Plastic composite barrier structures

Abstract

Composite moisture and oxygen barrier structures in the form of films, sheets, tubes, and bottles are described which are composed of foils of high density polyethylene and foils of polar oxygen barrier resins adhered to each other with a coextruded bonding resin composition composed of blends of predominantly high density polyethylene containing low levels of a grafted unsaturated dicarboxylic acid anhydride and linear low density polyethylenes which are copolymers of ethylene with either octene-1 or butene-1. The preferred dicarboxylic acid anhydride is maleic anhydride. The oxygen barrier resins are preferably ethylene/vinyl alcohol copolymers or amorphous polycarboxylamides from condensation polymerization of aliphatic diamines and aromatic dicarboxylic acids.

I claim: 
     
       1. A melt-extrudable bonding resin composition capable of adhering nonpolar high density linear polyethylene in the form of foils, sheets, tubes or blown bottles to polar oxygen barrier resins in the form, respectively, of foils, sheets, tubes or blown bottles which exhibits a combination of resistance to separation of said nonpolar high density polyethylene from said polar oxygen barrier resins and low moisture vapor transmission, said bonding resin composition consisting essentially of a blend of from 70 to 90 weight percent of composition (i) and from 10 to 30 weight percent of composition (ii) wherein composition (i) is composed of a blend of high density linear polyethylene having a melt index in the range of 0.1 to 8.0 g/10 min and a density in the range of from above 0.950 to 0.970 g/cm 3  and sufficient of a high density linear polyethylene having a melt index in the range of 0.1 to 8.0 g/10 min and a density in the range of 0.950 to 0.970 g/cm 3  having from .[.0.7-14 mole.]. .Iadd.0.5 to 1 weight .Iaddend.percent of maleic anhydride grafted to said high density linear polyethylene to provide from .[.0.245-1.05 mole.]. .Iadd.0.055 to 0.2 weight .Iaddend.percent of said grafted maleic anhydride in said composition (i), wherein composition (ii) is a linear low density polyethylene selected from the group consisting of linear copolymers of ethylene with butene-1 and linear copolymers of ethylene with octene-1 having a density in the range of 0.912 to 0.930 g/cm 3  and a melt index in the range of 0.5 to 3.35 g/10 min. 
     
     
       2. The bonding resin of claim 1 in which composition (i) comprises 80 to 90 weight percent and composition (ii) comprises 10 to 20 weight percent of the bonding resin. 
     
     
       3. The bonding resin of claim 2 in which the linear low density polyethylene of composition (ii) is a copolymer of ethylene and octene-1. 
     
     
       4. The bonding resin of claim 2 in which the linear low density polyethylene of composition (ii) is a copolymer of ethylene and butene-1.