Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream

Abstract

The present invention is directed to using methyl acetate from a vinyl acetate-based or a vinyl- or ethylene-alcohol based polymer or copolymer process directly for use in a methanol carbonylation production process to produce acetic acid, acetic anhydride, or a coproduction of each. Methyl acetate is a by-product of commercial polyvinyl-alcohol or alkene vinyl alcohol copolymer-based processes. Generally, this material is processed to recover methanol and acetic acid. Discussed herein is a cost-saving scheme to by-pass the methyl acetate processing at production or plant facilities and utilize the methyl acetate in an integrated methanol carbonylation unit. The scheme discussed eliminates an expensive hydrolysis step often associated with the polymer process.

1. A method of integrating a process for the production of poly vinyl alcohol or an alkene vinyl alcohol copolymer with a carbonylation process for the production of acetic acid comprising the steps of:
 a) producing acetic acid; 
 b) contacting the acetic acid with reactants under conditions sufficient to form vinyl acetate; 
 c) contacting the vinyl acetate with reactants under conditions sufficient to form poly vinyl acetate or an alkene vinyl acetate copolymer; 
 d) contacting the poly vinyl acetate or the alkene vinyl acetate copolymer with a base and methanol under conditions sufficient to form poly vinyl alcohol or an alkene vinyl alcohol copolymer and a methyl acetate byproduct stream; 
 e) purifying the methyl acetate byproduct stream by a process consisting essentially of extractive distillation to form a methyl acetate stream, wherein the purifying step removes sufficient impurities from the resulting methyl acetate stream such that the methyl acetate stream is suitable to feed to a carbonylation production process to produce acetic acid; and 
 f) directing the methyl acetate stream to a carbonylation production process to produce acetic acid. 
 
     
     
       2. The process of  claim 1  wherein the methyl acetate byproduct stream comprises methyl acetate, methanol, light organics, and water. 
     
     
       3. The process of  claim 1  wherein the methyl acetate stream comprises methyl acetate, methanol and water. 
     
     
       4. The process of  claim 1  wherein the methyl acetate stream comprises methyl acetate and water, with a concentration of water in the purified methyl acetate stream being limited to no more than an equimolar ratio with methyl acetate. 
     
     
       5. The process of  claim 1  wherein the extractive distillation is operated so as to maintain about one mole of water for every mole of methyl acetate in the purified methyl acetate stream.