Benzodisultams

Abstract

The invention relates to new benzodisultams of the general formula (I) ##STR1## in which R 1 represents an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R 2 represents hydrogen or an optionally substituted radical from the series comprising alkyl, alkenyl, alkinyl and aralkyl, and R 3 represents an optionally substituted and/or optionally fused six-membered aromatic heterocyclic radical which contains at least one nitrogen atom, a process for their preparation and their use as herbicides.

We claim: 
     
       1. A process for the preparation of a benzodisultam of the formula ##STR199## in which R 1  represents C 1  -C 12  -alkyl which is optionally substituted by fluorine, chlorine, cyano, C 1  -C 4  -alkoxy, C 1  -C 4  -alkylthio, C 1  -C 4  -alkylsulphinyl, C 1  -C 4  -alkylsulphonyl, C 1  -C 4  -alkylcarbonyl, C 1  -C 4  -alkoxy-carbonyl, C 1  -C 4  -alkylamino-carbonyl or di-(C 1  -C 4  -alkyl)-amino-carbonyl; or represents C 3  -C 6  -alkenyl which is optionally substituted by fluorine, chlorine or bromine; or represents C 3  -C 6  -alkinyl, C 3  -C 6  -cycloalkyl, C 3  -C 6  -cycloalkyl-C 1  -C 2  -alkyl or phenyl-C 1  -C 2  -alkyl which is optionally substituted by fluorine, chlorine, nitro, cyano, C 1  -C 4  -alkyl, C 1  -C 4  -alkoxy or C 1  -C 4  -alkoxy-carbonyl; or represents phenyl which is optionally substituted by fluorine, chlorine, nitro, cyano, C 1  -C 4  -alkyl, trifluoromethyl, C 1  -C 4  -alkoxy, C 1  -C 2  -fluoroalkoxy, C 1  -C 4  -alkylthio, trifluoromethylthio or C 1  -C 4  -alkoxycarbonyl; R 2  represents hydrogen; C 1  -C 4  -alkyl which is optionally substituted by fluorine, chlorine, cyano, C 1  -C 4  -alkoxy, C 1  -C 4  -alkylthio, C 1  -C 4  -alkylsulphinyl, C 1  -C 4  -alkylsulphonyl, C 1  -C 4  -alkylcarbonyl, C 1  -C 4  -alkoxy-carbonyl, C 1  -C 4  -alkylamino-carbonyl or di-(C 1  -C 4  -alkyl)-aminocarbonyl; or represents C 3  -C 6  -alkenyl, C 3  -C 6  -alkinyl or phenyl-C 1  -C 2  -alkyl which is optionally substituted by fluorine, chlorine, nitro, cyano, C 1  -C 4  -alkyl, C 1  -C 4  -alkoxy or C 1  -C 4  -alkoxy-carbonyl; R 4  represents hydrogen; fluorine, chlorine; bromine, hydroxyl; C 1  -C 4  -alkyl which is optionally substituted by fluorine and/or chlorine; C 1  -C 4  -alkoxy which is optionally substituted by fluorine and/or chlorine; C 1  -C 4  -alkylthio which is optionally substituted by fluorine and/or chlorine; amino, C 1  -C 4  -alkylamino or di-(C 1  -C 4  -alkyl)-amino;   X represents nitrogen or a methine bridge (CH),   Y represents nitrogen or an optionally substituted methine bridge C-R 5 ,   R 5  represents hydrogen, fluorine, chlorine, bromine, C 1  -C 4  -alkyl, C 1  -C 4  -alkylcarbonyl or C 1  -C 4  -alkoxycarbonyl,   Z represents nitrogen or an optionally substituted methine bridge C-R 6 ,   R 6  represents hydrogen; fluorine; chlorine; bromine; hydroxyl; C 1  -C 4  -alkyl which is optionally substituted by fluorine and/or chlorine; C 1  -C 4  -alkoxy which is optionally substituted by fluorine and/or chlorine; C 1  -C 4  -alkylthio which is optionally substituted by fluorine and/or chlorine; amino; C 1  -C 4  -alkylamino or di-C 1  -C 4  -alkyl)-amino comprising reacting benzene-1,2-disulphonic acid dichloride of the formula ##STR200##  with an oxyguanidine derivative of the formula ##STR201##  in the presence of an acid acceptor.