US2025327158A1PendingUtilityA1

Martensitic stainless steel material

Assignee: NIPPON STEEL CORPPriority: Mar 24, 2021Filed: Mar 23, 2022Published: Oct 23, 2025
Est. expiryMar 24, 2041(~14.6 yrs left)· nominal 20-yr term from priority
C21D 8/02C21D 8/10C21D 8/06C22C 38/60C22C 38/50C22C 38/48C22C 38/46C22C 38/44C22C 38/42C22C 38/06C22C 38/04C22C 38/02C22C 38/008C22C 38/004C22C 38/002C22C 38/001C21D 2211/008C21D 9/46C21D 8/0263C21D 8/0226C21D 6/008C21D 6/007C21D 6/005C21D 6/004C21D 1/18C21D 9/0075C21D 8/0247C21D 1/25C22C 38/52C21D 9/08C21D 8/0205
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Claims

Abstract

A martensitic stainless steel material that achieves both a high yield strength and excellent SSC resistance is provided. The martensitic stainless steel material according to the present disclosure consists of, in mass %, C: 0.030% or less, Si: 1.00% or less, Mn: 1.00% or less, P: 0.030% or less, S: 0.0050% or less, Cu: 0.01 to 3.50%, Cr: 10.00 to 14.00%, Ni: 4.50 to 7.50%, Mo: 1.00 to 4.00%, Ti: 0.050 to 0.300%, V: 0.01 to 1.00%, Al: 0.001 to 0.100%, Co: 0.010 to 0.500%, Ca: 0.0005 to 0.0050%, Sn: 0.0005 to 0.0500%, N: 0.0010 to 0.0500%, O: 0.050% or less, and the balance: Fe and impurities, and has a yield strength of 758 MPa or more. Within this range, the contents of elements and the yield strength satisfy Formula (1) described in the description.

Claims

exact text as granted — not AI-modified
1 . A martensitic stainless steel material consisting of, in mass %,
 C: 0.030% or less,   Si: 1.00% or less,   Mn: 1.00% or less,   P: 0.030% or less,   S: 0.0050% or less,   Cu: 0.01 to 3.50%,   Cr: 10.00 to 14.00%,   Ni: 4.50 to 7.50%,   Mo: 1.00 to 4.00%,   Ti: 0.050 to 0.300%,   V: 0.01 to 1.00%,   Al: 0.001 to 0.100%,   Co: 0.010 to 0.500%,   Ca: 0.0005 to 0.0050%,   Sn: 0.0005 to 0.0500%,   N: 0.0010 to 0.0500%,   O: 0.050% or less,   W: 0 to 0.50%,   Nb: 0 to 0.500%,   As: 0 to 0.0100%,   Sb: 0 to 0.0100%, and   the balance: Fe and impurities,   wherein:   a yield strength is 758 MPa or more; and   within a range of contents of elements and the yield strength of the martensitic stainless steel material, the contents of elements and the yield strength satisfy Formula (1);   
       
         
           
             
               
                 
                   
                     0.15 
                     ≤ 
                     
                       
                         ( 
                         
                           
                             S 
                             ⁢ 
                             n 
                           
                           + 
                           
                             A 
                             ⁢ 
                             s 
                           
                           + 
                           Sb 
                         
                         ) 
                       
                       / 
                       
                         { 
                         
                           
                             ( 
                             
                               
                                 C 
                                 ⁢ 
                                 u 
                               
                               + 
                               Ni 
                             
                             ) 
                           
                           / 
                           YS 
                         
                         } 
                       
                     
                     ≤ 
                     
                       
                         1 
                         . 
                         0 
                       
                       ⁢ 
                       0 
                     
                   
                 
                 
                   
                     ( 
                     1 
                     ) 
                   
                 
               
             
           
         
         where, in Formula (1), a content of a corresponding element in percent by mass is substituted for each symbol of an element, and a yield strength in MPa is substituted for YS, and, if a corresponding element is not contained, “0” is substituted for the symbol of the relevant element. 
       
     
     
         2 . The martensitic stainless steel material according to  claim 1 , containing one or more elements selected from a group consisting of:
 W: 0.01 to 0.50%,   Nb: 0.001 to 0.500%,   As: 0.0001 to 0.0100%, and   Sb: 0.0001 to 0.0100%.   
     
     
         1 . A martensitic stainless steel material consisting of, in mass %,
 C: 0.030% or less,   Si: 1.0 0 % or less,   Mn: 1.00% or less,   P: 0.030% or less,   S: 0.0050% or less,   Cu: 0.01 to 3.50%,   Cr: 10.00 to 14.00%,   Ni: 4.50 to 7.50%,   Mo: 1.00 to 4.00%,   Ti: 0.050 to 0.300%,   V: 0.01 to 1.00%,   Al: 0.001 to 0.100%,   Co: 0.010 to 0.500%,   Ca: 0.0005 to 0.0050%,   Sn: 0.0005 to 0.0500%,   N: 0.0010 to 0.0500%,   O: 0.050% or less,   W: 0 to 0.50%,   Nb: 0 to 0.500%,   As: 0 to 0.0100%,   Sb: 0 to 0.0100%, and   the balance: Fe and impurities,   wherein:   a yield strength is 758 MPa or more; and   within a range of contents of elements and the yield strength of the martensitic stainless steel material, the contents of elements and the yield strength satisfy Formula (1);   
       
         
           
             
               
                 
                   
                     0.15 
                     ≤ 
                     
                       
                         ( 
                         
                           
                             S 
                             ⁢ 
                             n 
                           
                           + 
                           
                             A 
                             ⁢ 
                             s 
                           
                           + 
                           Sb 
                         
                         ) 
                       
                       / 
                       
                         { 
                         
                           
                             ( 
                             
                               
                                 C 
                                 ⁢ 
                                 u 
                               
                               + 
                               Ni 
                             
                             ) 
                           
                           / 
                           YS 
                         
                         } 
                       
                     
                     ≤ 
                     
                       
                         1 
                         . 
                         0 
                       
                       ⁢ 
                       0 
                     
                   
                 
                 
                   
                     ( 
                     1 
                     ) 
                   
                 
               
             
           
         
         where, in Formula (1), a content of a corresponding element in percent by mass is substituted for each symbol of an element, and a yield strength in MPa is substituted for YS, and, if a corresponding element is not contained, “0” is substituted for the symbol of the relevant element. 
       
     
     
         2 . The martensitic stainless steel material according to  claim 1 , containing one or more elements selected from a group consisting of:
 W: 0.01 to 0.50%,   Nb: 0.001 to 0.500%,   As: 0.0001 to 0.0100%, and   Sb: 0.0001 to 0.0100%.

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