US7361687B2ExpiredUtilityPatentIndex 95
Arylsulphonamide derivatives and methods of preparing
Est. expiryJun 14, 2022(expired)· nominal 20-yr term from priority
A61P 9/12A61P 3/06A61P 37/08A61P 9/10A61P 25/24C07D 239/06A61P 25/00A61P 25/04C07D 233/64A61P 29/00A61P 25/22C07D 409/12
95
PatentIndex Score
62
Cited by
18
References
21
Claims
Abstract
The present invention relates to novel arylsulphonamide compounds, defined by formula I and the description, as well as their method of preparation and their therapeutic use
Claims
exact text as granted — not AI-modified1. A compound of formula I:
wherein:
R 1 is aromatic group, where said aromatic is optionally substituted by one or more atoms or groups of atoms selected from the group consisting of halogen, C 1 -C 3 alkyl, C 1 -C 3 alkoxy, nitro, cyano, trifluoromethyl, and trifluoromethoxy;
R 2 is hydrogen or C 1 -C 4 alkyl, where said C 1 -C 4 alkyl is optionally monosubstituted by a phenyl or —CONH 2 or optionally substituted by one or more fluorine atoms;
R 3 is hydrogen or hydroxy;
R 4 is hydrogen;
or R 4 , together with R 3 , forms a —CH═N— or a straight or branched C 2 -C 4 alkylene;
R 5 is hydrogen or C 1 -C 3 alkyl;
R 6 is hydrogen or halogen;
Y is straight or branched saturated C 2 -C 4 alkylene or straight or branched unsaturated C 2 -C 4 alkylene, where said C 2 -C 4 alkylene is optionally interrupted between two carbon atoms by an oxygen atom;
or an acid addition salt thereof.
2. A compound according to claim 1 ,
wherein R 1 is chlorophenyl, dichlorophenyl, trichlorophenyl, chloro-methoxyphenyl, chloro-trifluoromethoxyphenyl, dichloro-trifluoromethyl-phenyl, chlorofluorophenyl, difluorophenyl, trifluoromethyl-phenyl, trifluoromethyl-methoxyphenyl, trifluoromethyl-chlorophenyl trifluoromethoxy-phenyl, tolyl, chlorotolyl, dichlorotolyl, dimethyltolyl, methoxytolyl, methoxy-methyltolyl, dichloromethoxy, trifluoromethoxy-tolyl, naphthyl, nitrophenyl, trifluoromethyl-nitrophenyl, cyanophenyl, or thienyl.
3. A compound according to claim 1 ,
wherein R 1 is phenyl substituted by one or more atoms or groups of atoms selected from the group consisting of halogen, C 1 -C 3 alkyl, and C 1 -C 3 alkoxy.
4. A compound according to claim 1 ,
wherein R 2 is C 1 -C 4 alkyl.
5. A compound according to claim 1 ,
wherein R 2 is hydrogen, methyl, cyclopropyl, trifluoroethyl, isopropyl, —CH 2 CONH, —(CH 2 ) 2 CONH, or phenethyl.
6. A compound according to claim 1 ,
wherein R 3 is hydrogen.
7. A compound according to claim 1 ,
wherein R 3 is hydroxy.
8. A compound according to claim 1 ,
wherein R 4 is hydrogen.
9. A compound according to claim 1 ,
wherein R 3 and R 4 together form a —N═CH— or C 2 -C 3 alkylene.
10. A compound according to claim 1 ,
wherein R 3 and R 4 together form —N═CH—, —(CH 2 ) 2 —, or —CH 2 —C(CH 3 ) 2 —.
11. A compound according to claim 1 ,
wherein R 5 is hydrogen, methyl, ethyl, or isopropyl.
12. A compound according to claim 1 ,
wherein R 6 is hydrogen, difluoro, or dichloro.
13. A compound according to claim 1 ,
wherein R 5 and R 6 are hydrogen.
14. A compound according to claim 1 ,
wherein Y is saturated C 2 -C 4 alkylene or saturated C 2 -C 4 alkylene interrupted by an oxygen atom.
15. A compound according to claim 1 ,
wherein Y is —(CH 2 ) 2 —, —(CH 2 ) 3 —, —(CH 2 ) 4 —, —CH 2 —CH═CH—, —(CH 2 ) 2 —O—CH 2 —, or
16. A compound according to claim 1 ,
wherein Y is —(CH 2 ) 4 —.
17. A compound according to claim 1 ,
wherein Y is —(CH 2 ) 2 —O—CH 2 —.
18. A compound according to claim 1 ,
wherein said compound is:
5-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
4-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-butanamide;
3-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
4-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-(2E)-2-butenamide;
5-[[(2-chlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
(2E)-4-[[(2-chlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
3-[[(2,3-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
4-[[(2,3-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-butanamide;
5-[[(2,3-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
(2E)-4-[[(2,3-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
5-[[(2,6-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
(2E)-4-[[(2,6-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
5-[methyl[(1-naphthalenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
(2E)-4-[methyl[(1-naphthalenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
5-[[(2-chlorophenyl)sulphonyl]cyclopropylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[cyclopropyl[(2,3-dichlorophenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[cyclopropyl[(2,6-dichlorophenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[[(2,6-dichlorophenyl)sulphonyl](1-methylethyl)amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[(2-amino-2-oxoethyl)[(2,4-dichloro-3-methylphenyl)sulphonyl]-amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[(3-amino-3-oxopropyl)[(2,4-dichloro-3-methylphenyl)sulphonyl]-amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
3-[[(2,3-dichlorophenyl)sulphonyl](1-methylethyl)amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
3-[[(2,6-dichlorophenyl)sulphonyl](1-methylethyl)amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
2-[2-[[(2-chlorophenyl)sulphonyl]cyclopropylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[cyclopropyl[(2,3-dichlorophenyl)sulphonyl]amino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[cyclopropyl[(2,6-dichlorophenyl)sulphonyl]amino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,4-dichloro-3-methylphenyl)sulphonyl](2-phenylethyl)-amino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
3-[[(2,6-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
3-[cyclopropyl[(2,3-dichlorophenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
3-[cyclopropyl[(2,6-dichlorophenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
3-[(2,2,2-trifluoroethyl)[(2,3-dichlorophenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
3-[(2,2,2-trifluoroethyl)[(2,6-dichlorophenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-propanamide;
N-[[4-(4,5-dihydro-1H-imidazol-2yl)phenyl]methyl]-N-methyl-4-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]-(2E)-2-butenamide;
4-[[(2,4-dichloro-3-methylphenyl)sulphonyl]amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-(2E)-2-butenamide;
5-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]-N-[[4-(5,5-dimethyl-4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]-N-[[4-(5,5-dimethyl-4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
2-[2-[[(2,3-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-methyl-N-[[4-(1,4,5,6-tetrahydro-2-pyrimidinyl)phenyl]methyl]acetamide;
2-[2-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,3-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,3-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,6-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2-chlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,3-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[2-fluoro-4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,3-dichlorophenyl)sulphonyl]methylamino]propoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,3-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-methyl-N-[[4-(1,4,5,6-tetrahydro-2-pyrimidinyl)phenyl]methyl]acetamide;
2-[2-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,3-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]ethoxy]-acetamide;
2-[2-[[(2,4-dichlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,4-dichloro-5-methylphenyl)sulphonyl]methylamino]-ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[(2-nitrophenyl)sulphonyl]amino]ethoxy]acetamide;
2-[2-[[[2,6-dichloro-4-(trifluoromethyl)phenyl]sulphonyl]-methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2-chloro-3-methylphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2-cyanophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[(2,3,4-trichlorophenyl)sulphonyl]amino]ethoxy]acetamide;
2-[2-[[(3-chloro-2-methylphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2-chloro-4-cyanophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[[2-nitro-4-(trifluoromethyl)phenyl]sulphonyl]amino]-ethoxy]acetamide;
2-[2-[[(2,6-difluorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[[4-(trifluoromethoxy)phenyl]sulphonyl]amino]-ethoxy]acetamide;
2-[2-[[(2,5-dichlorothien-3-yl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[(3-methylphenyl)sulphonyl]amino]ethoxy]acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl(1-naphthalenylsulphonyl)amino]ethoxy]acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[[3-(trifluoromethyl)phenyl]sulphonyl]amino]-ethoxy]acetamide;
2-[2-[[(4-chloro-3-methylphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2,4-difluorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(3-chlorophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-5-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]pentanamide;
5-[[(2,4-dichloro-5-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl-N-methyl-5-[methyl[(3-methylphenyl)sulphonyl]amino]pentanamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-5-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methylamino]-N-methyl-pentanamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl-N-methyl-5-[methyl[(2,3,4-trichlorophenyl)sulphonyl]amino]pentanamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl-N-methyl-5-[methyl[(2-nitrophenyl)sulphonyl]amino]pentanamide;
5-[[(2,4-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[[(2-chloro-3-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
N-[[4-[amino(hydroxyimino)methyl]phenyl]methyl]-5-[[(2,4-dichloro-3-methyl)phenyl]sulphonyl]methylamino]-N-methyl-pentanamide
N-[[4-(aminoiminomethyl)phenyl]methyl]-5-[[(2,4-dichloro-3-methylphenyl)sulphonyl]methylamino]-N-methyl-pentanamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-2-[2-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methylamino]ethoxy]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-4-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]-(2E)-2-butenamide;
N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-4-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]-(2E)-2-butenamide;
4-[[(2,3-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)-2-fluorophenyl]methyl]-N-methyl-(2E)-2-butenamide;
4-[[(2-chlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)-2-fluorophenyl]methyl]-N-methyl-(2E)-2-butenamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-3-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methylamino]-N-methyl-propanamide;
N-[[2-chloro-4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-5-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methylamino]-N-methyl-pentanamide;
N-[[2-chloro-4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-5-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methylamino]-N-methyl-pentanamide;
N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]-ethoxy]acetamide;
N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]-ethoxy]acetamide;
N-[[2-chloro-4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-2-[2-[[(2-chlorophenyl)sulphonyl]methylamino]ethoxy]-N-methyl-acetamide;
N-[[2-chloro-4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-2-[2-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methylamino]ethoxy]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1-(1-methylethyl)-1H-imidazol-2-yl)phenyl]-methyl]-2-[2-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methyl-amino]ethoxy]-N-methyl-acetamide;
N-[[2-chloro-4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]-methyl]-2-[2-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methyl-amino]ethoxy]-N-methyl-acetamide;
N-[[2-chloro-4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]-methyl]-2-[2-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methyl-amino]ethoxy]-N-methyl-acetamide;
N-[[2-chloro-4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]-methyl]-N-methyl-2-[2-[methyl[[2-(trifluoromethyl)phenyl]-sulphonyl]amino]ethoxy]acetamide;
N-[[2-chloro-4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]-methyl]-N-methyl-2-[2-[methyl[[2-(trifluoromethyl)phenyl]-sulphonyl]amino]ethoxy]acetamide;
2-[2-[[(2-cyanophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2-cyanophenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2-chloro-4-methoxyphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(2-chloro-4-methoxyphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1-methyl-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl-N-methyl-3-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]amino]propanamide;
N-[[4-(1-ethyl-4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-[2-[methyl[[2-(trifluoromethyl)phenyl]sulphonyl]-amino]ethoxy]acetamide;
N-[[4-[1-(1-methylethyl)-4,5-dihydro-1H-imidazol-2-yl]phenyl]-methyl]-N-methyl-2-[2-[methyl[[2-(trifluoromethyl)phenyl]-sulphonyl]amino]ethoxy]acetamide;
N-[[4-(1H-1,2,4-triazol-5-yl)phenyl]methyl]-N-methyl-2-[2-[methyl-[(4-methoxy-2,6-dimethylphenyl)sulphonyl]amino]ethoxy]acetamide;
(2E)-4-[[(2-chloro-4-fluorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[[2,6-dichloro-4-(trifluoromethyl)phenyl]sulphonyl]methyl-amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2,6-difluorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2-nitrophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2,4,6-trimethylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2,5-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2,4-dichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(3-chloro-2-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2-cyanophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2-chloro-4-methoxyphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2,4-dichloro-5-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(2,3,4-trichlorophenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[[2-chloro-4-(trifluoromethoxy)phenyl]sulphonyl]-methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[[4-methoxy-2-(trifluoromethyl)phenyl]sulphonyl]methyl-amino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
(2E)-4-[[(4-methoxy-2,6-dimethylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-2-butenamide;
5-[[(2-chloro-4-methoxyphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[[(4-methoxy-2-methylphenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[[[2-methyl-4-(trifluoromethoxy)phenyl]sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
5-[[[4-methoxy-2-(trifluoromethyl)phenyl)sulphonyl]methylamino]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-pentanamide;
2-[2-[[(2-chloro-4-methoxyphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide;
2-[2-[[(4-methoxy-2-methylphenyl)sulphonyl]methylamino]ethoxy]-N-[[4-(4,5-dihydro-1H-imidazol-2-yl)phenyl]methyl]-N-methyl-acetamide.
or an acid addition salt thereof.
19. A compound according to claim 18 ,
wherein said acid addition salt is hydrochloride, fumarate, or trifluoroacetate.
20. A method for preparing a compound according to claim 1 or an acid addition salt thereof, comprising the steps consisting of:
a) reacting an acid of formula II:
wherein
R 1 is aryl, where said aryl is optionally substituted by one or more atoms or groups of atoms selected from the group consisting of halogen, C 1 -C 3 alkyl, C 1 -C 3 alkoxy, nitro, cyano, trifluoromethyl, and trifluoromethoxy;
R 2 is hydrogen or C 1 -C 4 alkyl, where said C 1 -C 4 alkyl is optionally monosubstituted by a phenyl or —CONH 2 or optionally substituted by one or more fluorine atoms;
Y is straight or branched saturated C 2 -C 4 alkylene or straight or branched unsaturated C 2 -C 4 alkylene, where said C 2 -C 4 alkylene is optionally interrupted between two carbon atoms by an oxygen atom; R 1 is an aromatic system that is non-substituted or substituted by one or more atoms or groups of atoms selected from the group consisting of halogen, C 1 -C 3 alkyl, C 1 -C 3 alkoxy, nitro, cyano, trifluoromethyl and trifluoromethoxy;
with an amine of formula III:
wherein
R 3 is hydrogen;
R 4 is hydrogen;
or R 4 , together with R 3 , forms a —CH═N— or a straight or branched C 2 -C 4 alkylene;
R′ 5 is hydrogen, C 1 -C 3 alkyl, or an amino-protecting group;
R 6 is hydrogen or halogen;
wherein the reaction being conducted in a solvent in the presence of at least one activator agent at a temperature of room temperature to 60° C. to obtain the amide of formula:
wherein
R 1 is aryl, where said aryl is optionally substituted by one or more atoms or groups of atoms selected from the group consisting of halogen, C 1 -C 3 alkyl, C 1 -C 3 alkoxy, nitro, cyano, trifluoromethyl, and trifluoromethoxy;
R 2 is hydrogen or C 1 -C 4 alkyl, where said C 1 -C 4 alkyl is optionally monosubstituted by a phenyl or —CONH 2 or optionally substituted by one or more fluorine atoms;
R 3 is hydrogen;
R 4 is hydrogen;
or R 4 , together with R 3 , forms a —CH═N— or a straight or branched C 2 -C 4 alkylene;
R′ 5 is hydrogen, C 1 -C 3 alkyl, or an amino-protecting group;
R 6 is hydrogen or halogen; and
Y is straight or branched saturated C 2 -C 4 alkylene or straight or branched unsaturated C 2 -C 4 alkylene, where said C 2 -C 4 alkylene is optionally interrupted between two carbon atoms by an oxygen atom; R 1 is an aromatic system that is non-substituted or substituted by one or more atoms or groups of atoms selected from the group consisting of halogen, C 1 -C 3 alkyl, C 1 -C 3 alkoxy, nitro, cyano, trifluoromethyl and trifluoromethoxy;
b) if necessary, when said R′ 5 is an amino-protecting group, reacting said compound of formula IV to remove said amino-protecting group and replace it by hydrogen, thereby obtaining said compound of formula I, where R 5 is hydrogen;
c) if necessary, reacting said compound of formula IV or compound of formula I with a mineral or organic acid to obtain said acid addition salt of said compound of formula IV or said compound of formula I.
21. A composition, comprising:
at least one compound according to claim 1 or an acid addition salt thereof; and
at least one physiologically suitable excipient.Cited by (0)
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