Fluidized bed polymerization reactor with multiple fluidization grids

Abstract

The invention teaches a novel design for a fluidized bed polymerization reactor which utilizes a primary fluidization grid to provide mixing and fluidization of the polymer and at least one secondary distribution plate located above the first distribution plate to promote segregation of polymer particles by size, the larger particles falling into the lower fluidization zone and the smaller particles being entrained up from the primary fluidization grid and through the secondary distribution grid into an upper reaction zone.

We claim: 
     
       1. A gas-phase polymerization reactor comprising a housing having disposed therein cylindrical reaction zones of diameter D and a transport disengaging section having a diameter greater than D, said housing comprising: a. a primary fluidization grid disposed within said housing, the primary fluidization grid having means to provide mixing and fluidization of granular polymer particles;   b. at least one secondary fluidization grid above the primary fluidization grid, the secondary fluidization grid having means to promote segregation of granular polymer particles and to allow granular polymer particles to fall through the at least one secondary fluidization grid;   c. a primary reaction zone above the at least one secondary fluidization grid having diameter D, the primary reaction zone including a fluidized bed containing growing granular polymer particles and catalyst;   d. a secondary reaction zone below the at least one secondary fluidization grid having diameter D, the secondary reaction zone including a fluidized bed containing growing granular polymer particles and catalyst; and   e. the transport disengaging section above the primary reaction zone, whereby the diameter of the transport disengaging section is greater than D, wherein the primary reaction zone and the secondary reaction zone are in fluid communication with one another to allow for downflow of solids and upflow of gases and liquids.   
     
     
       2. A reactor according to claim 1, wherein the secondary fluidization grid is about 0.5 to 2.0 D above the primary fluidization grid. 
     
     
       3. A reactor according to claim 2, wherein the primary fluidization grid has less than about 75 percent of open area. 
     
     
       4. A reactor according to claim 2, wherein the secondary fluidization grid has greater than about 75 percent of its area open for gas flow. 
     
     
       5. A reactor according to claim 1, further comprising (f) a recycle line outside said housing to recycle material to the bottom of the housing, said recycle line containing a compressor and a heat exchanger. 
     
     
       6. A reactor according to claim 1 additionally comprising (f) a catalyst feeder disposed above said primary fluidization grid; and (g) a product discharge system disposed adjacent said primary and/or secondary reaction zone. 
     
     
       7. A polymerization process comprising: feeding at least one olefin and a catalyst to the gas phase reactor according to claim 1, the reactor having primary and secondary reaction zones of a diameter D and length L;   passing the at least one olefin through the primary fluidization grid;   contacting the at least one olefin that passed through the primary fluidization grid with the catalyst and a bed of growing granular polymer particles in the secondary reaction zone;   passing unreacted olefin and any granular polymer particles entrained therein that passed through the secondary reaction zone through the at least one secondary fluidization grid;   contacting the unreacted olefin and any granular polymer particles entrained therein passed through the at least one secondary fluidization grid with catalyst and growing granular polymer particles in the primary reaction zone; and   passing any unreacted olefin and granular polymer particles entrained therein that passed through the primary reaction zone into a transport disengaging zone having a diameter greater than D.   
     
     
       8. A process according to claim 7, wherein the secondary fluidization grid is about 0.5 to about 1.5 D above the primary fluidization grid. 
     
     
       9. A process according to claim 8, additionally comprising recycling any unreacted olefin and granular polymer particles entrained therein that passed through the primary reaction zone and into the transport disengaging zone to the reactor by first passing the recycle stream through a compressor and a heat exchanger. 
     
     
       10. A process according to claim 9, wherein the recycle stream is introduced below the primary fluidization grid. 
     
     
       11. A process according to claim 9, wherein the recycle stream is introduced at the secondary fluidization grid.