Process for the production of aromatic polyesters

Abstract

In a continuous process for the manufacture of aromatic polyesters by polycondensation of mono- or multi-nuclear substituted or unsubstituted diphenols, with halides of aromatic dicarboxylic acids according to the two-phase interface polycondensation process, the first step is to produce continuously a fine pre-emulsion with an organic solvent and from the aqueous phase, consisting of a solution obtained from the diphenols, of an alkaline hydroxide in order to form the diphenates and possibly of a phase transfer catalyst in water or in a mixture of water and of an organic solubilizer. This pre-emulsion is fed in quantities to a dispersion unit jointly with the organo-liquid phase forming the acid chloride solution. The compounds involved in the polycondensation reaction are mixed in the dispersion unit in constant proportions in order to produce a reaction emulsion which then passes successively through one or several dispersion units and/or into static mixers, the polycondensation taking place and being completed during this period. The phases are then separated and the polyester formed is precipitated from the organic phase.

I claim: 
     
       1. A continuous process for producing an aromatic polyester by polycondensing at least one mono- or multinuclear substituted .Iadd.or unsubstituted .Iaddend.diphenol as first reactant with at least one aromatic dicarboxylic acid halide as second reactant comprising: preparing an aqueous phase by mixing the said at least one diphenol, an alkali metal hydroxide for the formation of diphenolates with or without a phase transfer catalyst, water or a mixture of water and an organic solubilizer;   preparing an organic liquid phase by mixing the said at least one aromatic dicarboxylic acid halide and an organic solvent to form a solution thereof;   continuously mixing the aqueous phase with an organic solvent to form a fine pre-emulsion;   preparing a reaction emulsion by continuously supplying organic liquid phase and pre-emulsion to an input of a dispersing unit whereby reactants in said phase and pre-emulsion are mixed in constant proportions;   passing and reacting the reaction emulsion through at least one dispersing unit.   
     
     
       2. The process of claim 1 comprising passing the reaction emulsion in addition to its passing through dispersing units, through a static mixer or through several static mixers. 
     
     
       3. The process of claim 2 wherein the reaction emulsion passes first through one or several static mixers subsequently through a dispersing unit and subsequently again through one or several static mixers. 
     
     
       4. The process of claim 1 wherein in the reaction emulsion the volume of the aqueous phase is smaller than the volume of the other phase of the reaction emulsion. 
     
     
       5. The process of claim 4 comprising passing the reaction emulsion in addition to its passing through dispersing units, through a static mixer or through several static mixers. 
     
     
       6. The process of claim 4 wherein in the fine pre-emulsion the volume of the aqueous phase is smaller than the volume of the organic solvent. 
     
     
       7. The process of claim 1 wherein the dispersing units have a rotor rotating at a circumferential speed of at least 5 meters per second which is provided with several recesses or perforations, and which, in each instance, is separated by a small mixing chamber from an associated stator also provided with recesses or perforations. 
     
     
       8. The process of claim 7 wherein said dispersing units have a rotor rotating at a circumferential speed of at least 10 meters per second.