US2023416877A1PendingUtilityA1

Super-heat-resistant alloy

Assignee: KOREA INSTITUTE MATERIALS SCIENCEPriority: Nov 9, 2020Filed: Nov 9, 2021Published: Dec 28, 2023
Est. expiryNov 9, 2040(~14.3 yrs left)· nominal 20-yr term from priority
C22C 19/057C22C 19/03C22C 30/00
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Claims

Abstract

Provided is a super-heat-resistant alloy consisting of aluminum (Al): 4.0 wt % to 5.2 wt %, cobalt (Co): 1.0 wt % to 10.0 wt %, chromium (Cr): 5.0 wt % to 8.0 wt %, molybdenum (Mo): 0.5 wt % to 2.0 wt %, tantalum (Ta): 7.0 wt % to 10.0 wt %, titanium (Ti): 0 wt %<Ti≤1.5 wt %, tungsten (W): 7.0 wt % to 10.5 wt %, and nickel (Ni): balance, and not containing rhenium (Re).

Claims

exact text as granted — not AI-modified
1 . A super-heat-resistant alloy consisting of aluminum (Al): 4.0 wt % to wt %, cobalt (Co): 1.0 wt % to 10.0 wt %, chromium (Cr): 5.0 wt % to 8.0 wt %, molybdenum (Mo): 0.5 wt % to 2.0 wt %, tantalum (Ta): 7.0 wt % to 10.0 wt %, titanium (Ti): 0 wt %<Ti≤1.5 wt %, tungsten (W): 7.0 wt % to 10.5 wt %, and nickel (Ni): balance, and not containing rhenium (Re),
 wherein a creep resistance sustainability of the super-heat-resistant alloy according to Equations 1 and 2 below is greater than or equal to 60%.
   Stable creep resistance time (hours)= t   max   −t   min   <Equation 1>
 
   in a period of time satisfying 
   [ε t(i) −ε t(i−1)   ]/[t ( i )− t ( i− 1)]≤0.005(%/hours)
 
 
 (where ε t(i)  denotes a creep strain of the super-heat-resistant alloy at time t(i), ε t(i−1)  denotes a creep strain of the super-heat-resistant alloy at time t(i−1), t max  denotes a maximum time value in the period of time, and t min  denotes is a minimum time value in the period of time.)
   Creep resistance sustainability=[(Stable creep resistance time)/(Total CreepLife)×100]  <Equation 2>
 
 
 (where the stable creep resistance time and the total creep life are measured under conditions of 1100° C. and 137 MPa.) 
 
     
     
         2 . The super-heat-resistant alloy of  claim 1 , wherein the time stable creep resistance time according to Equation 1 is 150 hours or more. 
     
     
         3 . A super-heat-resistant alloy consisting of aluminum (Al): 4.0 wt % to wt %, cobalt (Co): 1.0 wt % to 10.0 wt %, chromium (Cr): 5.0 wt % to 8.0 wt %, molybdenum (Mo): 0.5 wt % to 2.0 wt %, tantalum (Ta): 7.0 wt % to 10.0 wt %, titanium (Ti): 0 wt %<Ti≤1.5 wt %, tungsten (W): 7.0 wt % to 10.5 wt %, hafnium (Hf): 0 wt %<Hf≤1.5 wt %, and nickel (Ni): balance, and not containing rhenium (Re),
 wherein a creep resistance sustainability of the super-heat-resistant alloy according to Equations 1 and 2 below is greater than or equal to 60%.
   Stable creep resistance time (hours)= t   max   −t   min   <Equation 1>
 
   in a period of time satisfying 
   [ε t(i) −ε t(i−1)   ]/[t ( i )− t ( i− 1)]≤0.005(%/hours)
 
 
 (where ε t(i)  denotes a creep strain of the super-heat-resistant alloy at time t(i), ε t(i−1)  denotes a creep strain of the super-heat-resistant alloy at time t(i−1), t max  denotes a maximum time value in the period of time, and t min  denotes is a minimum time value in the period of time.)
   Creep resistance sustainability=[(Stable creep resistance time)/(Total CreepLife)×100]  <Equation 2>
 
 
 (where the stable creep resistance time and the total creep life are measured under conditions of 1100° C. and 137 MPa.) 
 
     
     
         4 . The super-heat-resistant alloy of  claim 3 , wherein the stable creep resistance time according to Equation 1 is 150 hours or more. 
     
     
         5 . The super-heat-resistant alloy of  claim 1 , wherein the super-heat-resistant alloy does not contain iron (Fe). 
     
     
         6 . The super-heat-resistant alloy of  claim 1 , wherein a lattice misfit δ of the super-heat-resistant alloy according to Equation 3 below is higher than −0.35% and lower than −0.28%. 
       
         
           
             
               
                 
                   
                     
                       Lattice 
                       ⁢ 
                           
                       Misfit 
                       ⁢ 
                           
                       δ 
                     
                     = 
                     
                       2 
                       × 
                       
                         
                           
                             α 
                             
                               γ 
                               ⁢ 
                               ′ 
                             
                           
                           - 
                           
                             α 
                             γ 
                           
                         
                         
                           
                             α 
                             γ′ 
                           
                           + 
                           
                             α 
                             γ 
                           
                         
                       
                     
                   
                 
                 
                   
                     [ 
                     
                       Equation 
                       ⁢ 
                           
                       3 
                     
                     ] 
                   
                 
               
             
           
         
         (where α γ  denotes a lattice parameter of a matrix γ, and α γ′  denotes a lattice parameter of a precipitate γ′.) 
       
     
     
         7 . The super-heat-resistant alloy of  claim 1 , wherein a γ lattice parameter distribution parameter of the super-heat-resistant alloy according to Equation 8 below is greater than 0.12. 
       
         
           
             
               
                 
                   
                     
                       γ 
                       ⁢ 
                          
                       Lattice 
                       ⁢ 
                           
                       Parameter 
                       ⁢ 
                           
                       Distribution 
                       ⁢ 
                           
                       Parameter 
                     
                     = 
                     
                       
                         
                           ∑ 
                           i 
                         
                         
                           ( 
                           
                             
                               k 
                               i 
                             
                             × 
                             
                               x 
                               i 
                             
                             × 
                             
                               V 
                               i 
                               γ 
                             
                           
                           ) 
                         
                       
                       > 
                       
                         
                           0 
                           . 
                           1 
                         
                         ⁢ 
                         2 
                       
                     
                   
                 
                 
                   
                     [ 
                     
                       Equation 
                       ⁢ 
                           
                       8 
                     
                     ] 
                   
                 
               
             
           
         
         (where k i  denotes a partitioning coefficient of each alloying element and indicates x i   γ /x i   γ′ , x i  denotes an atomic fraction (at. %) of each alloying element, x i   γ  denotes an atomic fraction (at. %) of each alloying element in a matrix γ phase, x i   γ′  denotes an atomic fraction (at. %) of each alloying element in a precipitate γ′ phase, and V i   γ  denotes a Vegard coefficient of each alloying element in the matrix γ phase.)

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