US2024352551A1PendingUtilityA1

Cold rolled steel sheet having excellent weldability, strength, and formability, and method for manufacturing same

Assignee: POSCO CO LTDPriority: Aug 26, 2021Filed: Aug 25, 2022Published: Oct 24, 2024
Est. expiryAug 26, 2041(~15.1 yrs left)· nominal 20-yr term from priority
C21D 8/02C22C 38/38C22C 38/32C22C 38/28C22C 38/26C22C 38/22C22C 38/06C22C 38/02C22C 38/002C22C 38/001C21D 2211/008C21D 2211/005C21D 2211/002C21D 2211/001C21D 8/0278C21D 8/0263C21D 8/0236C21D 8/0226C21D 6/008C21D 6/005C21D 6/004C21D 1/84C21D 1/18C23C 2/06B21C 47/02C21D 8/0273C22C 38/14C22C 38/12C22C 38/04C21D 9/46C21D 8/0205
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Claims

Abstract

Provided is a cold-rolled steel sheet including: by weight %, C: 0.10 to 0.16%, Si: 0.3 to 0.8%, Al: 0.01 to 0.5%, Mn: 2.0 to 3.0%, Cr: 0.001 to 0.5%, Mo: 0.001 to 0.5%, B: 0.0001 to 0.001%, Nb: 0.001 to 0.05%, Ti: 0.001 to 0.05%, P: 0.04% or less (excluding 0%), S: 0.01% or less (excluding 0%), N: 0.01% or less (excluding 0%), a remainder of Fe, and other unavoidable impurities, as a microstructure, by area %, ferrite: 10% or less (excluding 0%), retained austenite: more than 1% to 5% or less, martensite: 25% or more but less than 50%, and bainite: 35% or more but less than 70%. An average size of martensite-austenite (MA) in the bainite is 0.35 to 0.55 μm.

Claims

exact text as granted — not AI-modified
1 . A cold-rolled steel sheet comprising:
 by weight %, C: 0.10 to 0.16%, Si: 0.3 to 0.8%, Al: 0.01 to 0.5%, Mn: 2.0 to 3.0%, Cr: 0.001 to 0.5%, Mo: 0.001 to 0.5%, B: 0.0001 to 0.001%, Nb: 0.001 to 0.05%, Ti: 0.001 to 0.05%, P: 0.04% or less (excluding 0%), S: 0.01% or less (excluding 0%), N: 0.01% or less (excluding 0%), a remainder of Fe, and other unavoidable impurities,   as a microstructure comprises, by area %, ferrite: 10% or less (excluding 0%), retained austenite: more than 1% to 5% or less, martensite: 25% or more but less than 50%, and bainite: 35% or more but less than 70%, and   an average size of martensite-austenite (MA) in the bainite is 0.35 to 0.55 μm.   
     
     
         2 . The cold-rolled steel sheet of  claim 1 , wherein a value defined by the following Relationship 1 satisfies 70 or more: 
       
         
           
             
               
                 
                   
                     
                       2 
                       ⁢ 
                       3 
                       ⁢ 
                       4 
                       × 
                       
                         [ 
                         C 
                         ] 
                       
                     
                     - 
                     
                       29 
                       × 
                       
                         [ 
                         Si 
                         ] 
                       
                     
                     - 
                     
                       1 
                       ⁢ 
                       2 
                       ⁢ 
                       8 
                       × 
                       
                         [ 
                         Al 
                         ] 
                       
                     
                     + 
                     
                       2 
                       ⁢ 
                       9 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     + 
                     
                       1 
                       ⁢ 
                       0 
                       × 
                       
                         [ 
                         Cr 
                         ] 
                       
                     
                     - 
                     
                       1 
                       ⁢ 
                       7 
                       × 
                       
                         [ 
                         Mo 
                         ] 
                       
                     
                     - 
                     
                       3 
                       ⁢ 
                       7 
                       × 
                       
                         [ 
                         Nb 
                         ] 
                       
                     
                     - 
                     
                       4 
                       ⁢ 
                       9 
                       × 
                       
                         [ 
                         Ti 
                         ] 
                       
                     
                     + 
                     
                       100 
                       × 
                       
                         [ 
                         B 
                         ] 
                       
                     
                   
                 
                 
                   
                     [ 
                     
                       Relationship 
                       ⁢ 
                            
                       1 
                     
                     ] 
                   
                 
               
             
           
         
         where [C], [Si], [Al], [Mn], [Cr], [Mo], [Nb], [Ti], and [B] represent weight percentages of the elements in parentheses, respectively. 
       
     
     
         3 . The cold-rolled steel sheet of  claim 1 , wherein a value defined by the following Relationship 2 satisfies 270 or more and 330 or less: 
       
         
           
             
               
                 
                   
                     
                       2 
                       ⁢ 
                       7 
                       ⁢ 
                       0 
                       × 
                       
                         [ 
                         C 
                         ] 
                       
                     
                     + 
                     
                       9 
                       ⁢ 
                       0 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                     + 
                     
                       7 
                       ⁢ 
                       0 
                       × 
                       
                         [ 
                         Cr 
                         ] 
                       
                     
                     + 
                     
                       8 
                       ⁢ 
                       0 
                       × 
                       
                         [ 
                         Mo 
                         ] 
                       
                     
                   
                 
                 
                   
                     [ 
                     
                       Relationship 
                       ⁢ 
                            
                       2 
                     
                     ] 
                   
                 
               
             
           
         
         where [C], [Mn], [Cr], and [Mo] represent weight percentages of the elements in parentheses, respectively. 
       
     
     
         4 . The cold-rolled steel sheet of  claim 1 , wherein a value defined by the following Relationship 3 satisfies 1.8 or less: 
       
         
           
             
               
                 
                   
                     
                       5 
                       × 
                       
                         [ 
                         C 
                         ] 
                       
                     
                     + 
                     
                       [ 
                       Si 
                       ] 
                     
                     + 
                     
                       
                         0 
                         . 
                         5 
                       
                       × 
                       
                         [ 
                         Al 
                         ] 
                       
                     
                   
                 
                 
                   
                     [ 
                     
                       Relationship 
                       ⁢ 
                            
                       3 
                     
                     ] 
                   
                 
               
             
           
         
         where [C], [Si], and [Al] represent weight percentages of the elements in parentheses, respectively. 
       
     
     
         5 . The cold-rolled steel sheet of  claim 1 , wherein the microstructure comprises, by area %, 2 to 7% of the ferrite. 
     
     
         6 . The cold-rolled steel sheet of  claim 1 , wherein the microstructure comprises, by area %, 2 to 4% of the retained austenite. 
     
     
         7 . The cold-rolled steel sheet of  claim 1 , wherein the microstructure comprises, by area %, 45 to 63% of the bainite. 
     
     
         8 . The cold-rolled steel sheet of  claim 1 , wherein the microstructure comprises, by area %, 29 to 49% of the martensite. 
     
     
         9 . The cold-rolled steel sheet of  claim 1 , wherein the cold-rolled steel sheet has a tensile strength of 980 to 1150 MPa and a yield strength of 740 to 950 MPa. 
     
     
         10 . The cold-rolled steel sheet of  claim 1 , wherein the cold-rolled steel sheet has a hole expansion ratio (HER) of 45% or more. 
     
     
         11 . A method for manufacturing a cold-rolled steel sheet, comprising:
 heating a steel slab including, by weight %, C: 0.10 to 0.16%, Si: 0.3 to 0.8%, Al: 0.01 to 0.5%, Mn: 2.0 to 3.0%, Cr: 0.001 to 0.5%, Mo: 0.001 to 0.5%, B: 0.0001 to 0.001%, Nb: 0.001 to 0.05%, Ti: 0.001 to 0.05%, P: 0.04% or less (excluding 0%), S: 0.01% or less (excluding 0%), N: 0.01% or less (excluding 0%), a remainder of Fe, and other unavoidable impurities;   hot-rolling the heated slab in a finish hot rolling temperature range of 830 to 980° C. to obtain a hot-rolled steel sheet;   coiling the hot-rolled steel sheet in a temperature range of 450 to 700° C.;   cold-rolling the coiled hot-rolled steel sheet;   continuously annealing the cold-rolled steel sheet in a temperature range of 790 to 830° C.;   primary cooling the continuously annealed steel sheet at an average cooling rate of less than 10° C./s to a primary cooling end temperature of 450 to 600° C.;   secondary cooling the primary cooled steel sheet at an average cooling rate of 10° C./s or more to a secondary cooling end temperature of 250 to 350° C.; and   reheating the secondary cooled steel sheet to a temperature in a range of 350 to 480° C.,   wherein the method for manufacturing the cold-rolled steel sheet satisfies the following Relationship 4:   
       
         
           
             
               
                 
                   
                     
                       V 
                       ⁢ 
                       
                         1 
                         / 
                         V 
                       
                       ⁢ 
                       2 
                       × 
                       t 
                     
                     > 
                     
                       0 
                       . 
                       5 
                     
                   
                 
                 
                   
                     [ 
                     
                       Relationship 
                       ⁢ 
                             
                       4 
                     
                     ] 
                   
                 
               
             
           
         
       
       where V1 represents an average cooling rate during the primary cooling, V2 represents an average cooling rate during the secondary cooling, and t represents a thickness of the cold-rolled steel sheet. 
     
     
         12 . The method of  claim 11 , wherein, during the cold-rolling, a cold-rolling reduction rate is 30 to 60%. 
     
     
         13 . The method of  claim 11 , further comprising plating the reheated steel sheet in a zinc plating bath in a temperature range of 450 to 470° C. 
     
     
         14 . The method of  claim 13 , further comprising alloying and heat-treating the plated steel sheet in a temperature range of 470 to 550° C. 
     
     
         15 . The method of  claim 14 , further comprising cooling the alloy heat-treated steel sheet to room temperature and then temper-rolling the cooled alloy heat-treated steel sheet at a reduction ratio of less than 1%. 
     
     
         16 . The method of  claim 11 , wherein an average temperature increase rate during the reheating is 0.5 to 2.5° C./s.

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