US6635256B1ExpiredUtility

Glycoprotein hormone compositions comprising two β subunits and methods of use thereof

53
Assignee: UNIV WASHINGTONPriority: Oct 19, 1998Filed: Oct 19, 1998Granted: Oct 21, 2003
Est. expiryOct 19, 2018(expired)· nominal 20-yr term from priority
A61P 43/00A61P 15/00A61P 15/08C07K 2319/00A61K 38/24A61K 38/00C07K 14/59
53
PatentIndex Score
10
Cited by
34
References
30
Claims

Abstract

Forms of differentially acting glycoprotein hormones are disclosed. These compositions are of the formulawherein each of beta<1 >and beta<2 >has the amino acid sequence of the beta subunit of a vertebrate glycoprotein hormone or a variant of said amino acid sequence as variants are defined herein. "alpha" designates the a subunit of a vertebrate glycoprotein hormone or a variant thereof; "linker" refers to a covalently linked moiety that spaces the beta<1 >and beta<2 >subunits at appropriate distances from the alpha subunit and from each other. "≈" is a noncovalent link. Each of m and n is independently 0 or 1.

Claims

exact text as granted — not AI-modified
What is claimed is:  
     
       1. A method to provide a subject with glycoprotein hormone activities which method comprises administering to a subject in need of said activities a composition of the formula: 
       
         
           β 2 ≈α-(linker) m -β 1   (1); or  
         
       
       
         
           β 1 -(linker) m -α≈β 2   (2)  
         
       
       wherein each of β 1  and β 2  has the amino acid sequence of the β subunit of a vertebrate glycoprotein hormone, or a variant thereof;  
       “α” has the amino acid sequence of the α subunit of a vertebrate glycoprotein hormone or a variant thereof;  
       “linker” is a linker moiety; and  
       “≈” is a noncovalent link between α and β 2 ;  
       m is 0 or 1;  
       wherein each of β 1  and β 2  is the native β subunit of the same glycoprotein hormone or a variant thereof.  
     
     
       2. The method of  claim 1  wherein β 1  and β 2  are native β subunits. 
     
     
       3. The method of  claim 1  wherein β 1  and β 2  exhibit different biological half-lives. 
     
     
       4. The method of  claim 1  wherein one of β 1  and β 2  confers agonist activity and the other confers antagonist activity. 
     
     
       5. The method of  claim 4 , wherein β 1  is FSHβ or a variant thereof and β 2  is FSHβ or a variant thereof. 
     
     
       6. The method of  claim 4 , wherein β 1  is LHβ or a variant thereof and β 2  is LHβ or a variant thereof. 
     
     
       7. The method of  claim 4 , wherein β 1  is TSHβ or a variant thereof and β 2  is TSHβ or a variant thereof. 
     
     
       8. The method of  claim 4 , wherein β 1  is CGβ or a variant thereof and β 2  is CGβ or a variant thereof. 
     
     
       9. The method of  claim 1  wherein said subject is being treated to enhance fertility. 
     
     
       10. The method of  claim 9  wherein 
       both β 1  and β 2  confer FSH agonist activity on said composition; or  
       both β 1  and β 2  confer CG agonist activity; or  
       both β 1  and β 2  confer LH antagonist activity.  
     
     
       11. The method of  claim 1  wherein said subject is being treated so as to become infertile or to remain infertile. 
     
     
       12. The method of  claim 11  wherein both β 1  and β 2  confer FSH antagonist activity on said composition; or 
       wherein both β 1  and β 2  confer CG antagonist activity; or  
       wherein both β 1  and β 2  confer LH agonist activity.  
     
     
       13. The method of  claim 1  wherein the subject is in need of treatment for polycystic ovarian disease. 
     
     
       14. The method of  claim 13  wherein 
       both β 1  and β 2  confer FSH agonist activity; or  
       both β 1  and β 2  confer LH antagonist activity.  
     
     
       15. The method of  claim 1 , wherein both of β 1  and β 2  confer agonist activity. 
     
     
       16. The method of  claim 15 , wherein β 1  is FSHβ or a variant thereof and β 2  is FSHβ or a variant thereof. 
     
     
       17. The method of  claim 15 , wherein β 1  is LHβ or a variant thereof and β 2  is LHβ or a variant thereof. 
     
     
       18. The method of  claim 15 , wherein β 1  is TSHβ or a variant thereof and β 2  is TSHβ or a variant thereof. 
     
     
       19. The method of  claim 15 , wherein β 1  is CGβ or a variant thereof and β 2  is CGβ or a variant thereof. 
     
     
       20. The method of  claim 1 , where both of β 1  and β 2  confer antagonist activity. 
     
     
       21. The method of  claim 20 , wherein β 1  is an FSHβ variant and β 2  is an FSHβ variant. 
     
     
       22. The method of  claim 20 , wherein β 1  is an LHβ variant and β 2  is an LHβ variant. 
     
     
       23. The method of  claim 20 , wherein β 1  is a TSHβ variant and β 2  is a TSHβ variant. 
     
     
       24. The method of  claim 20 , wherein β 1  is a CGβ variant and β 2  is a CGβ variant. 
     
     
       25. A glycosylated or nonglycosylated composition of the formula 
       
         
           β 2 ≈α-(linker) m -β 1   (1); or  
         
       
       
         
           β 1 -(linker) m -α≈β 2   (2)  
         
       
       wherein each of β 1  and β 2  has the amino acid sequence of the β subunit of a vertebrate glycoprotein hormone, or a variant thereof;  
       “α” has the amino acid sequence of the a subunit of a vertebrate glycoprotein hormone or a variant thereof;  
       “linker” is a linker moiety; and  
       “≈” is a noncovalent link between α and β 2 ;  
       m is 0 or 1;  
       wherein each of β 1  and β 2  is the native β subunit of the same glycoprotein hormone or a variant thereof.  
     
     
       26. The composition of  claim 25 , wherein β 1  is FSHβ or a variant thereof and β 2  is FSHβ or a variant thereof. 
     
     
       27. The composition of  claim 25 , wherein β 1  is LHβ or a variant thereof and β 2  is LHβ or a variant thereof. 
     
     
       28. The composition of  claim 25 , wherein β 1  is TSHβ or a variant thereof and β 2  is TSHβ or a variant thereof. 
     
     
       29. The composition of  claim 25 , wherein β 1  is CGβ or a variant thereof and β 2  is CGβ or a variant thereof. 
     
     
       30. A pharmaceutical composition which regulates the glycoprotein hormone concentrations in a mammal which comprises an effective amount of the composition of the formula 
       
         
           β 2 ≈α-(linker) m -β 1   (1); or  
         
       
       
         
           β 1 -(linker) m -α≈β 2   (2)  
         
       
       in admixture with at least one pharmaceutically acceptable excipient; and  
       wherein each of β 1  and β 2  has the amino acid sequence of the β subunit of a vertebrate glycoprotein hormone, or a variant thereof;  
       “α” has the amino acid sequence of the α subunit of a vertebrate glycoprotein hormone or a variant thereof;  
       “linker” is a linker moiety; and  
       “≈” is a noncovalent link between α and β 2 ;  
       each of m and n is independently 0 or 1;  
       wherein each of β 1  and β 2  is the native β subunit of the same glycoprotein hormone or a variant thereof.

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