Process for magnetic image character recognition

Abstract

Disclosed is an improved, simple, economical process for generating documents, such as personal checks, suitable for magnetic image character recognition, which process comprises generating such documents with conventional xerographic methods in a high speed electronic laser printing device, and wherein there is selected as the developer composition a magnetic toner containing from about 20 percent by weight to about 70 percent by weight of magnetite particles, and from about 30 percent by weight to about 80 percent by weight of toner resin particles of styrene copolymers, such as a styrene butadiene copolymer, a styrene n-butylmethacrylate copolymer, or polyesters, and wherein the carrier particles are comprised of ferrite cores, coated with various polymeric resinous compositions. There can also be included in the developer composition various additives such as collodial silica particles, and charge enhancing additives, and further conductive carbon black or insulating carbon black particles can be incorporated into the carrier polymeric resinous coating.

We claim: 
     
       1. An improved process for generating documents which comprises providing the document desired, imprinting characters thereon by electrostatographic methods with a high speed electronic printing device, and developing the characters with a magnetic developer composition comprised of from about 20 percent by weight to about 70 percent by weight of magnetite, and from about 30 percent by weight to about 80 percent by weight of toner resin particles, selected from the group consisting of styrene methacrylate copolymers, styrene butadiene copolymers, and styrene acrylate copolymers; and carrier particles comprised of ferrite cores coated with polymeric compositions. 
     
     
       2. A process in accordance with claim 1 wherein the documents generated are personal checks. 
     
     
       3. A process in accordance with claim 1 wherein the magnetite is present in an amount of from about 20 percent by weight to about 50 percent by weight and the toner resin particles are present in an amount of from about 50 percent by weight to about 80 percent by weight. 
     
     
       4. A process in accordance with claim 1 wherein the toner resin particles are comprised of a styrene butadiene copolymer, containing from about 85 percent to about 90 percent of styrene, and from about 10 percent to about 15 percent by weight of butadiene, or a styrene n-butylmethacrylate resin particle, wherein the styrene is present in an amount of from about 40 percent by weight to about 90 percent by weight, and the n-butylmethacrylate is present in an amount of from about 10 percent by weight to about 60 percent by weight. 
     
     
       5. A process in accordance with claim 1 wherein there is further included in the polymeric coating for the carrier particles conductive carbon black or insulating carbon black particles. 
     
     
       6. A process in accordance with claim 1 wherein there is further included in the toner resin particles carbon black particles, or collidal silica particles. 
     
     
       7. A process in accordance with claim 1 wherein the polymeric coating composition for the ferrite core is a methacrylate, styrene, vinyl triethoxy silane terpolymer. 
     
     
       8. A process in accordance with claim 1 wherein the magnetite is comprised of acicular magnetite. 
     
     
       9. A process in accordance with claim 1 wherein there is further incorporated into the toner composition as a charge enhancing additive stearyl dimethyl phenethyl ammonium para-toluene sulfonate. 
     
     
       10. A process in accordance with claim 1 wherein there is added to the toner composition alkyl pyridinium charge enhancing additives. 
     
     
       11. A process in accordance with claim 10 wherein the additive is cetyl pyridinium chloride. 
     
     
       12. A process in accordance with claim 1 wherein the magnetite is cubical magnetite. .Iadd. 
     
     
       13.  An improved process for generating documents which comprises providing the document desired, imprinting characters thereon by electrostatographic methods with a high speed electronic printing device, and developing the characters with a magnetic developer composition comprised of from about 20 percent by weight to about 70 percent by weight of magnetite, and from about 30 percent by weight to about 80 percent by weight of toner resin particles selected from the group consisting of styrene methacrylate copolymers, styrene butadiene copolymers, and styrene acrylate copolymers; and carrier particles. .Iaddend. .Iadd. 
     
     
       14.  A process in accordance with claim 13 wherein the carrier particles consist of a core with a polymeric coating thereover. .Iaddend. .Iadd.15. A process in accordance with claim 14 wherein there is selected as the core a component selected from the group consisting of steel, iron, nickel and ferrites. .Iaddend. .Iadd.16. A process in accordance with claim 14 wherein the polymeric coating is a terpolymer of styrene, methylmethacrylate, and an organo silane. .Iaddend. .Iadd.17. A process in accordance with claim 14 wherein the polymeric coating for the carrier particles includes conductive carbon black or insulating carbon black particles. .Iaddend. .Iadd.18. A process in accordance with claim 15 wherein the coating includes conductive carbon black or insulating carbon black particles. .Iaddend. .Iadd.19. An improved aerographic process which comprises forming a latent image on an imaging member; thereafter developing this image with a magnetic developer composition comprised of from about 20 percent to about 70 percent by weight of magnetite, and from about 30 percent by weight to about 80 percent by weight of toner resin particles selected from the group consisting of styrene methacrylate copolymers, styrene butadiene copolymers and styrene acrylate copolymers, and polyesters; and carrier particles; subsequently transferring the developed image to a supporting substrate; and affixing the image thereto. .Iaddend. .Iadd.20. A process in accordance with claim 19 wherein the carrier particles are comprised of a core selected from the group 
     
     
        consisting of iron, nickel and ferrites. .Iaddend. .Iadd.21.  A process in accordance with claim 19 wherein the carrier particles include a polymeric coating. .Iaddend. .Iadd.22. A process in accordance with claim 21 wherein the coating is a styrene methacrylate organo silane terpolymer. .Iaddend. .Iadd.23. A process in accordance with claim 21 wherein there is included in the polymeric coating conductive carbon black or insulating carbon black particles. .Iaddend. .Iadd.24. A process in accordance with claim 19 wherein there are further included in the toner composition charge enhancing additives selected from the group consisting of stearyl dimethyl phenethyl ammonium paratoluene sulfonate, and alkyl pyridinium halides. .Iaddend. .Iadd.25. A process in accordance with claim 19 wherein the supporting substrates are personal checks. .Iaddend. .Iadd.26. A process in accordance with claim 19 wherein the latent image is formulated by a high speed electronic printing device. .Iaddend. .Iadd.27. A process in accordance with claim 19 wherein the magnetite is present in an amount of from about 20 percent by weight to about 50 percent by weight, and the toner resin particles are present in an amount of from about 50 percent by 
     
     
        weight to about 80 percent by weight. .Iaddend. .Iadd.28.  A process in accordance with claim 19 wherein the toner resin particles are comprised of a styrene butadiene copolymer containing from about 85 percent to about 90 percent of styrene, and from about 10 percent to about 15 percent by weight of butadiene, or a styrene n-butylmethacrylate resin particle, wherein the styrene is present in an amount of from about 40 percent by weight to about 90 percent by weight, and the n-butylmethacrylate is present in an amount of from about 10 percent by weight to about 60 percent by weight. .Iaddend. .Iadd.29. A process in accordance with claim 19 wherein there are further included in the developer colloidal silica particles. .Iaddend. .Iadd.30. A process in accordance with claim 19 wherein the imaging member is comprised of a component selected from the group consisting of selenium and selenium alloys. .Iaddend. .Iadd.31. A process in accordance with claim 19 wherein the images are permanently affixed by heat. .Iaddend.