US5286842AExpiredUtilityPatentIndex 96
Process for producing a biodegradable polymer
Est. expiryJul 1, 2011(expired)· nominal 20-yr term from priority
Inventors:KIMURA YOSHIHARU
C07D 323/00C07D 321/08C08G 63/08
96
PatentIndex Score
89
Cited by
12
References
6
Claims
Abstract
A process for producing a biodegradable polymer, which comprises subjecting a cyclic compound of the following formula (1) or (2) to ring opening polymerization: ##STR1## wherein R 1 is a C 1-10 alkyl group, ##STR2## wherein R 2 is a C 1-10 alkyl group, and R 3 is a hydrogen atom or a C 1-10 alkyl group.
Claims
exact text as granted — not AI-modifiedI claim:
1. A process for producing a biodegradable polymer, which comprises subjecting a cyclic compound of the following formula (1) or (2) to ring opening polymerization: ##STR8## wherein R 1 is a C 1-10 alkyl group, ##STR9## wherein R 2 is a C 1-10 alkyl group, and R 3 is a hydrogen atom or a C 1-10 alkyl group.
2. A cyclic compound of the formula (1): ##STR10## wherein R 1 is a C 1-10 alkyl group.
3. A process for producing a cyclic compound of the formula (1): ##STR11## wherein R 1 is a C 1-10 alkyl group, which comprises cyclically trimerizing a compound of the formula (3): ##STR12## wherein R 1 is as defined above and R 4 is a C 1-10 alkyl group, by an ester exchange catalyst.
4. A cyclic compound of the formula (2): ##STR13## wherein R 2 is a C 1-10 alkyl group, and R 3 is a hydrogen atom or a C 1-10 alkyl group.
5. A process for producing a cyclic compound of the formula (2): ##STR14## wherein R 2 is a C 1-10 alkyl group, and R 3 is a hydrogen atom or a C 1-10 alkyl group, Which comprises reacting a compound of the formula (4): HO--CHR.sub.2 --CH.sub.2 COOH (4) wherein R 2 is as defined above, with a compound of the formula (5): X--CHR.sub.3 --CO--Y (5) wherein R 3 is as defined above, and each of X and Y is a halogen atom, to form a compound of the formula (6): ##STR15## wherein R 2 , R 3 and X are as defined above, and then subjecting the compound of the formula (6) to a ring closure reaction.
6. The process of claim 5, wherein compounds (4) and (5) are dissolved in a solvent and reacted in the presence of an amine compound to obtain compound (6), and compound (6) is then treated with alkali to obtain compound (2) by a ring closure reaction.Cited by (0)
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