US2024279779A1PendingUtilityA1

Strip made of 6xxx alloy and manufacturing process

Assignee: CONSTELLIUM NEUF BRISACHPriority: Jun 17, 2021Filed: Jun 16, 2022Published: Aug 22, 2024
Est. expiryJun 17, 2041(~14.9 yrs left)· nominal 20-yr term from priority
C22F 1/043C22F 1/002C22C 21/02
41
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Claims

Abstract

The invention relates to the field of 6XXX series aluminum alloy strips and to a process for manufacturing same. These strops are particularly useful for producing bodywork parts of motor vehicles on account of the compromise they offer between corrosion resistance and formability.

Claims

exact text as granted — not AI-modified
1 . An aluminum alloy strip with a composition of, in % by weight:
 Si: 1.2-1.5,   Fe: ≤0.25,   Cu: ≤0.05,   Mn: 50.15,   Mg: 0.20-0.45,   Cr: 0.002-0.09   Ni: ≤0.15   Zn: ≤0.15   Ti: ≤0.15   Zr: ≤0.15,   unavoidable elements and impurities in a maximum of 0.05% each, together 0.15% maximum, remainder aluminum.   
     
     
         2 . The aluminum alloy strip according to  claim 1  wherein Si: 1.25-1.45, optionally 1.25-1.40. 
     
     
         3 . The aluminum alloy strip according to  claim 1  wherein Fe: 0.10-0.20, or 0.10-0.15 or 0.15-0.20. 
     
     
         4 . The aluminum alloy strip according to  claim 1  wherein Mn: 0.05-0.10. 
     
     
         5 . The aluminum alloy strip according to  claim 1  wherein Mg: is less than or equal to 0.39%, optionally 0.35%, optionally 0.34%, mere optionally 0.33%. 
     
     
         6 . The aluminum alloy strip according to  claim 1  wherein Cu: maximum 0.03, or Cu 0.01-0.04 or Cu 0.02-0.04. 
     
     
         7 . The aluminum alloy strip according to  claim 1  wherein Ti≤0.10, or ≤0.06, or 0.02-0.08. 
     
     
         8 . The aluminum alloy strip according to  claim 1  wherein Cr 0.005-0.03 or Cr 0.01-0.05. 
     
     
         9 . The aluminum alloy strip according to  claim 1  wherein Ni 0.002-0.01 or Ni 0.005-0.02. 
     
     
         10 . The aluminum alloy strip according to  claim 1  wherein excess of Si content over Mg content is at least 0.95% by weight, optionally at least 1.00% by weight. 
     
     
         11 . The aluminum alloy strip according to  claim 1  wherein the strip of thickness between 0.7 and 1.0 mm in T4 temper has a minimum LDH of at least 26.0 mm, wherein the strip of thickness between 1.1 and 1.5 mm T4 temper has a minimum LDH of at least 26.5 mm. 
     
     
         12 . The aluminum alloy strip according to  claim 1 , wherein the average length of the filiform corrosion filaments, wherein according to EN 3665, in an unsanded zone is less than 2 mm, optionally less than 1 mm, after the strip has been pre-deformed by 2% in the rolling transverse direction, then painted, then paint bake at 180° C. for 20 minutes, or that the average length of the filiform corrosion filaments, characterized according to 3665, in an unsanded zone is less than 1 mm, optionally less than 0.8 mm, after the strip has been pre-deformed by 2% in a rolling transverse direction, then painted, then paint bake at 180° C. for 20 minutes. 
     
     
         13 . A method for manufacturing an aluminum alloy strip according to  claim 1  comprising:
 a. Casting a slab, optionally by semi-continuous vertical casting, 
 b. Homogenizing the slab optionally at a temperature between 500° C. and 600° C., optionally between 540 and 580° C. and optionally between 1 hour and 12 hours, optionally comprising a second stage between 420° C. and 550° C. with a maximum duration of 4 hours, 
 c. Cooling the slab to the hot rolling start temperature between 350° C. and 550° C. at a cooling rate optionally greater than 150° C./h or cooling the slab to room temperature and then reheating the slab to said hot rolling start temperature, 
 d. Hot rolling the slab into a strip, with the hot rolling end temperature between 250° C. and 450° C., 
 e. Cold rolling the strip, optionally in two parts separated by intermediate annealing, said annealing being optionally carried out on the strip rolled up into a coil, 
 f. Solution heat treating the strip, optionally between 500° C. and 600° C. for 10 to 60 s, followed by quenching, 
 g. Pre-ageing the strip by coiling the slab to a temperature of between 50 and 100° C., followed by cooling to room temperature, 
 h. Naturally ageing the strip at room temperature between 72 hours and 6 months. 
 
     
     
         14 . A car body part obtained by
 a. Supplying an aluminum alloy strip according to  claim 1 ,   b. Stamping   c. Painting   d. Paint baking between 15 and 60 minutes at a temperature of between 120 and 200° C.,   wherein average length of filiform corrosion filaments, after a corrosion test according to EN 3665, in an sanded zone is less than 2 mm, optionally less than 1 mm, or that the average length of filiform corrosion filaments in an unsanded zone is less than 1 mm, optionally less than 0.8 mm.

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