Gypsum fertilizer products with polymer adjuvants

Abstract

Improved gypsum fertilizer compositions are provided by coating of naturally-occurring or synthesized gypsum with low pH maleic-itaconic copolymers. The preferred copolymers are aqueous dispersions of acid or partial salt maleic-itaconic copolymers, and are applied by spraying or other means onto the surface of gypsum and allowed to dry. The copolymer coatings increase the solubility of sulfate and Ca ions from the gypsum, allowing accelerated plant availability and uptake of such nutrients.

1. A fertilizer composition comprising respective quantities of gypsum and a copolymer in contact with said gypsum, said copolymer being an acid form copolymer containing individual quantities of maleic and itaconic moieties, said copolymer being the dried residue of an aqueous copolymer dispersion having a pH of from about 0.1-2, said copolymer being present at a level such that the plant availability of calcium and/or sulfate ion is greater than the corresponding plant availability of uncoated gypsum. 
     
     
       2. The fertilizer composition of  claim 1 , said copolymer comprising at least about 93% by weight of itaconic and maleic moieties. 
     
     
       3. The fertilizer composition of  claim 1 , said copolymer being a copolymer containing from about 10-90% by weight maleic moieties, and from about 90-10% by weight itaconic moieties. 
     
     
       4. The fertilizer composition of  claim 1 , said copolymer being present at a level of from about 0.05-5% by weight, based upon the total weight of the composition taken as 100% by weight. 
     
     
       5. The fertilizer composition of  claim 1 , said gypsum being in the form of commercial grade agricultural gypsum. 
     
     
       6. The fertilizer composition of  claim 1 , said copolymer being essentially free of any moieties other than said maleic and itaconic moieties. 
     
     
       7. A method of fertilizing soil comprising the step of applying a fertilizer composition to soil, said fertilizer composition comprising respective quantities of gypsum and a copolymer, said copolymer being an acid form copolymer containing individual quantities of maleic and itaconic moieties, said copolymer being the dried residue of an aqueous copolymer dispersion having a pH of from about 0.1-2, said copolymer being present at a level such that the plant availability of calcium and/or sulfate ion is greater than the corresponding plant availability of uncoated gypsum. 
     
     
       8. The method of  claim 7 , said copolymer comprising at least about 93% by weight of itaconic and maleic moieties. 
     
     
       9. The method of  claim 8 , said copolymer being a copolymer containing from about 10-90% by weight maleic moieties, and from about 90-10% by weight itaconic moieties. 
     
     
       10. The method of  claim 7 , said copolymer being present at a level of from about 0.05-5% by weight, based upon the total weight of the composition taken as 100% by weight. 
     
     
       11. The method of  claim 7 , said copolymer being essentially free of any moieties other than said maleic and itaconic moieties. 
     
     
       12. A method of preparing a fertilizer composition including the steps of providing a quantity of gypsum, and at least partially coating said gypsum with a copolymer, said copolymer being an acid form copolymer containing individual quantities of maleic and itaconic moieties, said copolymer being the dried residue of an aqueous copolymer dispersion having a pH of from about 0.1-2, said copolymer being present at a level such that the plant availability of calcium and/or sulfate ion is greater than the corresponding plant availability of uncoated gypsum. 
     
     
       13. The method of  claim 12 , said copolymer having a pH of from about 0.2-0.8. 
     
     
       14. The method of  claim 12 , said copolymer being applied to said gypsum at a level of from about 0.05-5% by weight, based upon the total weight of the composition taken as 100% by weight.