H
R B4
L A2004
R B3
R B7
H
R B7
L A2005
R B3
R B7
H
R B12
L A2006
R B3
R B7
H
R B18
L A2007
R B3
R B7
H
R A3
L A2008
R B3
R B7
H
R A34
L A2009
R B3
R B12
H
R B1
L A2010
R B3
R B12
H
R B3
L A2011
R B3
R B12
H
R B4
L A2012
R B3
R B12
H
R B7
L A2013
R B3
R B12
H
R B12
L A2014
R B3
R B12
H
R B18
L A2015
R B3
R B12
H
R A3
L A2016
R B3
R B12
H
R A34
L A2017
R B3
R A34
H
R B1
L A2018
R B3
R A34
H
R B3
L A2019
R B3
R A34
H
R B4
L A2020
R B3
R A34
H
R B7
L A2021
R B3
R A34
H
R B12
L A2022
R B3
R A34
H
R B18
L A2023
R B3
R A34
H
R A3
L A2024
R B3
R A34
H
R A34
L A2025
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R B3
H
R B1
L A2026
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R B3
H
R B3
L A2027
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R B3
H
R B4
L A2028
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R B3
H
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L A2029
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R B3
H
R B12
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R B3
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R B3
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R A3
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R B3
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R B5
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R B5
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R B3
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R B5
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R B5
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R B7
L A2037
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R B5
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R B12
L A2038
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R B5
H
R B18
L A2039
R B4
R B5
H
R A3
L A2040
R B4
R B5
H
R A34
L A2041
R B4
R B6
H
R B1
L A2042
R B4
R B6
H
R B3
L A2043
R B4
R B6
H
R B4
L A2044
R B4
R B6
H
R B7
L A2045
R B4
R B6
H
R B12
L A2046
R B4
R B6
H
R B18
L A2047
R B4
R B6
H
R A3
L A2048
R B4
R B6
H
R A34
L A2049
R B4
R B7
H
R B1
L A2050
R B4
R B7
H
R B3
L A2051
R B4
R B7
H
R B4
L A2052
R B4
R B7
H
R B7
L A2053
R B4
R B7
H
R B12
L A2054
R B4
R B7
H
R B18
L A2055
R B4
R B7
H
R A3
L A2056
R B4
R B7
H
R A34
L A2057
R B4
R B12
H
R B1
L A2058
R B4
R B12
H
R B3
L A2059
R B4
R B12
H
R B4
L A2060
R B4
R B12
H
R B7
L A2061
R B4
R B12
H
R B12
L A2062
R B4
R B12
H
R B18
L A2063
R B4
R B12
H
R A3
L A2064
R B4
R B12
H
R A34
L A2065
R B4
R A34
H
R B1
L A2066
R B4
R A34
H
R B3
L A2067
R B4
R A34
H
R B4
L A2068
R B4
R A34
H
R B7
L A2069
R B4
R A34
H
R B12
L A2070
R B4
R A34
H
R B18
L A2071
R B4
R A34
H
R A3
L A2072
R B4
R A34
H
R A34
L A2073
R B7
R B3
H
R B1
L A2074
R B7
R B3
H
R B3
L A2075
R B7
R B3
H
R B4
L A2076
R B7
R B3
H
R B7
L A2077
R B7
R B3
H
R B12
L A2078
R B7
R B3
H
R B18
L A2079
R B7
R B3
H
R A3
L A2080
R B7
R B3
H
R A34
L A2081
R B7
R B4
H
R B1
L A2082
R B7
R B4
H
R B3
L A2083
R B7
R B4
H
R B4
L A2084
R B7
R B4
H
R B7
L A2085
R B7
R B4
H
R B12
L A2086
R B7
R B4
H
R B18
L A2087
R B7
R B4
H
R A3
L A2088
R B7
R B4
H
R A34
L A2089
R B7
R B5
H
R B1
L A2090
R B7
R B5
H
R B3
L A2091
R B7
R B5
H
R B4
L A2092
R B7
R B5
H
R B7
L A2093
R B7
R B5
H
R B12
L A2094
R B7
R B5
H
R B18
L A2095
R B7
R B5
H
R A3
L A2096
R B7
R B5
H
R A34
L A2097
R B7
R B6
H
R B1
L A2098
R B7
R B6
H
R B3
L A2099
R B7
R B6
H
R B4
L A2100
R B7
R B6
H
R B7
L A2101
R B7
R B6
H
R B12
L A2102
R B7
R B6
H
R B18
L A2103
R B7
R B6
H
R A3
L A2104
R B7
R B6
H
R A34
L A2105
R B7
R B12
H
R B1
L A2106
R B7
R B12
H
R B3
L A2107
R B7
R B12
H
R B4
L A2108
R B7
R B12
H
R B7
L A2109
R B7
R B12
H
R B12
L A2110
R B7
R B12
H
R B18
L A2111
R B7
R B12
H
R A3
L A2112
R B7
R B12
H
R A34
L A2113
R B7
R A34
H
R B1
L A2114
R B7
R A34
H
R B3
L A2115
R B7
R A34
H
R B4
L A2116
R B7
R A34
H
R B7
L A2117
R B7
R A34
H
R B12
L A2118
R B7
R A34
H
R B18
L A2119
R B7
R A34
H
R A3
L A2120
R B7
R A34
H
R A34
L A2121
R B43
R B3
H
R B1
L A2122
R B43
R B3
H
R B3
L A2123
R B43
R B3
H
R B4
L A2124
R B43
R B3
H
R B7
L A2125
R B43
R B3
H
R B12
L A2126
R B43
R B3
H
R B18
L A2127
R B43
R B3
H
R A3
L A2128
R B43
R B3
H
R A34
L A2129
R B43
R B4
H
R B1
L A2130
R B43
R B4
H
R B3
L A2131
R B43
R B4
H
R B4
L A2132
R B43
R B4
H
R B7
L A2133
R B43
R B4
H
R B12
L A2134
R B43
R B4
H
R B18
L A2135
R B43
R B4
H
R A3
L A2136
R B43
R B4
H
R A34
L A2137
R B43
R B5
H
R B1
L A2138
R B43
R B5
H
R B3
L A2139
R B43
R B5
H
R B4
L A2140
R B43
R B5
H
R B7
L A2141
R B43
R B5
H
R B12
L A2142
R B43
R B5
H
R B18
L A2143
R B43
R B5
H
R A3
L A2144
R B43
R B5
H
R A34
L A2145
R B43
R B6
H
R B1
L A2146
R B43
R B6
H
R B3
L A2147
R B43
R B6
H
R B4
L A2148
R B43
R B6
H
R B7
L A2149
R B43
R B6
H
R B12
L A2150
R B43
R B6
H
R B18
L A2151
R B43
R B6
H
R A3
L A2152
R B43
R B6
H
R A34
L A2153
R B43
R B7
H
R B1
L A2154
R B43
R B7
H
R B3
L A2155
R B43
R B7
H
R B4
L A2156
R B43
R B7
H
R B7
L A2157
R B43
R B7
H
R B12
L A2158
R B43
R B7
H
R B18
L A2159
R B43
R B7
H
R A3
L A2160
R B43
R B7
H
R A34
L A2161
R B43
R B12
H
R B1
L A2162
R B43
R B12
H
R B3
L A2163
R B43
R B12
H
R B4
L A2164
R B43
R B12
H
R B7
L A2165
R B43
R B12
H
R B12
L A2166
R B43
R B12
H
R B18
L A2167
R B43
R B12
H
R A3
L A2168
R B43
R B12
H
R A34
L A2169
R B43
R A34
H
R B1
L A2170
R B43
R A34
H
R B3
L A2171
R B43
R A34
H
R B4
L A2172
R B43
R A34
H
R B7
L A2173
R B43
R A34
H
R B12
L A2174
R B43
R A34
H
R B18
L A2175
R B43
R A34
H
R A3
L A2176
R B43
R A34
H
R A34
L A2177 through L A2720 , that are based on a structure of Formula Ie,
in each of which R 1 , R 2 , R 4 , and R 5 are defined as follows:
R 1
R 2
R 4
R 5
L A2177
R B1
R B3
H
H
L A2178
R B1
R B3
R B1
H
L A2179
R B1
R B3
R B3
H
L A2180
R B1
R B3
R B4
H
L A2181
R B1
R B3
R B7
H
L A2182
R B1
R B3
R B12
H
L A2183
R B1
R B3
R B18
H
L A2184
R B1
R B3
R A3
H
L A2185
R B1
R B3
R A34
H
L A2186
R B1
R B4
H
H
L A2187
R B1
R B4
R B1
H
L A2188
R B1
R B4
R B3
H
L A2189
R B1
R B4
R B4
H
L A2190
R B1
R B4
R B7
H
L A2191
R B1
R B4
R B12
H
L A2192
R B1
R B4
R B18
H
L A2193
R B1
R B4
R A3
H
L A2194
R B1
R B4
R A34
H
L A2195
R B1
R B5
H
H
L A2196
R B1
R B5
R B1
H
L A2197
R B1
R B5
R B3
H
L A2198
R B1
R B5
R B4
H
L A2199
R B1
R B5
R B7
H
L A2200
R B1
R B5
R B12
H
L A2201
R B1
R B5
R B18
H
L A2202
R B1
R B5
R A3
H
L A2203
R B1
R B5
R A34
H
L A2204
R B1
R B6
H
H
L A2205
R B1
R B6
R B1
H
L A2206
R B1
R B6
R B3
H
L A2207
R B1
R B6
R B4
H
L A2208
R B1
R B6
R B7
H
L A2209
R B1
R B6
R B12
H
L A2210
R B1
R B6
R B18
H
L A2211
R B1
R B6
R A3
H
L A2212
R B1
R B6
R A34
H
L A2213
R B1
R B7
H
H
L A2214
R B1
R B7
R B1
H
L A2215
R B1
R B7
R B3
H
L A2216
R B1
R B7
R B4
H
L A2217
R B1
R B7
R B7
H
L A2218
R B1
R B7
R B12
H
L A2219
R B1
R B7
R B18
H
L A2220
R B1
R B7
R A3
H
L A2221
R B1
R B7
R A34
H
L A2222
R B1
R B12
H
H
L A2223
R B1
R B12
R B1
H
L A2224
R B1
R B12
R B3
H
L A2225
R B1
R B12
R B4
H
L A2226
R B1
R B12
R B7
H
L A2227
R B1
R B12
R B12
H
L A2228
R B1
R B12
R B18
H
L A2229
R B1
R B12
R A3
H
L A2230
R B1
R B12
R A34
H
L A2231
R B1
R A34
H
H
L A2232
R B1
R A34
R B1
H
L A2233
R B1
R A34
R B3
H
L A2234
R B1
R A34
R B4
H
L A2235
R B1
R A34
R B7
H
L A2236
R B1
R A34
R B12
H
L A2237
R B1
R A34
R B18
H
L A2238
R B1
R A34
R A3
H
L A2239
R B1
R A34
R A34
H
L A2240
R B3
R B4
H
H
L A2241
R B3
R B4
R B1
H
L A2242
R B3
R B4
R B3
H
L A2243
R B3
R B4
R B4
H
L A2244
R B3
R B4
R B7
H
L A2245
R B3
R B4
R B12
H
L A2246
R B3
R B4
R B18
H
L A2247
R B3
R B4
R A3
H
L A2248
R B3
R B4
R A34
H
L A2249
R B3
R B5
H
H
L A2250
R B3
R B5
R B1
H
L A2251
R B3
R B5
R B3
H
L A2252
R B3
R B5
R B4
H
L A2253
R B3
R B5
R B7
H
L A2254
R B3
R B5
R B12
H
L A2255
R B3
R B5
R B18
H
L A2256
R B3
R A3
R B5
H
L A2257
R B3
R B5
R A34
H
L A2258
R B3
R B6
H
H
L A2259
R B3
R B6
R B1
H
L A2260
R B3
R B6
R B3
H
L A2261
R B3
R B6
R B4
H
L A2262
R B3
R B6
R B7
H
L A2263
R B3
R B6
R B12
H
L A2264
R B3
R B6
R B18
H
L A2265
R B3
R B6
R A3
H
L A2266
R B3
R B6
R A34
H
L A2267
R B3
R B7
H
H
L A2268
R B3
R B7
R B1
H
L A2269
R B3
R B7
R B3
H
L A2270
R B3
R B7
R B4
H
L A2271
R B3
R B7
R B7
H
L A2272
R B3
R B7
R B12
H
L A2273
R B3
R B7
R B18
H
L A2274
R B3
R B7
R A3
H
L A2275
R B3
R B7
R A34
H
L A2276
R B3
R B12
H
H
L A2277
R B3
R B12
R B1
H
L A2278
R B3
R B12
R B3
H
L A2279
R B3
R B12
R B4
H
L A2280
R B3
R B12
R B7
H
L A2281
R B3
R B12
R B12
H
L A2282
R B3
R B12
R B18
H
L A2283
R B3
R B12
R A3
H
L A2284
R B3
R B12
R A34
H
L A2285
R B3
R A34
H
H
L A2286
R B3
R A34
R B1
H
L A2287
R B3
R A34
R B3
H
L A2288
R B3
R A34
R B4
H
L A2289
R B3
R A34
R B7
H
L A2290
R B3
R A34
R B12
H
L A2291
R B3
R A34
R B18
H
L A2292
R B3
R A34
R A3
H
L A2293
R B3
R A34
R A34
H
L A2294
R B4
R B3
H
H
L A2295
R B4
R B3
R B1
H
L A2296
R B4
R B3
R B3
H
L A2297
R B4
R B3
R B4
H
L A2298
R B4
R B3
R B7
H
L A2299
R B4
R B3
R B12
H
L A2300
R B4
R B3
R B18
H
L A2301
R B4
R B3
R A3
H
L A2302
R B4
R B3
R A34
H
L A2303
R B4
R B5
H
H
L A2304
R B4
R B5
R B1
H
L A2305
R B4
R B5
R B3
H
L A2306
R B4
R B5
R B4
H
L A2307
R B4
R B5
R B7
H
L A2308
R B4
R B5
R B12
H
L A2309
R B4
R B5
R B18
H
L A2310
R B4
R B5
R A3
H
L A2311
R B4
R B5
R A34
H
L A2312
R B4
R B6
H
H
L A2313
R B4
R B6
R B1
H
L A2314
R B4
R B6
R B3
H
L A2315
R B4
R B6
R B4
H
L A2316
R B4
R B6
R B7
H
L A2317
R B4
R B6
R B12
H
L A2318
R B4
R B6
R B18
H
L A2319
R B4
R B6
R A3
H
L A2320
R B4
R B6
R A34
H
L A2321
R B4
R B7
H
H
L A2322
R B4
R B7
R B1
H
L A2323
R B4
R B7
R B3
H
L A2324
R B4
R B7
R B4
H
L A2325
R B4
R B7
R B7
H
L A2326
R B4
R B7
R B12
H
L A2327
R B4
R B7
R B18
H
L A2328
R B4
R B7
R A3
H
L A2329
R B4
R B7
R A34
H
L A2330
R B4
R B12
H
H
L A2331
R B4
R B12
R B1
H
L A2332
R B4
R B12
R B3
H
L A2333
R B4
R B12
R B4
H
L A2334
R B4
R B12
R B7
H
L A2335
R B4
R B12
R B12
H
L A2336
R B4
R B12
R B18
H
L A2337
R B4
R B12
R A3
H
L A2338
R B4
R B12
R A34
H
L A2339
R B4
R A34
H
H
L A2340
R B4
R A34
R B1
H
L A2341
R B4
R A34
R B3
H
L A2342
R B4
R A34
R B4
H
L A2343
R B4
R A34
R B7
H
L A2344
R B4
R A34
R B12
H
L A2345
R B4
R A34
R B18
H
L A2346
R B4
R A34
R A3
H
L A2347
R B4
R A34
R A34
H
L A2348
R B7
R B3
H
H
L A2349
R B7
R B3
R B1
H
L A2350
R B7
R B3
R B3
H
L A2351
R B7
R B3
R B4
H
L A2352
R B7
R B3
R B7
H
L A2353
R B7
R B3
R B12
H
L A2354
R B7
R B3
R B18
H
L A2355
R B7
R B3
R A3
H
L A2356
R B7
R B3
R A34
H
L A2357
R B7
R B4
H
H
L A2358
R B7
R B4
R B1
H
L A2359
R B7
R B4
R B3
H
L A2360
R B7
R B4
R B4
H
L A2361
R B7
R B4
R B7
H
L A2362
R B7
R B4
R B12
H
L A2363
R B7
R B4
R B18
H
L A2364
R B7
R B4
R A3
H
L A2365
R B7
R B4
R A34
H
L A2366
R B7
R B5
H
H
L A2367
R B7
R B5
R B1
H
L A2368
R B7
R B5
R B3
H
L A2369
R B7
R B5
R B4
H
L A2370
R B7
R B5
R B7
H
L A2371
R B7
R B5
R B12
H
L A2372
R B7
R B5
R B18
H
L A2373
R B7
R B5
R A3
H
L A2374
R B7
R B5
R A34
H
L A2375
R B7
R B6
H
H
L A2376
R B7
R B6
R B1
H
L A2377
R B7
R B6
R B3
H
L A2378
R B7
R B6
R B4
H
L A2379
R B7
R B6
R B7
H
L A2380
R B7
R B6
R B12
H
L A2381
R B7
R B6
R B18
H
L A2382
R B7
R B6
R A3
H
L A2383
R B7
R B6
R A34
H
L A2384
R B7
R B12
H
H
L A2385
R B7
R B12
R B1
H
L A2386
R B7
R B12
R B3
H
L A2387
R B7
R B12
R B4
H
L A2388
R B7
R B12
R B7
H
L A2389
R B7
R B12
R B12
H
L A2390
R B7
R B12
R B18
H
L A2391
R B7
R B12
R A3
H
L A2392
R B7
R B12
R A34
H
L A2393
R B7
R A34
H
H
L A2394
R B7
R A34
R B1
H
L A2395
R B7
R A34
R B3
H
L A2396
R B7
R A34
R B4
H
L A2397
R B7
R A34
R B7
H
L A2398
R B7
R A34
R B12
H
L A2399
R B7
R A34
R B18
H
L A2400
R B7
R A34
R A3
H
L A2401
R B7
R A34
R A34
H
L A2402
R B43
R B3
H
H
L A2403
R B43
R B3
R B1
H
L A2404
R B43
R B3
R B3
H
L A2405
R B43
R B3
R B4
H
L A2406
R B43
R B3
R B7
H
L A2407
R B43
R B3
R B12
H
L A2408
R B43
R B3
R B18
H
L A2409
R B43
R B3
R A3
H
L A2410
R B43
R B3
R A34
H
L A2411
R B43
R B4
H
H
L A2412
R B43
R B4
R B1
H
L A2413
R B43
R B4
R B3
H
L A2414
R B43
R B4
R B4
H
L A2415
R B43
R B4
R B7
H
L A2416
R B43
R B4
R B12
H
L A2417
R B43
R B4
R B18
H
L A2418
R B43
R B4
R A3
H
L A2419
R B43
R B4
R A34
H
L A2420
R B43
R B5
H
H
L A2421
R B43
R B5
R B1
H
L A2422
R B43
R B5
R B3
H
L A2423
R B43
R B5
R B4
H
L A2424
R B43
R B5
R B7
H
L A2425
R B43
R B5
R B12
H
L A2426
R B43
R B5
R B18
H
L A2427
R B43
R B5
R A3
H
L A2428
R B43
R B5
R A34
H
L A2429
R B43
R B6
H
H
L A2430
R B43
R B6
R B1
H
L A2431
R B43
R B6
R B3
H
L A2432
R B43
R B6
R B4
H
L A2433
R B43
R B6
R B7
H
L A2434
R B43
R B6
R B12
H
L A2435
R B43
R B6
R B18
H
L A2436
R B43
R B6
R A3
H
L A2437
R B43
R B6
R A34
H
L A2438
R B43
R B7
H
H
L A2439
R B43
R B7
R B1
H
L A2440
R B43
R B7
R B3
H
L A2441
R B43
R B7
R B4
H
L A2442
R B43
R B7
R B7
H
L A2443
R B43
R B7
R B12
H
L A2444
R B43
R B7
R B18
H
L A2445
R B43
R B7
R A3
H
L A2446
R B43
R B7
R A34
H
L A2447
R B43
R B12
H
H
L A2448
R B43
R B12
R B1
H
L A2449
R B43
R B12
R B3
H
L A2450
R B43
R B12
R B4
H
L A2451
R B43
R B12
R B7
H
L A2452
R B43
R B12
R B12
H
L A2453
R B43
R B12
R B18
H
L A2454
R B43
R B12
R A3
H
L A2455
R B43
R B12
R A34
H
L A2456
R B43
R A34
H
H
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R B43
R A34
R B1
H
L A2458
R B43
R A34
R B3
H
L A2459
R B43
R A34
R B4
H
L A2460
R B43
R A34
R B7
H
L A2461
R B43
R A34
R B12
H
L A2462
R B43
R A34
R B18
H
L A2463
R B43
R A34
R A3
H
L A2464
R B43
R A34
R A34
H
L A2465
R B1
R B3
H
R B1
L A2466
R B1
R B3
H
R B3
L A2467
R B1
R B3
H
R B4
L A2468
R B1
R B3
H
R B7
L A2469
R B1
R B3
H
R B12
L A2470
R B1
R B3
H
R B18
L A2471
R B1
R B3
H
R A3
L A2472
R B1
R B3
H
R A34
L A2473
R B1
R B4
H
R B1
L A2474
R B1
R B4
H
R B3
L A2475
R B1
R B4
H
R B4
L A2476
R B1
R B4
H
R B7
L A2477
R B1
R B4
H
R B12
L A2478
R B1
R B4
H
R B18
L A2479
R B1
R B4
H
R A3
L A2480
R B1
R B4
H
R A34
L A2481
R B1
R B5
H
R B1
L A2482
R B1
R B5
H
R B3
L A2483
R B1
R B5
H
R B4
L A2484
R B1
R B5
H
R B7
L A2485
R B1
R B5
H
R B12
L A2486
R B1
R B5
H
R B18
L A2487
R B1
R B5
H
R A3
L A2488
R B1
R B5
H
R A34
L A2489
R B1
R B6
H
R B1
L A2490
R B1
R B6
H
R B3
L A2491
R B1
R B6
H
R B4
L A2492
R B1
R B6
H
R B7
L A2493
R B1
R B6
H
R B12
L A2494
R B1
R B6
H
R B18
L A2495
R B1
R B6
H
R A3
L A2496
R B1
R B6
H
R A34
L A2497
R B1
R B7
H
R B1
L A2498
R B1
R B7
H
R B3
L A2499
R B1
R B7
H
R B4
L A2500
R B1
R B7
H
R B7
L A2501
R B1
R B7
H
R B12
L A2502
R B1
R B7
H
R B18
L A2503
R B1
R B7
H
R A3
L A2504
R B1
R B7
H
R A34
L A2505
R B1
R B12
H
R B1
L A2506
R B1
R B12
H
R B3
L A2507
R B1
R B12
H
R B4
L A2508
R B1
R B12
H
R B7
L A2509
R B1
R B12
H
R B12
L A2510
R B1
R B12
H
R B18
L A2511
R B1
R B12
H
R A3
L A2512
R B1
R B12
H
R A34
L A2513
R B1
R A34
H
R B1
L A2514
R B1
R A34
H
R B3
L A2515
R B1
R A34
H
R B4
L A2516
R B1
R A34
H
R B7
L A2517
R B1
R A34
H
R B12
L A2518
R B1
R A34
H
R B18
L A2519
R B1
R A34
H
R A3
L A2520
R B1
R A34
H
R A34
L A2521
R B3
R B4
H
R B1
L A2522
R B3
R B4
H
R B3
L A2523
R B3
R B4
H
R B4
L A2524
R B3
R B4
H
R B7
L A2525
R B3
R B4
H
R B12
L A2526
R B3
R B4
H
R B18
L A2527
R B3
R B4
H
R A3
L A2528
R B3
R B4
H
R A34
L A2529
R B3
R B5
H
R B1
L A2530
R B3
R B5
H
R B3
L A2531
R B3
R B5
H
R B4
L A2532
R B3
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H
R B7
L A2533
R B3
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H
R B12
L A2534
R B3
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H
R B18
L A2535
R B3
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H
R A3
L A2536
R B3
R B5
H
R A34
L A2537
R B3
R B6
H
R B1
L A2538
R B3
R B6
H
R B3
L A2539
R B3
R B6
H
R B4
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R B3
R B6
H
R B7
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R B3
R B6
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R B12
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R B3
R B6
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R B18
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R B3
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R A3
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R B3
R B6
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R B3
R B7
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R B1
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R B3
R B7
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R B3
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R B3
R B7
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R B4
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R B3
R B7
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R B7
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R B3
R B7
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R B12
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R B3
R B7
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R B18
L A2551
R B3
R B7
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R A3
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R B3
R B7
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R A34
L A2553
R B3
R B12
H
R B1
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H
R B3
L A2555
R B3
R B12
H
R B4
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R B3
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H
R B7
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R B3
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H
R B12
L A2558
R B3
R B12
H
R B18
L A2559
R B3
R B12
H
R A3
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R B3
R B12
H
R A34
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R B3
R A34
H
R B1
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R B3
R A34
H
R B3
L A2563
R B3
R A34
H
R B4
L A2564
R B3
R A34
H
R B7
L A2565
R B3
R A34
H
R B12
L A2566
R B3
R A34
H
R B18
L A2567
R B3
R A34
H
R A3
L A2568
R B3
R A34
H
R A34
L A2569
R B4
R B3
H
R B1
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R B4
R B3
H
R B3
L A2571
R B4
R B3
H
R B4
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R B4
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H
R B7
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R B4
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H
R B12
L A2574
R B4
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H
R B18
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R B4
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H
R A3
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R B4
R B3
H
R A34
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R B4
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H
R B1
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H
R B3
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R B4
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H
R B4
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R B4
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H
R B7
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R B4
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H
R B12
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R B4
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H
R B18
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R B4
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H
R A3
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R B4
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R A34
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R B4
R B6
H
R B1
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R B4
R B6
H
R B3
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R B4
R B6
H
R B4
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R B4
R B6
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R B7
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R B4
R B6
H
R B12
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R B4
R B6
H
R B18
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R B4
R B6
H
R A3
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R B4
R B6
H
R A34
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R B4
R B7
H
R B1
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R B4
R B7
H
R B3
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R B4
R B7
H
R B4
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R B4
R B7
H
R B7
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R B4
R B7
H
R B12
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R B4
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H
R B18
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R B4
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H
R A3
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R B4
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H
R A34
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R B4
R B12
H
R B1
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R B4
R B12
H
R B3
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R B12
H
R B4
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R B4
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H
R B7
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H
R B12
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R B4
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H
R B18
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R B12
H
R A3
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R B4
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H
R A34
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R B4
R A34
H
R B1
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R B4
R A34
H
R B3
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R B4
R A34
H
R B4
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R B4
R A34
H
R B7
L A2613
R B4
R A34
H
R B12
L A2614
R B4
R A34
H
R B18
L A2615
R B4
R A34
H
R A3
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R B4
R A34
H
R A34
L A2617
R B7
R B3
H
R B1
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R B7
R B3
H
R B3
L A2619
R B7
R B3
H
R B4
L A2620
R B7
R B3
H
R B7
L A2621
R B7
R B3
H
R B12
L A2622
R B7
R B3
H
R B18
L A2623
R B7
R B3
H
R A3
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R B7
R B3
H
R A34
L A2625
R B7
R B4
H
R B1
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R B7
R B4
H
R B3
L A2627
R B7
R B4
H
R B4
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R B7
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H
R B7
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R B7
R B4
H
R B12
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R B7
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H
R B18
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R B7
R B4
H
R A3
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R B7
R B4
H
R A34
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R B7
R B5
H
R B1
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R B7
R B5
H
R B3
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R B7
R B5
H
R B4
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R B7
R B5
H
R B7
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R B7
R B5
H
R B12
L A2638
R B7
R B5
H
R B18
L A2639
R B7
R B5
H
R A3
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R B7
R B5
H
R A34
L A2641
R B7
R B6
H
R B1
L A2642
R B7
R B6
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R B3
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R B7
R B6
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R B4
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R B7
R B6
H
R B7
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R B6
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R B12
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R B7
R B6
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R B18
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R B6
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R A3
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R B7
R B6
H
R A34
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R B7
R B12
H
R B1
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R B7
R B12
H
R B3
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R B12
H
R B4
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R B7
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H
R B7
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R B7
R B12
H
R B12
L A2654
R B7
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H
R B18
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R B7
R B12
H
R A3
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R B7
R B12
H
R A34
L A2657
R B7
R A34
H
R B1
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R B7
R A34
H
R B3
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R B7
R A34
H
R B4
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R B7
R A34
H
R B7
L A2661
R B7
R A34
H
R B12
L A2662
R B7
R A34
H
R B18
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R B7
R A34
H
R A3
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R B7
R A34
H
R A34
L A2665
R B43
R B3
H
R B1
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R B43
R B3
H
R B3
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R B43
R B3
H
R B4
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R B43
R B3
H
R B7
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R B43
R B3
H
R B12
L A2670
R B43
R B3
H
R B18
L A2671
R B43
R B3
H
R A3
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R B43
R B3
H
R A34
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R B4
H
R B1
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R B43
R B4
H
R B3
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R B4
H
R B4
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R B43
R B4
H
R B7
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R B43
R B4
H
R B12
L A2678
R B43
R B4
H
R B18
L A2679
R B43
R B4
H
R A3
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R B43
R B4
H
R A34
L A2681
R B43
R B5
H
R B1
L A2682
R B43
R B5
H
R B3
L A2683
R B43
R B5
H
R B4
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R B43
R B5
H
R B7
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R B43
R B5
H
R B12
L A2686
R B43
R B5
H
R B18
L A2687
R B43
R B5
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R A3
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R B43
R B5
H
R A34
L A2689
R B43
R B6
H
R B1
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R B43
R B6
H
R B3
L A2691
R B43
R B6
H
R B4
L A2692
R B43
R B6
H
R B7
L A2693
R B43
R B6
H
R B12
L A2694
R B43
R B6
H
R B18
L A2695
R B43
R B6
H
R A3
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R B43
R B6
H
R A34
L A2697
R B43
R B7
H
R B1
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R B43
R B7
H
R B3
L A2699
R B43
R B7
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R B4
L A2700
R B43
R B7
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R B7
L A2701
R B43
R B7
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R B12
L A2702
R B43
R B7
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R B18
L A2703
R B43
R B7
H
R A3
L A2704
R B43
R B7
H
R A34
L A2705
R B43
R B12
H
R B1
L A2706
R B43
R B12
H
R B3
L A2707
R B43
R B12
H
R B4
L A2708
R B43
R B12
H
R B7
L A2709
R B43
R B12
H
R B12
L A2710
R B43
R B12
H
R B18
L A2711
R B43
R B12
H
R A3
L A2712
R B43
R B12
H
R A34
L A2713
R B43
R A34
H
R B1
L A2714
R B43
R A34
H
R B3
L A2715
R B43
R A34
H
R B4
L A2716
R B43
R A34
H
R B7
L A2717
R B43
R A34
H
R B12
L A2718
R B43
R A34
H
R B18
L A2719
R B43
R A34
H
R A3
L A2720
R B43
R A34
H
R A34
wherein R B1 to R B44 have the following structures:
wherein R A1 to R A51 have the following structures:
12 . The compound of claim 1 , wherein the ligand L B is selected from the group consisting of:
wherein each X 1 to X 13 are independently selected from the group consisting of carbon and nitrogen;
wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO 2 , CR′R″, SiR′R″, and GeR′R″;
wherein R′ and R″ are optionally fused or joined to form a ring;
wherein each R a , R b , R c , and R d may represent from mono substitution to the possible maximum number of substitution, or no substitution;
wherein R′, R″, R a , R b , R c , and R d are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
wherein any two adjacent substituents of R a , R b , R c , and R d are optionally fused or joined to form a ring or form a multidentate ligand.
13 . The compound of claim 1 , wherein the ligand L C is selected from the group consisting of:
14 . The compound or claim 11 , wherein me compound is the compound x having the formula Ir(L Ai ) 2 (L Cj );
wherein x=17i+j−17; i is an integer from 1 to 2720, and j is an integer from 1 to 17; and wherein L C is selected from the group consisting of:
15 . An organic light emitting device (OLED) comprising:
an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having a formula M(L A ) x (L B ) y (L C ) z : wherein the ligand L A has Formula I,
wherein the ligand L B has Formula II,
wherein the ligand L C has Formula III,
wherein M is a metal having an atomic weight greater than 40;
wherein x is 1, 2, or 3;
wherein y is 0, 1, or 2;
wherein z is 0, 1, or 2;
wherein x+y+z is the oxidation state of the metal M;
wherein X 1 to X 5 are each independently a carbon or nitrogen;
wherein ring A is a 5- or 6-membered aromatic ring fused to the ring having X 1 ;
wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring;
wherein R 3 , R 4 , R C , and R D each independently represents none to a maximum possible number of substitution;
wherein each of R 3 , R 4 , R C , and R D , R X , R Y , and R Z are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any adjacent substituents of R 3 , R 4 , R C , and R D , R X , R Y , and R Z are optionally joined or fused into a ring;
wherein R 1 and R 2 are each independently selected from the group consisting of alkyl, cycloalkyl, silyl, germanyl, and substituted variants thereof; and
wherein R 1 is different from R 2 .
16 . The OLED of claim 15 , wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.
17 . The OLED of claim 15 , wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
18 . The OLED of claim 15 , wherein the organic layer further comprises a host, wherein the host is selected from the group consisting of:
and combinations thereof.
19 . A consumer product comprising an organic light-emitting device (OLED) comprising:
an anode; a cathode; and an organic layer, disposed between the anode and the cathode, comprising a compound having a formula M(L A ) x (L B ) y (L C ) z : wherein the ligand L A has Formula I,
wherein the ligand L B has Formula II,
wherein the ligand L C has Formula III,
wherein M is a metal having an atomic weight greater than 40;
wherein x is 1, 2, or 3;
wherein y is 0, 1, or 2;
wherein z is 0, 1, or 2;
wherein x+y+z is the oxidation state of the metal M;
wherein X 1 to X 5 are each independently a carbon or nitrogen;
wherein ring A is a 5- or 6-membered aromatic ring fused to the ring having X 1 ;
wherein rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring;
wherein R 3 , R 4 , R C and R D each independently represents none to a maximum possible number of substitutions;
wherein each of R 3 , R 4 , R C , and R D , R X , R Y and R Z are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any adjacent substituents of R 3 , R 4 , R C , and R D , R X , R Y , and R Z are optionally joined or fused into a ring;
wherein R 1 and R 2 are each independently selected from the group consisting of alkyl, cycloalkyl, silyl, germanyl, and substituted variants thereof; and
wherein R 1 is different from R 2 .
20 . The consumer product of claim 19 , wherein the consumer product is one of a flat panel display, a computer monitor, a medical monitors television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display, a 3-D display, a virtual reality or augmented reality display, a vehicle, a large area wall, a theater or stadium screen, and a sign.Join the waitlist — get patent alerts
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