Molecular level cleaning of contaminates from parts utilizing an envronmentally safe solvent

Abstract

The present invention provides a solvent mixture comprising n-Propyl bromide, a mixture of terpenes and a mixture of low boiling solvents, and a method for cleaning an article (e.g., an electrical, plastic, and metal parts) in a vapor degreaser using the solvent mixture. The solvent mixture of the present invention is non-flammable, noncorrosive and non-hazardous. In addition, it has a high solvency and a very low ozone depleting potential. Thus, using the solvent mixture of the present invention, oil, grease, rosin flux and other organic material can be readily removed from the article of interest in an environmentally safe manner.

What is claimed is: 
     
       1. A solvent mixture for use in a vapor degreasing system, said solvent mixture comprising: 90 percent to about 96.5 percent n-Propyl bromide;   an effective amount of up to about 6.5 percent of a mixture of terpenes, said terpene mixture comprising 35 percent to about 50 percent cis-pinane and 35 percent to about 50 percent trans-pinane; and   3.5 percent to about 5 percent of a mixture of low boiling solvents, said solvent mixture comprising 0.5 percent to about 1 percent nitromethane, 0.5 percent to about 1 percent 1,2-butylene oxide and 2.5   percent to about 3 percent 1,3-dioxolane.   
     
     
       2. A solvent mixture in accordance with claim 1 wherein said terpene mixture further comprises a terpene selected from the group consisting of endo-isocamphene, α-pinene, cis-para-menthane and trans-para-menthane. 
     
     
       3. A solvent mixture in accordance with claim 1 wherein said terpene mixture further comprises endo-isocamphene, a-pinene, cis-para-menthane and trans-para-menthane. 
     
     
       4. A solvent mixture in accordance with claim 1 wherein said solvent mixture in non-flammable. 
     
     
       5. A solvent mixture in accordance with claim 1 wherein said solvent mixture has a high solvency with a Kauri-Butanol value above 120. 
     
     
       6. A solvent mixture in accordance with claim 1 wherein said solvent mixture has a high solvency with a Kauri-Butanol value of 125 or above. 
     
     
       7. A solvent mixture in accordance with claim 1 wherein said solvent mixture in operation in a vapor degreasing system leaves a non-volatile residue (NVR) of less than 2.5 mg. 
     
     
       8. A solvent mixture in accordance with claim 1 wherein said solvent mixture in operation in a vapor degreasing system leaves no residue. 
     
     
       9. A solvent mixture in accordance with claim 1 wherein said solvent mixture has an evaporation rate of at least 0.96 (1,1,1 Trichloroethane=1). 
     
     
       10. A solvent mixture in accordance with claim 1 wherein said solvent mixture has a latent heat evaporation of about 58.8 cal/g. 
     
     
       11. A solvent mixture in accordance with claim 1 wherein said solvent mixture has a Ozone Depletion Potential between 0.001-0.04 and a Halogen Global Warming Potential of 0.0001-0.0003 or almost zero. 
     
     
       12. A method for cleaning an article in a vapor degreaser, said method comprising: (a) providing a vapor degreaser system;   (b) adding to the solvent reservoir of said vapor degreaser system a solvent mixture, said solvent mixture comprising: 90 percent to about 96.5 percent n-Propyl bromide;   an effective amount of up to about 6.5 percent of a mixture of terpenes, said terpene mixture comprising 35 percent to about 50 percent cis-pinane and 35 percent to about 50 percent trans-pinane; and   3.5 percent to about 5 percent of a mixture of low boiling solvents, said solvent mixture comprising 0.5 percent to about 1 percent nitromethane, 0.5 percent to about 1 percent 1,2-butylene oxide and 2.5 percent to about 3 percent 1,3-dioxolane.       (c) boiling said solvent mixture to form a vapor layer;   (d) introducing into said vapor layer said article to be cleaned, said vapor layer condensing on said article, thereby subjecting the surface of said article to a solvent-flushing action; and     (e) removing said article from said vapor layer.   
     
     
       13. A method in accordance with claim 12 wherein said terpene mixture further comprises a terpene selected from the group consisting of endo-isocamphene, α-pinene, cis-para-menthane and trans-para-menthane. 
     
     
       14. A method in accordance with claim 12 wherein said terpene mixture further comprises endo-isocamphene, α-pinene, cis-para-menthane and trans-para-menthane. 
     
     
       15. A method in accordance with claim 12 wherein said solvent mixture in non-flammable. 
     
     
       16. A method in accordance with claim 12 wherein said solvent mixture has a high solvency with a Kauri-Butanol value above 80. 
     
     
       17. A method in accordance with claim 12 wherein said solvent mixture has a high solvency with a Kauri-Butanol value above 125. 
     
     
       18. A method in accordance with claim 12 wherein said solvent mixture in operation in a vapor degreasing system leaves a non-volatile residue (NVR) of less than 2.5 mg. 
     
     
       19. A method in accordance with claim 12 wherein said solvent mixture in operation in a vapor degreasing system leaves no residue. 
     
     
       20. A method in accordance with claim 12 wherein said solvent mixture has an evaporation rate of at least 0.96 where 1,1,1 Trichloroethane=0.1. 
     
     
       21. A method in accordance with claim 12 wherein said solvent mixture has a latent heat evaporation of about 58.8 cal/g.