Hair care compositions comprising malodor reduction materials

Abstract

The present invention discloses a hair care composition comprising, based on total composition weight, a) a sum total of from about 0.1% to about 2% of a perfume with one or more malodor reduction materials having a wt % from about 0.0001% to about 2% of one or more of said malodor reduction materials; b) from about 0.01% to about 10% of a scalp active material selected from the group consisting of sulfur and mixtures thereof; c) from about 0.1% to about 40% of a surfactant.

What is claimed: 
     
         1 . A hair care composition comprising, based on total composition weight,
 a) a sum total of from about 0.1% to about 2% of a perfume with one or more malodor reduction materials having a wt % from about 0.0001% to about 2% of one or more of said malodor reduction materials wherein the malodor reduction material is selected from the group consisting of 2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane], (1′,1′,5′, 5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene], 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate), Decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene], CEDRYL METHYL ETHER, Ethyl (1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate, 3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan, alpha,alpha,6,6-tetramethyl bicyclo[3.1.1]hept-2-ene-propanal, 4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane), 4aR,8aS)-7-methyloctahydro-1,4-methanonaphthalen-6(2H)-one, 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde, 8,8-dimethyl-6,7-dihydro-5H-naphthalene-2-carbaldehyde, 2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene]), (2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan, 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one), 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate, 3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine, (8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate), 4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole, 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane, 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate, 3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole, (3R-(3alpha, 3a,6alpha,7,8aalpha))-octahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-6-yl formate, (1S,2R,5S,7R,8R)-2,6,6,8-tetramethyltricyclo[5.3.1.01,5]undecan-8-ol, 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one, ((E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal, 1R-(1alpha,4beta,4aalpha,6beta,8aalpha))-octahydro-4,8a,9,9-tetramethyl-1,6-methano-1(2H)-naphthol, [(3Z)-4,11,11-trimethyl-8-methylidene-5-bicyclo[7.2.0]undec-3-enyl] acetate, (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol, Z)-6-ethylideneoctahydro-2H-5,8-methanochromen-2-one), 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one, 3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile, 4-(1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl)cyclohexan-1-ol, (E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-(E)-5H-4,7-methanoinden-5-ylindene)-3-methylbutan-2-ol, (E)-3,7-dimethylocta-2,6-dien-1-yl palmitate), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8,-hexamethyl-cyclopenta[g]benzopyran, 5H-Cyclopenta[h]quinazoline,6,6a,7,8,9,9a-hexahydro-7,7,8,9,9-pentamethyl-, Cyclopentaneacetic acid, 3-oxo-2-pentyl-, methyl ester, Cyclohexanol, 3-(5,5,6-trimethylbicyclo[2.2.1]hept-2-yl)-, Cyclopentanecarboxylic acid, 2-hexyl-3-oxo-, methyl ester, Naphtho[2,1-b]furan, dodecahydro-3a,6,6,9a-tetramethyl-, (3aR,5aS,9aS,9bR)-, Ethanone, 1-(1,2,3,5,6,7,8,8a-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)-, Ethanone, 1-(1, 2,3,4,6,7,8,8a-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)-, 2-Naphthalenecarboxaldehyde, 1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-, 1H-3a,7-Methanoazulen-6-ol, octahydro-3,6, 8,8-tetramethyl-, 6-acetate, (3R,3aS,6R,7R,8aS)-, Tricyclo[6.3.1.02,5]dodecan-1-ol, 4,4,8-trimethyl-, (1R,2S,5R,8S)-, 1H-3a,6-Methanoazulene-3-methanol, octahydro-7,7-dimethyl-8-methylene-, (3S,3aR,6R,8aS)-, 1H-Indole-1-heptanol, -1H-indol-1-yl-α,α,ε-trimethyl-, [(1R2S)-1-methyl-2-[[(1R3S5S)-122-trimethyl-3-bicyclo[3.1.0]hexanyl]methyl]cyclopropyl]methanol, 1-Naphthalenol, 1,2,3,4,4a,7,8,8a-octahydro-2,4a,5,8a-tetramethyl-, 1-formate, Cyclohexanepropanol, 2,2,6-trimethyl-α-propyl-, Cyclododecaneethanol, β-methyl-, Ethyl cyclohexanecarboxylate, 6-Oxabicyclo[3.2.1]octane, 5-methyl-1-(2,2,3-trimethyl-3-cyclopenten-1-yl)-, Cyclododecane, 1,1-dimethoxy-, 2, 6.10.-Dodecatrien-1-ol, 3,7,11-trimethyl-, 2-Nonynoic acid, methyl ester, 2,6-Nonadien-1-ol, (2E,6Z)-, 3,6-Nonadien-1-ol, Patchouli and derivatives, Patchouli oil MD, Patchouli Indonesia, Patchouli 30 and Oils, Patchouli, patchoulol synthase-modified  Saccharomyces cerevisiae -fermented, from carbohydrates sold under the trademark Clear Wood®, Mint Spicata Terpeneless SX, Mint Piperita Cascade SX and Peppermint oil mixture;
 b) from about 0.01% to about 10% of a scalp active material selected from the group consisting of sulfur and mixtures thereof; 
 c) from about 0.1% to about 40% of a surfactant. 
   
     
     
         2 . A hair care composition according to  claim 1  wherein the malodor reduction material has a sulfur malodor reduction value MORV>3 and a ClogP>3. 
     
     
         3 . A hair care composition according to  claim 1  wherein the malodor reduction material has a sulfur malodor reduction value MORV>3 and ClogP>3 and a VP>0.005. 
     
     
         4 . A hair care composition according to  claim 1  wherein the malodor reduction material is selected from the group consisting of [(1R2S)-1-methyl-2-[[(1R3S5S)-122-trimethyl-3-bicyclo[3.1.0]hexanyl]methyl]cyclopropyl]methanol, 1-Naphthalenol, 1,2,3,4,4a,7,8,8a-octahydro-2,4a,5,8a-tetramethyl-, 1-formate, Cyclohexanepropanol, 2,2,6-trimethyl-α-propyl-, Cyclododecaneethanol, β-methyl-, Ethyl cyclohexanecarboxylate, 6-Oxabicyclo[3.2.1]octane, 5-methyl-1-(2,2,3-trimethyl-3-cyclopenten-1-yl)-, Cyclododecane, 1,1-dimethoxy-, 2, 6,10-Dodecatrien-1-ol, 3,7,11-trimethyl-, 2-Nonynoic acid, methyl ester, 2,6-Nonadien-1-ol, (2E,6Z)-, 3,6-Nonadien-1-ol and mixtures thereof. 
     
     
         5 . A hair care composition according to  claim 1  wherein the malodor reduction material is selected from the group consisting of Patchouli and derivatives, Patchouli oil MD, Patchouli Indonesia, Patchouli 30, Oils, Patchouli, patchoulol synthase-modified Saccharomyces cerevisiae-fermented, from carbohydrates sold under the trademark Clear Wood® and mixtures thereof. 
     
     
         6 . A hair care composition according to  claim 1  wherein the malodor reduction material is selected from the group consisting of Mint Spicata Terpeneless SX, Mint Piperita Cascade SX, Peppermint oil mixture and mixtures thereof. 
     
     
         7 . A hair care composition according to  claim 1  wherein there is a cumulative sulfur odor of 0 to 2. 
     
     
         8 . A hair care composition according to  claim 1 , wherein the surfactant is selected from the group consisting of anionic, amphoteric or zwitterionic, cationic or mixtures thereof. 
     
     
         9 . A hair care composition according to  claim 1  wherein the composition comprises the sum total of from about 0.0001% to about 0.5% of the malodor reduction material. 
     
     
         10 . A hair care composition according to  claim 1  wherein the composition comprises the sum total of from about 0.0002% to about 0.25% of the malodor reduction material. 
     
     
         11 . A hair care composition according to  claim 1  wherein the hair care composition is a shampoo. 
     
     
         12 . A hair care composition according to  claim 1  wherein the hair care composition is a rinse off conditioner. 
     
     
         13 . A hair care composition according to  claim 1  wherein the hair care composition is a leave on treatment. 
     
     
         14 . A method of controlling malodors comprising: contacting a situs comprising a malodor and/or a situs that will become malodorous with a hair care composition selected from the group consisting of the hair care composition of  claims 1 . 
     
     
         15 . The method of  claim 14  wherein, said situs is a head of hair and said contacting step comprises contacting said head of hair with a sufficient amount of a hair care composition to provide said hair with a level of malodor reduction material at least 0.0001 mg of malodor reduction material.