Pressure sensitive adhesives with reducible adhesive force using radiation, and films therewith

Abstract

A pressure sensitive adhesive film reducible in the adhesive force by the application thereto of ultraviolet light which comprises: (a) a base film permeable to ultraviolet light; and (b) a layer of a pressure sensitive adhesive formed on one side of the base film, the adhesive comprising: (i) at least one elastic polymer selected from the group consisting of a polymer mainly composed of an acrylic acid ester copolymer and a saturated copolyester mainly composed of dibasic carboxylic acids and dihydroxy alcohols; (ii) an ultraviolet light polymerizable acrylic acid ester having not less than two acryloyl or methacryloyl groups in the molecule and having a molecular weight of not more than about 1000, in amounts of about 15-200 parts by weight in relation to 100 parts by weight of the elastic polymer; and (iii) a photopolymerization initiator in amounts sufficent to induce the photopolymerization of the ultraviolet light polymerizable acrylic acid ester; The film is especially suitable for use as a dicing film in dicing a semiconductor wafer to dices in which the wafer is fixed on the film with a relatively large adhesive force and thereafter the film is irradiated by ultraviolet light from the other side thereof to substantially reduce the adhesive force of the film so that the dice is loosely adhered onto the film.

What is claimed is: 
     
       1. A pressure sensitive adhesive reducible in adhesive force by the application thereto of ultraviolet light which comprises: (i) at least one elastic polymer selected from the group consisting of a polymer comprising an acrylic acid ester copolymer, and a saturated copolyester comprising a dibasic carboxylic acid and a dihydroxy alcohol;   (ii) an ultraviolet light polymerizable acrylic acid ester having not less than two acryloyl or methacryloyl groups in the molecule and having a molecular weight of not more than about 1000, in amounts of about 15-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iii) a tackifier in amounts of about 10-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iv) anhydrous silica powder in amounts of about 1-30 parts by weight in relation to 100 parts by weight of the elastic polymer;   (v) a polyisocyanate in amounts of about 1-100 parts by weight in relation to 100 parts by weight of the elastic polymer; and   (vi) a photopolymerization initiator in a sufficient amount to induce the photopolymerization of the ultraviolet light polymerizable acrylic acid ester.   
     
     
       2. A pressure sensitive adhesive film reducible in adhesive force by the application thereto of ultraviolet light which comprises: (a) a base film permeable to the ultraviolet light; and   (b) a layer of a pressure sensitive adhesive formed on one side of the base film, the adhesive comprising: (i) at least one elastic polymer selected from the group consisting of a polymer comprising an acrylic acid ester copolymer, and a saturated copolyester comprising a dibasic carboxylic acid and a dihydroxy alcohol;   (ii) an ultraviolet light polymerizable acrylic acid ester having not less than two acryloyl or methacryloyl groups in the molecule and having a molecular weight of not more than about 1000, in amounts of about 15-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iii) a tackifier in amounts of about 10-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iv) anhydrous silica powder in amounts of about 1-30 parts by weight in relation to 100 parts by weight of the elastic polymer;   (v) a polyisocyanate in amounts of about 1-100 parts by weight in relation to 100 parts by weight of the elastic polymer; and   (vi) a photopolymerization initiator in a sufficient amount to induce the photopolymerization of the ultraviolet light polymerizable acrylic acid ester.     
     
     
       3. The pressure sensitive adhesive film as claimed in claim 2, wherein the base film is a polyvinyl chloride film. 
     
     
       4. A pressure sensitive adhesive film reducible in adhesive force by the application thereto of electromagnetic waves which comprises: (a) a base film permeable to the electromagnetic wave; and   (b) a layer of a pressure sensitive adhesive formed on one side of the base film, the adhesive comprising: (i) at least one elastic polymer selected from the group consisting of a polymer comprising an acrylic acid ester copolymer, and a saturated copolyester comprising a dibasic carboxylic acid and a dihydroxy alcohol;   (ii) an electromagnetic wave polymerizable acrylic acid ester having not less than two acryloyl or methacryloyl groups in the molecule and having a molecular weight of not more than about 1000, in amounts of about 15-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iii) a tackifier in amounts of about 10-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iv) anhydrous silica powder in amounts of about 1-30 parts by weight in relation to 100 parts by weight of the elastic polymer;   (v) a polyisocyanate in amounts of about 1-100 parts by weight in relation to 100 parts by weight of the elastic polymer.     
     
     
       5. A pressure sensitive adhesive film reducible in adhesive force by the application thereto of electron beam which comprises: (a) a base film permeable to the electron beam; and   (b) a layer of a pressure sensitive adhesive formed on one side of the base film, the adhesive comprising: (i) at least one elastic polymer selected from the group consisting of a polymer comprising an acrylic acid ester copolymer, and a saturated copolyester comprising a dibasic carboxylic acid and a dihydroxy alcohol;   (ii) an electron beam polymerizable acrylic acid ester having not less than two acryloyl or methacryloyl groups in the molecule and having a molecular weight of not more than about 1000, in amounts of about 15-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iii) a tackifier in amounts of about 10-200 parts by weight in relation to 100 parts by weight of the elastic polymer;   (iv) anhydrous silica powder in amounts of about 1-30 parts by weight in relation to 100 parts by weight of the elastic polymer;   (v) a polyisocyanate in amounts of about 1-100 parts by weight in relation to 100 parts by weight of the elastic polymer.