Magnesium-containing complexes, method for their preparation, and compositions containing the same

Abstract

Magnesium-containing complexes are prepared by heating a mixture of magnesium hydroxide, magnesium oxide, hydrated magnesium oxide or a magnesium alkoxide; a carboxylic acid, a sulfonic acid,a pentavalent phosphorus acid, or an ester or salt of any of these; water; and an organic solubilizing agent (which may be liquid or solid at ambient temperature) for the acid or ester. The amount of magnesium is such as to provide a basic composition. The resulting complexes may be obtained in liquid (which may be thickened) or solid form, and are useful as additives for lubricants and fuels and as protective coating compositions for metal surfaces (such as automotive undercoats and frame coatings). .[.This application is a continuation-in-part of copending application Ser. No. 681,627, filed Apr. 29, 1976 and now abandoned..].

What is claimed is: .[.1. A method for preparing a non-carbonated magnesium-containing complex which comprises heating, at a temperature above about 30° C., a mixture comprising: 
     
        acid or carboxylic acid formed by oxidation of petrolatum..]. .[.9.  A method according to claim 8 wherein the mole ratio of component C to component A is at least about 0.7:1..]. .[.10. A method according to claim 9 wherein component A is magnesium oxide. .]. .[.11. A method according to claim 1 wherein component D is at least one substantially inert organic material which is solid at ambient temperature..]. .[.12. A method according to claim 11 wherein component B is at least one sulfonic acid or salt thereof..]. .[.13. A method according to claim 12 wherein the molar ratio of component C to component A is at least about 0.7:1..]. .[.14. A method according to claim 13 wherein component B is at least one alkylaromatic sulfonic acid..]. .[.15. A method according to claim 14 wherein component B is at least one alkylbenzenesulfonic acid..]. .[.16. A method according to claim 15 wherein component A is magnesium oxide..]. .[.17. A method according to claim 1 wherein component D is a mixture of at least one one substantially inert material which is solid at ambient temperature with at least one substantially inert, normally liquid organic diluent..]. .[.18. A method according to claim 17 wherein component B is at least one sulfonic acid or a magnesium salt thereof..]. .[.19. A method according to claim 18 wherein the molar ratio of component C to component A is at least about 0.7:1..]. .[.20. A method according to claim 19 wherein component B is at least one alkylaromatic sulfonic acid..]. .[.21. A method according to claim 20 wherein component B is at least one alkylbenzenesulfonic acid..]. .[.22. A method according to claim 21 wherein component A is magnesium oxide..]. .[.23. A method according to claim 17 wherein component B is a mixture of at least one alkylbenzenesulfonic acid and at least one carboxylic acid formed by oxidation of petrolatum..]. .[.24. A method according to claim 23 wherein the mole ratio of component C to component A is at least about 0.7:1..]. .[.25. A method according to claim 24 wherein component A is magnesium oxide..]. .[.26. A complex prepared by the method of claim 1..]. .[.27. A complex prepared by the method of claim 3..]. .[.28. A complex prepared by the method of claim 5..]. .[.29. A complex prepared by the method of claim 6..]. .[.30. A complex prepared by the method of claim 8..]. .[.31. A complex which is solid at ambient temperature, prepared by the method of claim 11..]. .[.32. A complex which is solid at ambient temperature, prepared by the method of claim 12..]. .[.33. A complex which is solid at ambient temperature, prepared by the method of claim 14..]. .[.34. A complex which is solid at ambient temperature, prepared by the method of claim 15..]. .[.35. A thickened complex according to claim 26..]. .[.36. A thickened complex according to claim 27..]. .[.37. A thickened complex according to claim 28..]. .[.38. A thickened complex according to claim 29..]. .[.39. A thickened complex according to claim 30..]. .[.40. A thickened complex prepared by the method of claim 17..]. .[.41. A 
     
     
        thickened complex prepared by the method of claim 18..]. .[.42.  A thickened complex prepared by the method of claim 20..]. .[.43. A thickened complex prepared by the method of claim 21..]. .[.44. A thickened complex prepared by the method of claim 23..]. .[.45. A complex of magnesium oxide or hydroxide and a magnesium sulfonate prepared by heating, at a temperature within the range of about 40°-90° C., a mixture comprising: (A) Magnesium oxide;   (B) An alkylbenzenesulfonic acid having an equivalent weight within the range of about 300-500;   (C) Water; and   (D) At least one of mineral oil, Stoddard solvent, toluene and the alkylbenzene whose sulfonation product is component B;   the ratio of equivalents of component A to component B being at least about 5:1 and the molar ratio of component C to component A being between about 0.7:1 and 3.0:1..]. .[.46. A thickened complex according to claim 45..]. .[.47. A complex of magnesium oxide or hydroxide and a magnesium sulfonate which is solid at ambient temperature and which is prepared by heating, at a temperature within the range of about 95°-150° C., a mixture comprising:   (A) Magnesium oxide;   (B) An alkylbenzenesulfonic acid having an equivalent weight within the range of about 300-500;   (C) Water; and   (D) A mixture comprising hydrocarbon waxes, C 20-40  waxy aliphatic alcohols and the alkylbenzene whose sulfonation product is component B;   the ratio of equivalents of component A to component B being at least about 5:1 and the molar ratio of component C to component A being between about   
     
     
        0.7:1 and 3.0:1..]. 48. An additive concentrate comprising a substantially inert, normally liquid organic diluent and about 20-90% by weight of .[.the complex of claim 26.]. .Iadd.a complex according to any of claims 54-85. .Iaddend. .[.49. An additive concentrate comprising a substantially inert, normally liquid organic diluent and about 20-90% by weight of the 
     
     
        complex of claim 45..]. 50. A composition comprising a major amount of a lubricating oil and a minor amount sufficient to impart detergency thereto of .[.the complex of claim 26.]. .Iadd.a complex according to any of claims 54-85. .Iaddend. .[.51. A composition comprising a major amount of a lubricating oil and a minor amount, sufficient to impart detergency thereto and comprising about 0.5-10.0% by weight, of the complex of claim 
     
     
        45..]. 52. A composition comprising a major amount of a normally liquid fuel and a minor amount, sufficient to impart corrosion resistance thereto, suppress smoke or serve as a vanadium scavenger, of .[.the complex of claim 26.]. .Iadd.a complex according to any of claims 54-85. .Iaddend. .[.53. A composition comprising a major amount of a normally liquid fuel and a minor amount, sufficient to impart corrosion resistance thereto, suppress smoke or serve as a vanadium scavenger and comprising about 4-1000 parts by weight per million parts of fuel, of the complex of 
     
     
        claim 45..]. .Iadd.54.  A non-carbonated magnesium-containing complex in the form of a solid, grease or gel, prepared by heating, at a temperature above about 30° C. and up to about 150° C. a mixture consisting essentially of (A) at least one of magnesium hydroxide, magnesium oxide, hydrated magnesium oxide, or magnesium alkoxide;   (B) at least one oleophilic organic reagent consisting essentially of sulfonic acid, a pentavalent phosphorus acid, or an ester or alkali metal or alkaline earth metal salt of any of these;   (C) water; and   (D) at least one organic solubilizing agent for component B: the ratio of equivalents of magnesium to component B, calculated as the free sulfonic acid or as the phosphoric acid ester, being at least about 5:1; the amount of water present being at least sufficient to hydrate a substantial proportion of component A calculated as magnesium oxide and the weight ratio of solubilizing agent D to component A being at least 0.5:1. .Iaddend. .Iadd.55. A complex according to claim 54 wherein component D is at least one substantially inert, normally liquid organic diluent. .Iaddend. .Iadd.56. A complex according to claim 55 wherein component B is at least one sulfonic acid or salt thereof. .Iaddend. .Iadd.57. A complex according to claim 56 wherein the molar ratio of component C to component A is at least about 0.7:1. .Iaddend. .Iadd.58. A complex according to claim 57 wherein component B is at least one alkylaromatic sulfonic acid. .Iaddend. .Iadd.59. A complex according to claim 58 wherein component B is at least one alkylbenzenesulfonic acid. .Iaddend. .Iadd.60. A complex according to claim 59 wherein component A is magnesium oxide. .Iaddend.   
     
     
        .Iadd.61.  A solid complex according to claim 54 wherein component D is at least one substantially inert organic material which is solid at ambient temperature. .Iaddend. .Iadd.62. A solid complex according to claim 61 wherein component B is at least one sulfonic acid or salt thereof. .Iaddend. .Iadd.63. A solid complex according to claim 62 wherein the molar ratio of component C to component A is at least about 0.7:1. .Iaddend. .Iadd.64. A solid complex according to claim 63 wherein component B is at least one alkylaromatic sulfonic acid. .Iaddend. .Iadd.65. A solid complex according to claim 64 wherein component B is at least one alkylbenzenesulfonic acid. .Iaddend. .Iadd.66. A solid complex according to claim 65 wherein component A is magnesium oxide. .Iaddend. .Iadd.67. A complex according to claim 54 wherein component D is a mixture of at least one substantially inert material which is solid at ambient temperature with at least one substantially inert, normally liquid organic diluent. .Iaddend. .Iadd.68. A complex according to claim 67 wherein component B is at least one sulfonic acid or a magnesium salt thereof. .Iaddend. .Iadd.69. A complex according to claim 68 wherein the molar ratio of component C to component A is at least about 0.7:1. .Iaddend. .Iadd.70. A complex according to claim 69 wherein component B is at least one alkylaromatic sulfonic acid. .Iaddend. .Iadd.71. A complex according to claim 70 wherein component B is at least one alkylbenzenesulfonic acid. .Iaddend. .Iadd.72. A complex according to claim 71 wherein component A is magnesium oxide. .Iaddend. .Iadd.73. A complex of magnesium oxide or hydroxide and a magnesium sulfonate in the form of a solid, grease or gel, prepared by heating, at a temperature within the range of about 40°-90° C. consisting essentially of: (A) magnesium oxide;   (B) an alkylbenzenesulfonic acid having an equivalent weight within the range of about 300-500;   (C) water; and   (D) at least one of mineral oil, Stoddard solvent, toluene or alkylbenzene whose sulfonation product is component B;   the ratio of equivalents of component A to component B being at least about 5:1; the molar ratio of component C to component A being between about 0.7:1 and 3.0:1 and the weight ratio of component D to component B being   
     
     
        at least 0.5:1. .Iaddend. .Iadd.74.  A complex of magnesium oxide or hydroxide and a magnesium sulfonate which is solid at ambient temperature and which is prepared by heating, at a temperature within the range of about 95°-150° C., a mixture comprising: (A) magnesium oxide;   (B) an alkylbenzenesulfonic acid having an equivalent weight within the range of about 300-500;   (C) water; and   (D) a mixture comprising hydrocarbon waxes, C 20-40  waxy aliphatic alcohols and alkylbenzene whose sulfonation product is component B;   the ratio of equivalents of component A to component B being at least about 5:1 and the molar ratio of component C to component A being between about   
     
     
        0.7:1 and 3.0:1. .Iaddend. .Iadd.75.  A non-carbonated magnesium-containing complex in the form of a solid prepared by heating, at a temperature above about 30° C., a mixture comprising: (A) at least one of magnesium hydroxide, magnesium oxide, hydrated magnesium oxide, and a magnesium alkoxide;   (B) an oleophilic organic reagent comprising a mixture of a carboxylic acid containing at least 8 carbon atoms with a sulfonic acid, or esters or alkali metal or alkaline earth metal salts of any of these;   (C) water; and   (D) at least one organic solubilizing agent for component B, said agent being at least one substantially inert organic material which is solid at ambient temperature;   the ratio of equivalents of magnesium to component B, calculated as the free carboxylic or sulfonic acid being at least about 5:1, and the amount of water present being at least sufficient to hydrate a substantial proportion of component A calculated as magnesium oxide. .Iaddend. .Iadd.76. A complex according to claim 75 wherein component B is a mixture of at least one alkylbenzenesulfonic acid and at least one hydrogenated fatty acid or carboxylic acid formed by oxidation of petrolatum. .Iaddend. .Iadd.77. A complex according to claim 76 wherein the mole ratio of component C to component A is at least about 0.7:1. .Iaddend. .Iadd.78. A complex according to claim 77 wherein component A is magnesium oxide. .Iaddend. .Iadd.79. A solid complex according to claim 75 wherein component B is a mixture of at least one alkylbenzenesulfonic acid and at least one hydrogenated fatty acid or carboxylic acid formed by oxidation   
     
     
        of petrolatum. .Iaddend. .Iadd.80.  A solid complex according to claim 79 wherein the mole ratio of component C to component A is at least about 0.8:1. .Iaddend. .Iadd.81. A solid complex according to claim 80 wherein component A is magnesium oxide. .Iaddend. .Iadd.82. A complex according to claim 75 wherein component D is a mixture of at least one substantially inert material which is solid at ambient temperature with at least one substantially inert, normally liquid organic diluent. .Iaddend. .Iadd.83. A complex according to claim 82 wherein component B is a mixture of at least one alkylbenzenesulfonic acid and at least one carboxylic acid formed by oxidation of petrolatum. .Iaddend. .Iadd.84. A complex according to claim 83 wherein the mole ratio of component C to component A is at least about 0.7:1. .Iaddend. .Iadd.85. A complex according to claim 84 wherein component A is magnesium oxide. .Iaddend.