Thermoplastic fluororesin tube

Abstract

A thermoplastic fluororesin tube that, during the production of a catheter, can prevent a gap or air bubbles from being formed in the connection part of the catheter, and can be suitably used for the production of a catheter. The thermoplastic fluororesin tube includes a tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer (FEP), the thermoplastic fluororesin tube having tearability in a longitudinal direction, wherein a thermal expansion coefficient in the longitudinal direction upon heating in a gaseous phase at a temperature of 100° C. for 5 minutes is 0% or more.

What is claimed is: 
     
         1 . A thermoplastic fluororesin tube comprising a tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer (FEP), the thermoplastic fluororesin tube having tearability in a longitudinal direction, wherein a thermal expansion coefficient in the longitudinal direction upon heating in a gaseous phase at a temperature of 100° C. for 5 minutes is 0% or more. 
     
     
         2 . The thermoplastic fluororesin tube according to  claim 1 , wherein a heat shrinkage ratio of an inner diameter upon heating in a gaseous phase at a temperature of 200° C. for 5 minutes is 51% or more. 
     
     
         3 . The thermoplastic fluororesin tube according to  claim 1 , wherein the thermoplastic fluororesin further comprises a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA). 
     
     
         4 . The thermoplastic fluororesin tube according to  claim 1 , wherein the thermal expansion coefficient in the longitudinal direction upon heating at a temperature of 100° C. for 5 minutes is 0 to 4%. 
     
     
         5 . The thermoplastic fluororesin tube according to  claim 1 , which comprises a weld line in the longitudinal direction. 
     
     
         6 . The thermoplastic fluororesin tube according to  claim 2 , wherein the thermal expansion coefficient in the longitudinal direction upon heating at a temperature of 100° C. for 5 minutes is 0 to 4%. 
     
     
         7 . The thermoplastic fluororesin tube according to  claim 3 , wherein the thermal expansion coefficient in the longitudinal direction upon heating at a temperature of 100° C. for 5 minutes is 0 to 4%. 
     
     
         8 . The thermoplastic fluororesin tube according to  claim 2 , which comprises a weld line in the longitudinal direction. 
     
     
         9 . The thermoplastic fluororesin tube according to  claim 3 , which comprises a weld line in the longitudinal direction. 
     
     
         10 . The thermoplastic fluororesin tube according to  claim 4 , which comprises a weld line in the longitudinal direction. 
     
     
         11 . The thermoplastic fluororesin tube according to  claim 1 , wherein a tear strength of the thermoplastic fluororesin tube is 12 N/mm or less. 
     
     
         12 . A thermoplastic fluororesin tube comprising a tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer (FEP), the thermoplastic fluororesin tube having tearability in a longitudinal direction, wherein a thermal expansion coefficient in the longitudinal direction upon heating in a gaseous phase at a temperature of 100° C. for 5 minutes is 0% or more, wherein the thermoplastic fluororesin tube is produced by:
 subjecting a thermoplastic fluororesin comprising a tetrafluoroethylene-hexafluoropropylene-perfluoroalkyl vinyl ether copolymer (FEP) to melt extrusion molding to obtain a raw tube of the thermoplastic fluororesin tube; and 
 expanding an inner diameter of the raw tube while heating the raw tube to a temperature of from 110-135° C. 
 
     
     
         13 . The thermoplastic fluororesin tube according to  claim 12 , wherein the thermoplastic fluororesin further comprises a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA). 
     
     
         14 . The thermoplastic fluororesin tube according to  claim 12 , wherein a heat shrinkage ratio of an inner diameter of the thermoplastic fluororesin tube, upon heating in a gaseous phase at a temperature of 200° C. for 5 minutes, is 51% or more. 
     
     
         15 . The thermoplastic fluororesin tube according to  claim 12 , wherein the thermal expansion coefficient in the longitudinal direction upon heating at a temperature of 100° C. for 5 minutes is 0 to 4%. 
     
     
         16 . The thermoplastic fluororesin tube according to  claim 12 , which comprises a weld line in the longitudinal direction. 
     
     
         17 . The thermoplastic fluororesin tube according to  claim 12 , wherein a tear strength of the thermoplastic fluororesin tube is 12 N/mm or less.