Process for stable blend of waste plastic with petroleum feed for feeding to oil refinery units and process of preparing same

Abstract

Provided is a blend of a bio-feed and 1-20 wt. % of plastic, based on the weight of the blend, with the plastic comprising polyethylene and/or polypropylene, and the plastic in the blend comprising finely dispersed microcrystalline particles having an average particle size of 10 micron to less than 100 microns and less than 100 ppm chloride. A process for preparing a blend of plastic and bio-feed is provided, comprising mixing together a bio-feed and a plastic comprising polyethylene and/or polypropylene and heating the mixture in the range of from 550° F. to 700° F. The blend mixture is then hot filtered and then optionally treated with a chloride removal guard bed. The resulting blend can then be cooled and stored or sent directly to a refinery conversion unit.

What is claimed is: 
     
         1 . A process for preparing a blend of plastic and bio-feed comprising:
 (a) creating a mixture of a bio-feed and plastic comprising polyethylene and/or polypropylene and heating the mixture in the range of about 550° F. to about 700° F. (288-371° C.);   (b) recovering a product from step (a) and hot filtering the product to remove contaminants and produce a filtered blend; and   (c) then treating the filtered blend recovered from (b) with a chloride removal guard bed catalyst.   
     
     
         2 . The process of  claim 1 , wherein the heating is conducted while stripping the liquid using a gas such as nitrogen, hydrogen, steam, or light offgas from a conversion unit. 
     
     
         3 . The process of  claim 1 , wherein the treating of the filtered blend is conducted at a temperature of 250°-700° F. (121° to 371° C.) with a residence time of 5-240 minutes at a final treating temperature. 
     
     
         4 . The process of  claim 1 , wherein the amount of plastic mixed with the bio-feed ranges from 1-20 wt. % of the blend. 
     
     
         5 . The process of  claim 1 , wherein the amount of plastic in the blend comprises from 1-10 wt. % of the blend. 
     
     
         6 . The process of  claim 1 , wherein the plastic comprises low density polyethylene. 
     
     
         7 . The process of  claim 1 , wherein the plastic comprises high density polyethylene. 
     
     
         8 . The process of  claim 1 , wherein the plastic comprises multi-layer films comprising a metal barrier layer, polyethylene and/or polypropylene. 
     
     
         9 . The process of  claim 8 , wherein the metal barrier layer is comprised of aluminum. 
     
     
         10 . The process of  claim 1 , wherein the mixture comprises from 1-10 wt. % of the high density polyethylene. 
     
     
         11 . The process of  claim 1 , wherein the plastic comprises polypropylene having an average molecular weight, Mw, in the range of 5,000 to 150,000. 
     
     
         12 . The process of  claim 1 , wherein the plastic comprises polypropylene having an average molecular weight, Mw, in the range of 150,000 to 400,000. 
     
     
         13 . The process of  claim 4 , wherein the amount of plastic mixed with the bio-feed ranges from 1-10 wt. % of the blend. 
     
     
         14 . The process of  claim 1 , wherein a blend is recovered from (c), and then passed to a catalytic conversion unit. 
     
     
         15 . The process of  claim 14 , wherein the catalytic conversion unit is a FCC unit. 
     
     
         16 . The process of  claim 15 , wherein the FCC unit is in a refinery. 
     
     
         17 . The process of  claim 14 , wherein the catalytic conversion unit is in a refinery.