Organic electroluminescence device

Abstract

An organic electroluminescence device which has a pair of electrodes, at least one of which is transparent or semitransparent, and at least one organic layer formed between the electrodes. The organic layer contains a hole transporting material and a light emitting material in the same or different layer. The hole transporting material contains at least one polysilane whose main chain skeleton is composed of a repeating unit represented by the general formula (1) and a repeating unit represented by the general formula (2): wherein R1, R2, R3 and R4 independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group, Ar1 represents a substituted or unsubstituted arylene group and Ar2 represents a substituted or unsubstituted aryl group. The polysilane satisfies the expression 0.2</=z</=1 where a ratio of the number of the repeating unit (1) and that of the repeating unit (2) to the total number of the repeating units (1) and (2) are z and 1-z, respectively. The polysilane has a weight average molecular weight of not less than 5000 and a hole drift mobility of 10-3-10-1 cm2/v/sec. The organic EL device shows excellent characteristics of higher luminance and higher luminous efficiency at lower driving voltage.

What is claimed is: 
     
       1. An organic electroluminescence device comprising a pair of electrodes, at least one of which is transparent or semitransparent, and at least one organic layer formed between the electrodes, the organic layer containing a hole transporting material and a light emitting material in the same or different layer, wherein the hole transporting material contains at least one polysilane whose main chain skeleton is composed of a repeating unit represented by the following general formula (1): ##STR10## wherein R 1  and R 2  independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group, Ar 1  represents a substituted or unsubstituted arylene group and Ar 2  represents a substituted or unsubstituted aryl group and a repeating unit represented by the following general formula (2): ##STR11## wherein R 3  and R 4  independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group, and the polysilane satisfying the expression 0.2≦z≦1 where a ratio of the number of the repeating unit (1) and that of the repeating unit (2) to the total number of repeating units (1) and (2) are z and 1-z, respectively, the polysilane having a weight-average molecular weight of not less than 5000 and a hole drift mobility of 10 -3  -10 -1  cm 2  /v/sec. 
     
     
       2. The organic electroluminescence device according to claim 1, wherein a polysilane of the general formula (1) in which R 2  is a substituted or unsubstituted phenyl group, Ar 1  is a substituted or unsubstituted phenylene group and Ar 2  is a substituted or unsubstituted phenyl group is used. 
     
     
       3. The organic electroluminescence device according to claim 1 or 2, comprising a pair of electrodes, at least one of which is transparent or semitransparent, and at least one organic layer formed between the electrodes, the organic layer containing a hole transporting material and a light emitting material in the same or different layer, wherein the organic layer contains, as the light emitting material, at least one kind of a polymeric fluorescent substance which has fluorescence in the solid state and contains at least one kind of a repeating unit represented by the following formula (3): ##STR12## (wherein Ar 3  represents an arylene group having 4 to 20 carbon atoms, which takes part in a conjugated bond, or a heterocyclic compound group, and R 5  and R 6  independently represent a group selected from the group consisting of hydrogen, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, a heterocyclic compound group having 4 to 20 carbon atoms and a cyano group), the sum of the above repeating units being not less than 50% by mol of the total number of the repeating units, a number-average molecular weight of the polymeric fluorescent substance being 10 3  -10 7 . 
     
     
       4. The organic electroluminescence device according to claim 1, wherein a hole transporting layer containing at least one kind of the polysilane of claim 1 or 2 and a light emitting layer are laminated each other. 
     
     
       5. The organic electroluminescence device according to claim 1, wherein a hole transporting layer containing at least one kind of the polysilane, a light emitting layer and an electron transporting layer are laminated. 
     
     
       6. The organic electroluminescence device according to claim 1, comprising at least one organic layer which contains a hole transporting material containing at least one kind of the polysilane and a light emitting material. 
     
     
       7. The organic electroluminescence device according to claim 1, comprising at least one organic layer which contains a hole transporting material containing at least one kind of the polysilane, a light emitting material and an electron transporting material.