US2024295000A1PendingUtilityA1

High strength coated dual phase steel strip and method to produce it

Assignee: TATA STEEL IJMUIDEN BVPriority: Jul 7, 2021Filed: Jul 7, 2022Published: Sep 5, 2024
Est. expiryJul 7, 2041(~15 yrs left)· nominal 20-yr term from priority
C25D 3/44C25D 3/22C23C 2/40C23C 2/12C23C 2/06C22C 38/60C22C 38/06C22C 38/04C22C 38/02C22C 38/002C22C 38/001C21D 2211/008C21D 2211/005C21D 2211/003C21D 2211/002C21D 2211/001C21D 8/0273C21D 8/0263C21D 8/0236C23C 2/28C21D 9/46C21D 8/0226C22C 38/54C22C 38/50C22C 38/48C22C 38/46C22C 38/44C23C 2/0224C23C 2/02C21D 8/0473C21D 8/0436C21D 8/0426C21D 8/0478C21D 8/0278C22C 38/38C22C 38/32C22C 38/28C22C 38/24C22C 38/22C22C 38/14C22C 38/12C22C 38/58
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Claims

Abstract

A coated and optionally temper-rolled dual phase steel strip with a tensile strength Rm of 580-720 MPa and a yield strength Rp of 310-430 MPa high strength having improved formability. The invention also relates to a method for producing such steel strip and the use thereof.

Claims

exact text as granted — not AI-modified
1 . A dual phase steel strip consisting of, in wt. %: 
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   C: 
                   0.090-0.140 
                   B: 
                   0.0010-0.0050 
                 
                     
                   Mn: 
                   1.200-1.900 
                   S: 
                   at most 0.050 
                 
                     
                   Si: 
                   0.200-0.800 
                   P: 
                   at most 0.050 
                 
                     
                   Al: 
                   0.200-0.800 
                   N: 
                   at most 0.015 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
               
            
           
         
         and optionally one or more of the elements selected from: 
       
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cr: 
                   at most 0.500 
                   Nb: 
                   at most 0.060 
                 
                     
                   Mo: 
                   at most 0.400 
                   Ti: 
                   at most 0.060 
                 
                     
                   V: 
                   at most 0.200 
                   Ca: 
                   at most 0.0050 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
               
            
           
         
         the remainder being iron and unavoidable impurities, 
         wherein the steel has a tensile strength Rm of 580-720 MPa and a yield strength Rp of 310-430 MPa, and 
         wherein the steel strip is optionally i) a hot-dip galvanised or ii) electrogalvanized or iii) electroplated. 
       
     
     
         2 . The dual phase steel strip according to  claim 1 , consisting of, in wt. %: 
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   C: 
                   0.090-0.130 
                   B: 
                   0.0010-0.0040 
                 
                     
                   Mn: 
                   1.400-1.800 
                   S: 
                   at most 0.004 
                 
                     
                   Si: 
                   0.250-0.750 
                   P: 
                   at most 0.040 
                 
                     
                   Al: 
                   0.200-0.750 
                   N: 
                   at most 0.012 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
               
            
           
         
         and optionally one or more of the elements selected from: 
       
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cr: 
                   at most 0.400 
                   Nb: 
                   at most 0.050 
                 
                     
                   Mo: 
                   at most 0.300 
                   Ti: 
                   at most 0.050 
                 
                     
                   V: 
                   at most 0.150 
                   Ca: 
                   at most 0.0050 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
               
            
           
         
         the remainder being iron and unavoidable impurities. 
       
     
     
         3 . The dual phase steel strip according to  claim 1 , consisting of, in wt. %: 
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   C: 
                   0.090-0.130 
                   B: 
                   0.0010-0.0030 
                 
                     
                   Mn: 
                   1.400-1.750 
                   S: 
                   at most 0.003 
                 
                     
                   Si: 
                   0.250-0.700 
                   P: 
                   at most 0.015 
                 
                     
                   Al: 
                   0.200-0.650 
                   N: 
                   at most 0.006 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
               
            
           
         
         and optionally one or more of the elements selected from: 
       
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cr: 
                   at most 0.120 
                   Nb: 
                   at most 0.010 
                 
                     
                   Mo: 
                   at most 0.015 
                   Ti: 
                   at most 0.010 
                 
                     
                   V: 
                   at most 0.010 
                   Ca: 
                   at most 0.0050 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
               
            
           
         
         the remainder being iron and unavoidable impurities. 
       
     
     
         4 . The dual phase steel strip according to  claim 1 , consisting of, in wt. %: 
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   C: 
                   0.110-0.130 
                   B: 
                   0.0012-0.0028 
                 
                     
                   Mn: 
                   1.400-1.750 
                   S: 
                   at most 0.003 
                 
                     
                   Si: 
                   0.500-0.700 
                   P: 
                   at most 0.015 
                 
                     
                   Al: 
                   0.200-0.400 
                   N: 
                   at most 0.006 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
               
            
           
         
         and optionally one or more of the elements selected from: 
       
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cr: 
                   at most 0.040 
                   Nb: 
                   at most 0.010 
                 
                     
                   Mo: 
                   at most 0.015 
                   Ti: 
                   at most 0.010 
                 
                     
                   V: 
                   at most 0.010 
                   Ca: 
                   at most 0.0050 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
               
            
           
         
         the remainder being iron and unavoidable impurities. 
       
     
     
         5 . The dual phase steel strip according to  claim 1 , consisting of, in wt. %: 
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   C: 
                   0.110-0.130 
                   B: 
                   0.0012-0.0028 
                 
                     
                   Mn: 
                   1.400-1.750 
                   S: 
                   at most 0.003 
                 
                     
                   Si: 
                   0.500-0.700 
                   P: 
                   at most 0.015 
                 
                     
                   Al: 
                   0.200-0.400 
                   N: 
                   at most 0.006 
                 
                     
                   Cr: 
                   0.020-0.150 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
               
            
           
         
         and optionally one or more of the elements selected from: 
       
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Mo: 
                   at most 0.015 
                   Ti: 
                   at most 0.010 
                 
                     
                   V: 
                   at most 0.010 
                   Ca: 
                   at most 0.0050 
                 
                     
                   Nb: 
                   at most 0.010 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
               
            
           
         
         the remainder being iron and unavoidable impurities. 
       
     
     
         6 . The dual phase steel strip according to  claim 1 , consisting of, in wt. %: 
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   C: 
                   0.090-0.130 
                   B: 
                   0.0010-0.0035 
                 
                     
                   Mn: 
                   1.300-1.800 
                   S: 
                   at most 0.003 
                 
                     
                   Si: 
                   0.250-0.750 
                   P: 
                   at most 0.030 
                 
                     
                   Al: 
                   0.200-0.650 
                   N: 
                   at most 0.010 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
               
            
           
         
         and optionally one or more of the elements selected from: 
       
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cr: 
                   at most 0.150 
                   Nb: 
                   at most 0.040 
                 
                     
                   Mo: 
                   at most 0.200 
                   Ti: 
                   at most 0.040 
                 
                     
                   V: 
                   at most 0.100 
                   Ca: 
                   at most 0.0050 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
               
            
           
         
         the remainder being iron and unavoidable impurities. 
       
     
     
         7 . The dual phase steel strip according to  claim 1 , wherein one or more or all of Cr, Mo, V, Nb and Ti is present only as an impurity which means that, if applicable, Cr is below 0.020 wt. %, Ti is below 0.010 wt. %, V is below 0.010 wt. %, Mo is below 0.015 wt. %, Nb is below 0.010 wt. %. 
     
     
         8 . The dual phase steel strip according to  claim 1 , wherein the steel has a tensile strength Rm of 590-720 MPa and/or a yield strength Rp of 320-430 MPa. 
     
     
         9 . The dual phase steel strip according to  claim 1 , wherein the steel has a uniform elongation Ag of at least 18%. 
     
     
         10 . The dual phase steel strip according to  claim 1 , wherein the steel has a hole expansion capacity HEC of at least 35%. 
     
     
         11 . The dual phase steel strip according to  claim 1 , wherein the steel has an average strain hardening exponent or n-value of at least 0.16. 
     
     
         12 . The dual phase steel strip according to  claim 1 , which is provided with the metallic coating by hot-dip coating immediately subsequent to continuous annealing or by electrodeposition of the strip after cooling the continuously annealed strip to ambient temperature. 
     
     
         13 . A method for producing a coated and optionally temper-rolled dual phase steel strip with a tensile strength Rm of 580-720 MPa and a yield strength Rp of 310-430 MPa according to  claim 1 , comprising the following steps:
 providing a hot-rolled steel strip by hot rolling a continuously cast slab with a composition consisting of, in wt. %:   
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   C: 
                   0.090-0.140 
                   B: 
                   0.0010-0.0050 
                 
                     
                   Mn: 
                   1.200-1.900 
                   S: 
                   at most 0.050 
                 
                     
                   Si: 
                   0.200-0.800 
                   P: 
                   at most 0.050 
                 
                     
                   Al: 
                   0.200-0.800 
                   N: 
                   at most 0.015 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
               
            
           
         
       
       and optionally one or more of the elements selected from: 
       
         
           
                 
                 
                 
                 
                 
               
                     
                     
                 
                     
                   Cr: 
                   at most 0.500 
                   Nb: 
                   at most 0.060 
                 
                     
                   Mo: 
                   at most 0.400 
                   Ti: 
                   at most 0.060 
                 
                     
                   V: 
                   at most 0.200 
                   Ca: 
                   at most 0.0050 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
               
            
           
         
       
       the remainder being iron and unavoidable impurities, 
       to a hot-rolled strip having a thickness of 2.0-4.5 mm, wherein finish-rolling is performed while the strip has an austenitic microstructure;
 Cooling the hot-rolled strip after finish-rolling with a cooling rate of at least 30° C./s; 
 Coiling the cooled strip at a coiling temperature CT in the range of 500 to 650° C. wherein the amount of austenite is more than 60% and the coiled strip is subsequently allowed to cool to ambient temperatures; 
 Uncoiling the coiled hot-rolled strip, followed by pickling and cold-rolling with a reduction of 40-80%; 
 Continuous annealing of the cold-rolled strip by: 
 i. heating the strip to a temperature T 1  in the range of 550-710° C. with a heating rate HR 1  of at least 3° C./s to allow the recrystallisation of the cold-rolled strip to proceed for at least 60% prior to the start of the austenite formation; 
 ii. further heating of the strip with an average heating rate HR 2  to a temperature T 2  in the range of (Ac1+50° C.) to (Ac3−30° C.) to form a partially austenitic microstructure; 
 iii. subsequently either:
 a. keeping the strip at T 2  for a time period t 2  of up to 300 s, followed by slow cooling of the strip with a cooling rate CR 1  in the range of 0.5-12° C./s to a temperature T 3  in the range of 600-790° C., preferably 620-790° C. so that 16-30% austenite is present in the slow cooled strip, or 
 b. immediately slowly cooling the strip from T 2  with a cooling rate CR 1  in the range of 0.5-12° C./s to a temperature T 3  in the range of 600-790° C. so that 16-30% austenite is present in the slow cooled strip; 
 
 iv. rapidly cooling the slowly cooled strip comprising 16-30% austenite with an average cooling rate CR 2  in the range of 5-70° C./s either:
 a. to a temperature T 4  in the range of 330-470° C.; or 
 b. to an overaging temperature T_oa for a time t_oa in the range of 5 to 100 s, wherein T_oa is between 390 and 465° C.; 
 
 v. cooling the steel strip at a cooling rate CR 3  of at least 4° C./s to a temperature below 300° C.; 
 wherein the strip is a). provided with a metallic coating by hot-dip coating between step iv. and v., optionally followed by galvannealing the hot-dip coated strip, or b). with a metallic coating by electrodeposition after step v.; 
 Optionally temper rolling or tension levelling of the coated steel strip with a reduction of at most 0.70%; 
 Coiling the coated steel strip or cutting the coated steel strip into sheets or blanks; 
 Optionally shaping the coated steel strip, sheet or blank via cold-forming operations like stamping, bending, deep drawing or via warm press forming or hot press forming. 
 
     
     
         14 . The method according to  claim 13 , wherein one or more of the following process parameters apply:
 Coiling temperature is below 630° C.;   Coiling temperature is above 520° C.;   Cold rolling reduction is at least 44%;   T 3  is between 400 and 470° C.   
     
     
         15 . The method according to  claim 13  to produce a coated steel strip, sheet or blank having one or more of
 a uniform elongation Ag of at least 18%; 
 a total elongation A80 or JIS of at least 26%; 
 a hole expansion capacity HEC of at least 35%; 
 a total elongation minus uniform elongation of at least 7.0%. 
 
     
     
         16 . A car or truck component, such as an automotive chassis or safety component, a B-pillar, a reinforcement (crash) part, a front crash beam, a seat member, a bumper part, a door part, a component of the body in white, a component of the frame or the sub-frame, an electric battery holder or container part, said component having been produced from the steel according to  claim 1 . 
     
     
         17 . The dual phase steel strip according to  claim 1 , wherein the steel has a uniform elongation Ag of at least 30%. 
     
     
         18 . The dual phase steel strip according to  claim 1 , wherein the steel has an average strain hardening exponent or n-value of at least 0.24. 
     
     
         19 . The method of  claim 13 , wherein the temperature T 3  is in the range of 620-790° C. 
     
     
         20 . The method according to  claim 13 , wherein one or more of the following process parameters apply:
 Coiling temperature is below 600° C.;   Coiling temperature is above 530° C.;   Cold rolling reduction is at least 67%;   T 3  is between 400 and 470° C.

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