Photoelectric conversion film, photoelectric conversion device and color image sensor having the photoelectric conversion device

Abstract

A blue color photoelectric conversion film includes: a p-type layer formed by depositing tetracene; a p,n-type layer formed by co-depositing tetracene and naphthalene-tetracarboxylic-dianhydride (“NTCDA”) on the p-type layer; and an n-type layer formed by depositing NTCDA on the p,n-type layer.

What is claimed is: 
     
       1. A blue color photoelectric conversion film comprising:
 a p-type layer formed by depositing tetraphenyl diamine; 
 a p,n-type layer formed by co-depositing tetraphenyl diamine and C 60  on the p-type layer; and 
 an n-type layer formed by depositing naphthalene-tetracarboxylic-dianhydride on the p,n-type layer. 
 
     
     
       2. A photoelectric conversion device comprising:
 a pair of electrodes; and 
 the blue color photoelectric conversion film of  claim 1  interposed between the pair of electrodes, 
 
       wherein the pair of electrodes comprises a first electrode adjacent to the p-type layer and a second electrode adjacent to the n-type layer. 
     
     
       3. The photoelectric conversion device of  claim 2 , wherein the first electrode is a transparent electrode comprising indium tin oxide, indium zinc oxide, ZnO, SnO 2 , antimony-doped tin oxide, Al-doped zinc oxide, gallium-doped zinc oxide, TiO 2 , fluorine-doped tin oxide or a combination comprising at least one of the foregoing, and the second electrode is the transparent electrode or is a metal electrode comprising Al, Cu, Ti, Au, Pt, Ag, Cr or a combination comprising at least one of the foregoing. 
     
     
       4. The photoelectric conversion device of  claim 2 , further comprising a buffer layer, a hole transfer layer, or an electron transfer layer interposed between the first electrode and the blue color photoelectric conversion film or the second electrode and the blue color photoelectric conversion film. 
     
     
       5. A color image sensor comprising the photoelectric conversion device of  claim 2 . 
     
     
       6. A green color photoelectric conversion film comprising:
 a p-type layer formed by depositing tetraphenyl diamine; 
 a p,n-type layer formed by co-depositing tetraphenyl diamine and N-methyl-3,4,9,10-perylenetetracarboxyl-diimide on the p-type layer; and 
 an n-type layer formed by depositing naphthalene-tetracarboxylic-dianhydride on the p,n-type layer. 
 
     
     
       7. A photoelectric conversion device comprising:
 a pair of electrodes; and 
 the green color photoelectric conversion film of  claim 6  interposed between the pair of electrodes, 
 
       wherein the pair of electrodes comprises a first electrode adjacent to the p-type layer and a second electrode adjacent to the n-type layer. 
     
     
       8. The photoelectric conversion device of  claim 7 , wherein the first electrode is a transparent electrode comprising indium tin oxide, indium zinc oxide, ZnO, SnO 2 , antimony-doped tin oxide, Al-doped zinc oxide, gallium-doped zinc oxide, TiO 2 , fluorine-doped tin oxide or a combination comprising at least one of the foregoing, and the second electrode is the same as transparent electrode or is a metal electrode comprising Al, Cu, Ti, Au, Pt, Ag, Cr or a combination comprising at least one of the foregoing. 
     
     
       9. The photoelectric conversion device of  claim 7 , further comprising a buffer layer, a hole transfer layer, or an electron transfer layer interposed between the first electrode and the green color photoelectric conversion film or the second electrode and green color photoelectric conversion film. 
     
     
       10. A color image sensor comprising the photoelectric conversion device of  claim 7 .