US2025179594A1PendingUtilityA1

Method for producing molten pig iron

Assignee: JFE STEEL CORPPriority: Mar 7, 2022Filed: Feb 28, 2023Published: Jun 5, 2025
Est. expiryMar 7, 2042(~15.6 yrs left)· nominal 20-yr term from priority
C21B 2100/00C21B 2100/26C22B 1/02C22B 1/24C22B 1/16C21B 7/00C21B 7/002C21B 5/008C21B 2100/22C21B 2100/282C21B 11/02C21B 5/06
54
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Claims

Abstract

A method for producing molten pig iron includes a first step of producing carbon-material-containing agglomerated ore from an iron-containing and carbon-containing raw materials, a second step of blowing an oxygen-containing gas into the carbon-material-containing agglomerated ore to reduce and melt it, thereby producing molten pig iron, and a third step of bringing a carbon-containing gas containing carbon monoxide and carbon dioxide produced as a by-product of the reduction into contact with a porous material, thereby recovering carbon, in which in the first step, the carbon recovered in the third step is used for a part of or an entirety of the carbon-containing raw material. The method may include, instead of the second step, a reduction step of heating the carbon-material-containing agglomerated ore to 1160 to 1450° C., and then cooling the carbon-material-containing agglomerated ore to obtain reduced iron, and a step of melting the reduced iron to produce molten pig iron.

Claims

exact text as granted — not AI-modified
1 . A method for producing molten pig iron, comprising:
 a first step of producing a carbon-material-containing agglomerated ore from an iron-containing raw material and a carbon-containing raw material;   a second step of blowing an oxygen-containing gas into the carbon-material-containing agglomerated ore to reduce and melt the carbon-material-containing agglomerated ore, thereby producing molten pig iron; and   a third step of bringing a carbon-containing gas containing carbon monoxide and carbon dioxide produced as a by-product of the reduction into contact with a porous material, thereby recovering carbon,   characterized in that:   in the first step, the carbon recovered in the third step is used for a part of or an entirety of the carbon-containing raw material.   
     
     
         2 . The method for producing molten pig iron according to  claim 1 , comprising, instead of the second step:
 a reduction step of obtaining reduced iron in which the carbon-material-containing agglomerated ore is heated to 1160 to 1450° C., reduced, melted, and then cooled, and   a melting step of producing molten pig iron in which the reduced iron is melted.   
     
     
         3 . The method for producing molten pig iron according to  claim 1 , wherein in the third step, the carbon-containing gas further contains a gas containing carbon monoxide and carbon dioxide produced as a by-product of a refining step of molten iron. 
     
     
         4 . The method for producing molten pig iron according to  claim 1 , further comprising, before bringing the carbon-containing gas into contact with the porous material in the third step, supplying hydrogen to the carbon-containing gas and heating the carbon-containing gas to 800 to 1200° C. to convert the carbon dioxide contained in the carbon-containing gas to carbon monoxide. 
     
     
         5 . The method for producing molten pig iron according to  claim 4 , further comprising, after heating the carbon-containing gas but before bringing the carbon-containing gas into contact with the porous material in the third step, removing water contained in the carbon-containing gas. 
     
     
         6 . The method for producing molten pig iron according to  claim 5 , comprising removing water contained in the carbon-containing gas and water generated through a reforming reaction of the carbon-containing gas so as to satisfy the following expression (1): 
       
         
           
             
               
                 
                   
                     [ 
                     
                       Math 
                       . 
                           
                       1 
                     
                     ] 
                   
                 
                 
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                         [ 
                         
                           
                             H 
                             2 
                           
                           ⁢ 
                           O 
                         
                         ] 
                       
                       / 
                       
                         ( 
                         
                           
                             [ 
                             
                               
                                 H 
                                 2 
                               
                               ⁢ 
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                             ] 
                           
                           + 
                           
                             [ 
                             
                               H 
                               2 
                             
                             ] 
                           
                         
                         ) 
                       
                     
                     < 
                     0.1 
                   
                 
                 
                   
                     ( 
                     1 
                     ) 
                   
                 
               
             
           
         
         where [H 2 O] represents a water concentration (volume %) in a reformed mixed gas, and [H 2 ] represents a hydrogen concentration (volume %) in the reformed mixed gas. 
       
     
     
         7 . The method for producing molten pig iron according to  claim 1 , wherein in the third step, the porous material is iron, and a part of the recovered carbon is iron carbide. 
     
     
         8 . The method for producing molten pig iron according to  claim 1 , wherein a particle size of the carbon-containing raw material is 100 μm or less. 
     
     
         9 . The method for producing molten pig iron according to  claim 1 , wherein in the first step, the carbon-containing raw material further contains biomass. 
     
     
         10 . The method for producing molten pig iron according to  claim 1 ,
 wherein:   the iron-containing raw material is iron ores, and   the method further comprises a pretreatment step of subjecting the iron ores to heat treatment in a temperature range of 300° C. to 1000° C. before the first step.   
     
     
         11 . The method for producing molten pig iron according to  claim 2 , wherein in the third step, the carbon-containing gas further contains a gas containing carbon monoxide and carbon dioxide produced as a by-product of a refining step of molten iron. 
     
     
         12 . The method for producing molten pig iron according to  claim 2 , further comprising, before bringing the carbon-containing gas into contact with the porous material in the third step, supplying hydrogen to the carbon-containing gas and heating the carbon-containing gas to 800 to 1200° C. to convert the carbon dioxide contained in the carbon-containing gas to carbon monoxide. 
     
     
         13 . The method for producing molten pig iron according to  claim 3 , further comprising, before bringing the carbon-containing gas into contact with the porous material in the third step, supplying hydrogen to the carbon-containing gas and heating the carbon-containing gas to 800 to 1200° C. to convert the carbon dioxide contained in the carbon-containing gas to carbon monoxide. 
     
     
         14 . The method for producing molten pig iron according to  claim 11 , further comprising, before bringing the carbon-containing gas into contact with the porous material in the third step, supplying hydrogen to the carbon-containing gas and heating the carbon-containing gas to 800 to 1200° C. to convert the carbon dioxide contained in the carbon-containing gas to carbon monoxide. 
     
     
         15 . The method for producing molten pig iron according to  claim 12 , further comprising, after heating the carbon-containing gas but before bringing the carbon-containing gas into contact with the porous material in the third step, removing water contained in the carbon-containing gas. 
     
     
         16 . The method for producing molten pig iron according to  claim 13 , further comprising, after heating the carbon-containing gas but before bringing the carbon-containing gas into contact with the porous material in the third step, removing water contained in the carbon-containing gas. 
     
     
         17 . The method for producing molten pig iron according to  claim 14 , further comprising, after heating the carbon-containing gas but before bringing the carbon-containing gas into contact with the porous material in the third step, removing water contained in the carbon-containing gas. 
     
     
         18 . A method for producing molten pig iron according to  claim 15 , comprising removing water contained in the carbon-containing gas and water generated through a reforming reaction of the carbon-containing gas so as to satisfy the following Expression (1): 
       
         
           
             
               
                 
                   
                     [ 
                     
                       Math 
                       . 
                           
                       1 
                     
                     ] 
                   
                 
                 
                    
                 
               
             
           
         
         
           
             
               
                 
                   
                     
                       
                         [ 
                         
                           
                             H 
                             2 
                           
                           ⁢ 
                           O 
                         
                         ] 
                       
                       / 
                       
                         ( 
                         
                           
                             [ 
                             
                               
                                 H 
                                 2 
                               
                               ⁢ 
                               O 
                             
                             ] 
                           
                           + 
                           
                             [ 
                             
                               H 
                               2 
                             
                             ] 
                           
                         
                         ) 
                       
                     
                     < 
                     0.1 
                   
                 
                 
                   
                     ( 
                     1 
                     ) 
                   
                 
               
             
           
         
         where [H 2 O] represents a water concentration (volume %) in a reformed mixed gas, and [H 2 ] represents a hydrogen concentration (volume %) in the reformed mixed gas. 
       
     
     
         19 . A method for producing molten pig iron according to  claim 16 , comprising removing water contained in the carbon-containing gas and water generated through a reforming reaction of the carbon-containing gas so as to satisfy the following Expression (1): 
       
         
           
             
               
                 
                   
                     [ 
                     
                       Math 
                       . 
                           
                       1 
                     
                     ] 
                   
                 
                 
                    
                 
               
             
           
         
         
           
             
               
                 
                   
                     
                       
                         [ 
                         
                           
                             H 
                             2 
                           
                           ⁢ 
                           O 
                         
                         ] 
                       
                       / 
                       
                         ( 
                         
                           
                             [ 
                             
                               
                                 H 
                                 2 
                               
                               ⁢ 
                               O 
                             
                             ] 
                           
                           + 
                           
                             [ 
                             
                               H 
                               2 
                             
                             ] 
                           
                         
                         ) 
                       
                     
                     < 
                     0.1 
                   
                 
                 
                   
                     ( 
                     1 
                     ) 
                   
                 
               
             
           
         
         where [H 2 O] represents a water concentration (volume %) in a reformed mixed gas, and [H 2 ] represents a hydrogen concentration (volume %) in the reformed mixed gas. 
       
     
     
         20 . A method for producing molten pig iron according to  claim 17 , comprising removing water contained in the carbon-containing gas and water generated through a reforming reaction of the carbon-containing gas so as to satisfy the following Expression (1): 
       
         
           
             
               
                 
                   
                     [ 
                     
                       Math 
                       . 
                           
                       1 
                     
                     ] 
                   
                 
                 
                    
                 
               
             
           
         
         
           
             
               
                 
                   
                     
                       
                         [ 
                         
                           
                             H 
                             2 
                           
                           ⁢ 
                           O 
                         
                         ] 
                       
                       / 
                       
                         ( 
                         
                           
                             [ 
                             
                               
                                 H 
                                 2 
                               
                               ⁢ 
                               O 
                             
                             ] 
                           
                           + 
                           
                             [ 
                             
                               H 
                               2 
                             
                             ] 
                           
                         
                         ) 
                       
                     
                     < 
                     0.1 
                   
                 
                 
                   
                     ( 
                     1 
                     ) 
                   
                 
               
             
           
         
         where [H 2 O] represents a water concentration (volume %) in a reformed mixed gas, and [H 2 ] represents a hydrogen concentration (volume %) in the reformed mixed gas.

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