Aqueous electrocoating composition of the reaction product of an epoxy ester resin and a maleinized drying oil blended with a cross-linking agent

Abstract

The aqueous coating composition contains filmforming constituents dispersed in an aqueous medium; The film-forming constituents are A. the reaction product of 1. an epoxy ester resin such as an epoxy hydroxy poly-ether resin and drying oil fatty acids, and 2. maleinized drying oil, and B. a water dispersible cross-linking agent such as benzoguanamine formaldehyde; The composition is neutralized to a pH of 7.2-10 with a basic compound such as potassium hydroxide or an amine; The composition is applied by conventional spray techniques or by electrodeposition and is useful as a primer or as a primer surfacer for automobile and truck bodies and small metal parts used in the manufacture of automobiles and trucks. Finishes of acrylic lacquers, acrylic enamels, acrylic dispersion lacquers or enamels or acrylic powders can be applied over the primed substrates.

The invention claimed is: 
     
       1. An aqueous coating composition having a pH of about 7.2-10.0 comprising 5-50% by weight of film-forming constituents uniformly dispersed in an aqueous medium; wherein the film-forming constituents consist essentially of a. 50-97% by weight, based on the weight of the film-forming constituents, of a polymer having an acid number of about 30-60 which is the reaction product of     
     
     
       1. an epoxy ester resin of an epoxy resin of the formula ##EQU3## where R is an alkylene group having 1-4 carbon atoms and m is a positive integer sufficiently large to provide a Gardner Holdt viscosity of A to Z 5  measured at 25°C. on a 40% weight solids polymer solution using ethylene glycol monobutyl ether solvent; and drying oil fatty acids selected from the group consisting of linseed oil fatty acids, tung oil fatty acids, dehydrated castor oil fatty acids, soya oil fatty acids and tall oil fatty acids; and 2.   
     
     
       2. a maleinized drying oil which is the reaction product of maleic anhydride and a drying oil selected from the group consisting of linseed oil, tung oil, dehydrated castor oil, soya oil and tall oil; and b. 3-50% by weight, based on the weight of the film-forming constituents, of a water dispersible cross-linking agent selected from the group consisting of phenol formaldehyde, urea formaldeyde, methylated urea formaldehyde, melamine formaldehyde, alkylated melamine formaldehyde having 1-4 carbon atoms in the alkyl group and benzoguanamine formaldehyde;   wherein the composition contains sufficient basic compound to have said pH and wherein the basic compound is selected from the group consisting of an   
     
     
        alkali metal hydroxide, an amine or a polyamine. 2. The coating composition of claim 1 containing 0.5-20% by weight, based on the weight of the film-forming constituents, of pigment. 
     
     
       3. The coating composition of claim 1 in which R is either methylene or isopropylidene. 
     
     
       4. The coating composition of claim 3 in which the cross-linking agent is benzoguanamine formaldehyde or hexakis(methoxymethyl) melamine. 
     
     
       5. The coating composition of claim 4 in which the film-forming constituents consist essentially of 60-95% by weight of said polymer; and correspondingly,   5-40% by weight of a water dispersible cross-linking agent.   
     
     
       6. The aqueous coating composition of claim 1 having a pH of about 7.5-8.5 comprising 10-40% by weight of film-forming constituents uniformly dispersed in an aqueous medium; wherein th film-forming constituents consists essentially of a. 60-95% by weight, based on the weight of the film-forming constituents, of a polymer which is the reaction product of 1. an epoxy ester resin of an epoxy resin of the formula ##EQU4## wherein m is a positive integer sufficiently large to provide a Gardner Holdt viscosity of D-G measured at 25°C. on a 40% weight solids polymer solution using ethylene glycol monobutyl ether solvent; and drying oil fatty acids selected from the group consisting of linseed oil fatty acids, tung oil fatty acids, dehydrated castor oil fatty acids, soya oil fatty acids and tall oil fatty acids; and       
     
     
       2. a maleinized drying oil which is the reaction product of maleic anhydride and a drying oil selected from the group consisting of linseed oil, tung oil, dehydrated castor oil, soya oil and tall oil; and the polymer has an acid number of about 30-60 and a Gardner-Holdt viscosity of Z 1  -Z 6  measured at 25°C. on a 75% weight solids polymer solution using ethylene glycol monobutyl ether solvent; and correspondingly, b. 5-40% by weight, based on the weight of the film-forming constituents, of a benzoguanamine formaldehyde or hexakis(methoxymethyl) melamine cross-linking agents; and     wherein the composition contains sufficient potassium hydroxide or dimethylamino ethanol to have said pH.   
     
     
       7. The aqueous coating composition of claim 6 in which the drying oil fatty acids are tall oil fatty acids in which the drying oil is linseed oil. 
     
     
       8. An electrocoating bath comprising the coating composition of claim 1 adapted for electrocoating in which the composition contains 2-35% by weight of film-forming constituents. 
     
     
       9. A replenishment concentrate for dispersing in an aqueous electrocoating bath comprising 60-90% by weight of film-forming constituents of claim 1 in a solvent wherein 0-50% of the film-forming constituents are neutralized with a basic compound. 
     
     
       10. The replenishment concentrate of claim 9 containing 0.5-50% by weight, based on the weight of the film-forming constituents, of pigment.