Bichromophoric benzoxazole ultraviolet stabilizers

Abstract

The invention relates to bichromophoric heterocyclic ester compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of these bichromophoric heterocyclic ester compositions to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

We claim: 
     
       1. A polychromophoric composition of matter having the formula:   (A).sub.x --C     where A is a group having the structure ##STR15## wherein R 1 , R 2 , R 3 , R 4  and R 5  are hydrogen, chloro, bromo, fluoro, lower alkyl, cycloalkyl, alkoxy, dimethylamino, cyano, and carboalkoxy;   I is the same as R 1 , R 2 , R 3  and R 4  and is present on all positions of the benzenoid ring, except the carbon atom shared with the heterocyclic ring and the carbon atom attached to the carbonyl group connecting the heterocyclic aromatic A group with the aromatic C group, at least one I substituent on one of the carbon atoms adjacent to said carbon atom attached to said carbonyl group is hydrogen and the remaining I substituents can all be the same or they may be different substituents as listed above;   x is an integer of 1 to 4; and   C is: (a) an aromatic group having the formula ##STR16##  where I is as defined above and is present in all positions of the benzenoid ring except the carbon atom attached to the carboxyl group connecting the A and C moieties, and said I substituents can all be the same or they may be different substituents as listed above;   (b) an aromatic group having the formula ##STR17##     
     
     
       2. A composition of matter according to claim 1 having the formula: ##STR18## wherein R 1 , R 2 , R 3 , R 4  and R 5  are hydrogen, chloro, bromo, lower alkyl, cycloalkyl, alkoxy, dimethylamino, cyano, and carboalkoxy; I is the same as R 1 , R 2 , R 3  and R 4  and is present on all positions of the benzenoid ring, except the carbon atom attached to the carbonyl linking substituent, at least one of said I substituents on the carbon atom adjacent to said carbon atom attached to said carbonyl group is hydrogen and the remaining I substitutents can all be the same or they may be different substituents as listed above.   
     
     
       3. A polychromophoric composition of matter having the formula:   (A).sub.x --C     where A is a group having the structure ##STR19## wherein R 1 , R 2 , R 3 , R 4  and R 5  are hydrogen, chloro, bromo, fluoro, lower alkyl, cycloalkyl, alkoxy, dimethylamino, cyano, and carboalkoxy;   I is the same as R 1 , R 2 , R 3  and R 4  and is present on all positions of the benzenoid ring, except the carbon atom incorporated in the heterocyclic ring and the carbon atom attached to the carbonyl group connecting the heterocyclic aromatic A group with the aromatic C group, at least one I substituent on one of the carbon atoms adjacent to said carbon atom attached to said carbonyl group is hydrogen and said remaining I substitutents can all be the same or they may be different substituents as listed above;   x is an integer of 2 to 4; and   C is an aromatic group having the formula ##STR20## where I is as defined above and is present in all positions of the benzenoid ring except the carbon atom attached to the carboxyl group connecting the A and C moieties, and said I substituents can all be the same or they may be different substituents as listed above.   
     
     
       4. A composition of matter having the formula: ##STR21## 
     
     
       5. A composition of matter having the formula: ##STR22## 
     
     
       6. A composition of matter having the formula: ##STR23##