Thermal dye transfer dye-donor element with transferable protection overcoat

Abstract

A dye-donor element for thermal dye transfer comprising a support having thereon at least one dye layer area comprising an image dye in a binder and another area comprising a transferable protection layer, the transferable protection layer area being approximately equal in size to the dye layer area, wherein the transferable protection layer comprises either a) poly(vinyl formal), poly(vinyl benzal) or poly(vinyl acetal) containing at least about 5 mole % hydroxyl and a crosslinking agent, or b) a phenoxy resin.

What is claimed is: 
     
       1. A dye-donor element for thermal dye transfer comprising a support having thereon at least one dye layer area comprising an image dye in a binder and another area comprising a transferable protection layer, said transferable protection layer area being approximately equal in size to said dye layer area, wherein said transferable protection layer comprises either a) poly(vinyl formal), poly(vinyl benzal) or poly(vinyl acetal) containing at least about 5 mole % hydroxyl and a crosslinking agent, or   b) a phenoxy resin and a crosslinking agent.   
     
     
       2. The element of claim 1 wherein said phenoxy resin comprises ##STR3## 
     
     
       3. The element of claim 1 wherein said transferable protection layer comprises poly(vinyl acetal) containing at least about 5 mole % hydroxyl and a crosslinking agent. 
     
     
       4. The element of claim 3 wherein said crosslinking agent is a titanium alkoxide. 
     
     
       5. The element of claim 4 wherein said titanium alkoxide is titanium butoxide and is present in an amount from about 0.01 g/m 2  to 0.045 g/m 2 . 
     
     
       6. The element of claim 1 wherein said dye-donor element is a multicolor element comprising repeating color patches of yellow, magenta and cyan image dyes, respectively, dispersed in a binder, and a patch containing said protection layer. 
     
     
       7. A process of forming a protection layer on top of a thermal dye transfer image comprising: (I) imagewise-heating a dye-donor element comprising a support having thereon a dye layer comprising an image dye in a binder, said dye-donor being in contact with a dye-receiving element, thereby transferring a dye image to said dye-receiving element to form said dye transfer image; and   (II) thermally transferring a protection layer on top of said transferred dye image, said protection layer being applied from an element which contains either a) poly(vinyl formal), poly(vinyl benzal) or poly(vinyl acetal) containing at least about 5 mole % hydroxyl and a crosslinking agent, or   b) a phenoxy resin and a crosslinking agent.     
     
     
       8. The process of claim 7 wherein said protection layer is present on a separate area of said dye-donor element. 
     
     
       9. The process of claim 7 wherein said protection layer is present on a separate donor element. 
     
     
       10. The process of claim 7 wherein said phenoxy resin comprises ##STR4## 
     
     
       11. The process of claim 7 wherein said transferable protection layer comprises poly(vinyl acetal) containing at least about 5 mole % hydroxyl and a crosslinking agent. 
     
     
       12. The process of claim 7 wherein said dye-donor element is a multicolor element comprising repeating color patches of yellow, magenta and cyan image dyes, respectively, dispersed in a binder, and a patch containing said protection layer. 
     
     
       13. A thermal dye transfer assemblage comprising (A) a dye-donor element for thermal dye transfer comprising a support having thereon at least one dye layer area comprising an image dye in a binder and another area comprising a transferable protection layer, said transferable protection layer area being approximately equal in size to said dye layer area, and   (B) a dye receiving element comprising a support having thereon a dye image-receiving layer, said dye-receiving element being in a superposed relationship with said dye-donor element so that said dye layer is in contact with said dye image-receiving layer; wherein said transferable protection layer comprises either   a) poly(vinyl formal), poly(vinyl benzal) or poly(vinyl acetal) containing at least about 5 mole % hydroxyl and a crosslinking agent, or   b) a phenoxy resin and a crosslinking agent.     
     
     
       14. The assemblage of claim 13 wherein said phenoxy resin comprises ##STR5## 
     
     
       15. The assemblage of claim 13 wherein said transferable protection layer comprises poly(vinyl acetal) containing at least about 5 mole % hydroxyl and a crosslinking agent. 
     
     
       16. The assemblage of claim 13 wherein said crosslinking agent is titanium butoxide and is present in an amount from about 0.01 g/m 2  to 0.045 g/m 2 . 
     
     
       17. The assemblage of claim 13 wherein said dye-donor element is a multicolor element comprising repeating color patches of yellow, magenta and cyan image dyes, respectively, dispersed in a binder, and a patch containing said protection layer.